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The distribution of cadmium in the sea

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Cadmium in the Environment

Part of the book series: Experientia Supplementum ((EXS,volume 50))

Abstract

Cadmium occurs in the sea at ultra trace levels. The concentration varies in various regions of the oceans according to the different oceanographic conditions. Among the heavy metal trace-elements with general or potential ecotoxic significance (Pb, Hg, Cu, Ni, Cr, As, Zn), Cd occurs in surface waters of the open oceans in the relatively lowest concentrations, mostly between 0.1 and 20 ng/kg. The lower section of this range corresponds to large areas in the subtropical and central gyres, whereas the upper section of the range is observed in areas of upwelling, at oceanic divergencies and at the subpolar fronts. Somewhat higher values can occur in shelf regions, due to release of Cd from the bottom sediment depot. In areas of pronounced upwelling the values in surface waters may even be raised to 50–70 ng/kg. Comparable or even higher levels are also observed as a consequence of anthropogenic input in polluted coastal waters (viz. e.g. North Sea and particularly its Southern Bight and German Bight).

Deceased, May 1985.

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References

  1. Boyle, E., and Huested, S., Aspects of the surface distribution of copper, nickel, cadmium and lead in the North Atlantic and North Pacific, in: Trace Metals in Sea Water, pp. 379–394. Eds C. S. Wong, E. Boyle, K.W. Bruland, D. Burton and E.D. Goldberg. Plenum Press, New York-London 1983.

    Google Scholar 

  2. Boyle, E., Huested, S., and Jones, S., On the distribution of copper, nickel and cadmium in the surface waters of the North Atlantic and North Pacific Ocean. J. geophys. Res. 86 (1981) 8048–8066.

    Article  Google Scholar 

  3. Boyle, E., Sclater, F., and Edmond, J. M., On the marine geochemistry of cadmium. Nature 263 (1976) 42–44.

    Article  Google Scholar 

  4. Branica, M., Peharec, Z., and Kwokal, Z., Concentrations of Zn, Pb, Cd and Cu in the surface waters of the Adriatic Sea (1980 cruise of the R/V “Andrija Mohorovicic”. Rapp. Comm. int. Mer médit. (Monaco), in press.

    Google Scholar 

  5. Breder, R., Flucht, R., and Nürnberg, H.W., A comparative study on the toxic trace metal situation in the Thyrrhenian estuaries. Thal-assiajugosl. 18 (1982) 135–171.

    Google Scholar 

  6. Brügmann, L., Danielsson, L.G., Magnusson, B., and Westerlund, S., Data from an expedition with R. V. “Alexander von Humboldt” on the Atlantic Ocean, June 1981, in: Report on the chemistry on sea water XXIX. University of Göteborg, Sweden, 1982.

    Google Scholar 

  7. Bruland, K.W., Oceanographic distributions of cadmium, zinc, nickel, and copper in the North Pacific. Earth planet. Sci. Lett. 47 (1980) 176–198.

    Article  Google Scholar 

  8. Bruland, K. W., Trace elements in sea water, Chapt. 45, Chemical Oceanography, Vol. 8. Eds J. P. Riley and R. Chester. Academic Press, London 1983.

    Google Scholar 

  9. Bruland, K. W., Coale, K. H., and Mart, L., Analysis of sea water for dissolved cadmium, copper and lead: an intercomparison of voltammetric and atomic absorption methods. Mar. Chem. 17 (1985) 285–300.

    Article  Google Scholar 

  10. Bruland, K.W., and Franks, R.P., Mn, Ni, Cu, Zn, and Cd in the western North Atlantic, pp.395–414. Eds C.S. Wong, E. Boyle, K. W. Bruland, D. Burton and E. D. Goldberg. Plenum Press, New York-London 1983.

    Google Scholar 

  11. Bruland, K.W., Franks, R.P., Knauer, G.A., and Martin, J.H., Sampling and analytical methods for the determination of copper, cadmium, zinc, and nickel at the nanogram per liter level in sea water. Analyt. chim. Acta 105 (1979) 233–245.

    Article  Google Scholar 

  12. Bruland, K.W., Knauer, G.A., and Martin, J.H., Cadmium in northeast Pacific waters. Limnol. Oceanogr. 23 (1978) 618–625.

    Article  Google Scholar 

  13. Copin-Montegut, G., Courau, P. and Nicolas, E., Cd and Pb in Mediterranean waters. Mar. Chem., in press.

    Google Scholar 

  14. Danielsson, L.G., Cadmium, cobalt, copper, iron, lead, nickel and zinc in Indian Ocean water. Mar. Chem. 8 (1980) 199–215.

    Article  Google Scholar 

  15. Danielsson, L.G., and Westerlund, S., Trace metals in the Arctic Ocean, in: Trace Metals in Sea Water, pp. 85–95. Eds C. S. Wong, E. Boyle, K.W. Bruland, J.D. Burton and E.D. Goldberg. Plenum Press, New York-London 1983.

