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The Schiff base of pyridoxal-5′-phospate with ethylenediamine and ethylamine: Species in solution

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Biochemistry of Vitamin B6 and PQQ

Part of the book series: Advances in Life Sciences ((ALS))

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Abstract

Elucidation of intermediates in the transamination reactions has been widely studied on the basis of model reactions between pyridoxal (PL) and pyridoxal 5′-phosphate (PLP) with amines and diamines. H-NMR and UV-visible data [l–4] suggested the presence of carbinolamine and/or geminaldiamine together with Schiff base. The present work deals with a contribution to the study of the reaction mixtures of PLP and ethylenediamine (Etd) and PLP and ethylamine (Et) by electrochemical techniques and UV-visible and fluorescence spectroscopies.

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© 1994 Birkhäuser Verlag Basel/Switzerland

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Sevilla, J.M., Hidalgo, C., Pineda, T., Garcia-Blanco, F., Blazquez, M. (1994). The Schiff base of pyridoxal-5′-phospate with ethylenediamine and ethylamine: Species in solution. In: Marino, G., Sannia, G., Bossa, F. (eds) Biochemistry of Vitamin B6 and PQQ. Advances in Life Sciences. Birkhäuser Basel. https://doi.org/10.1007/978-3-0348-7393-2_37

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  • DOI: https://doi.org/10.1007/978-3-0348-7393-2_37

  • Publisher Name: Birkhäuser Basel

  • Print ISBN: 978-3-0348-7395-6

  • Online ISBN: 978-3-0348-7393-2

  • eBook Packages: Springer Book Archive

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