    Google Scholar 

  16. Dorten, W., Nürnberg, H.W., Mart, L., and Valenta, P., Depth profiles of cadmium, lead and copper in the Black Sea. Sci. tot. Envir. (1986) in press.

    Google Scholar 

  17. Duinker, J. C., and Kramer, C. J. M., An experimental study on the speciation of dissolved Zn, Cd, Pb and Cu in River Rhine and North Sea water by differential pulse anodic stripping voltammetry. Mar. Chem. 5 (1977) 207–228.

    Article  Google Scholar 

  18. Duinker, J.C., and Nolting, R.F., Dissolved copper, zink and cadmium in the Southern Bight of the North Sea. Mar. Poll. Bull. 13 (1982) 93–96.

    Article  Google Scholar 

  19. Gillain, G., Duyckaerts, C., and Disteche, A., Trace metals (Zn, Cd, Pb, Cu, Sb and Bi) levels (ionic and dissolved organic complexes) in the Southern Bight (Belgian Coast). Action Interuniversitaire, Oceanologie, Service Premier Ministre, Bruxelles 1980.

    Google Scholar 

  20. Gustavsson, I., The concentrations of cadmium, lead and copper in filtrated Baltic sea water samples collected at two seasons 1979. Acta hydrochim. hydrobiol. 11 (1983) 309–317.

    Article  Google Scholar 

  21. Kremling, K., The distribution of selected trace metals in Baltic waters; a study on the basis of 2 anchor stations. Proc. of the XI. Conf. of Baltic oceanographers, 1978, vol. 1 pp. 290–297.

    Google Scholar 

  22. Kremling, K., Trace metal fronts in European shelf waters. Nature 303 (1983) 225–227.

    Article  Google Scholar 

  23. Kremling, K., The behaviour of Zn, Cd, Cu, Ni, Co, Fe, and Mn in anoxic Baltic waters. Mar. Chem. 13 (1983) 87–108.

    Article  Google Scholar 

  24. Kremling, K., and Petersen, H., The distribution of zinc, cadmium, copper, manganese and iron in waters of the open Mediterranean Sea. ‘Meteor’ Forsch. Ergebn. 23 (1981) 5–14.

    Google Scholar 

  25. Kremling, K., and Petersen, H., Synoptic survey on dissolved trace metal levels in Baltic surface waters. Mar. Poll. Bull. 15 (1984) 329–334.

    Article  Google Scholar 

  26. Magnusson, B., and Rasmussen, L., Trace metal levels in coastal sea water: Investigation of Danish waters. Mar. Poll. Bull. 13 (1982) 81–84.

    Article  Google Scholar 

  27. Magnusson, B., and Westerlund, S., The determination of Cd, Cu, Fe, Ni, Pb and Zin in the Baltic sea water. Mar. Chem. 8 (1980) 231–244.

    Article  Google Scholar 

  28. Magnusson, B., and Westerlund, S., Trace metal levels in sea water from the Skagerrak and the Kattegat, in: Trace Metals in Sea Water, pp.467–473. Eds C.S. Wong, E. Boyle, K.W. Bruland, J.D. Burton and E. D. Goldberg. Plenum Press, New York-London 1983.

    Google Scholar 

  29. Mart, L., Collection of surface water samples, Fresenius Z. analyt. Chem. 299 (1979) 97–102.

    Article  Google Scholar 

  30. Mart, L., Ermittlung und Vergleich des Pegels toxischer Spurenmetalle in nordatlantischen und mediterranen Küstengewässern. Ph. d. thesis, RWTH Aachen, FRG, 1979.

    Google Scholar 

  31. Mart, L., Minimization of accuracy risks in voltammetric ultra trace determination of heavy metals in natural waters. Talanta 29 (1982) 1035–1040.

    Article  Google Scholar 

  32. Mart, L., Golimowski, J., Klahre, P., Rützel, H., and Nürnberg, H. W., Trace metal levels in different oceanic regions. Sci. tot. Envir. in preparation.

    Google Scholar 

  33. Mart, L., and Nürnberg, H. W., Cd, Pb, Cu, Ni, and Co distribution in the German Bight, Mar. Chem. 18 (1986) in press.

    Google Scholar 

  34. Mart, L., Nürnberg, H.W., and Dyrssen, D., Low level determination of trace metals in Arctic sea water and snow by differential pulse anodic stripping voltammetry, in: Trace Metals in Sea Water, pp. 113–130. Eds C.S. Wong, E. Boyle, K.W. Bruland, J.D. Burton and E. D. Goldberg. Plenum Press, New York-London 1983.

    Google Scholar 

  35. Mart, L., Nürnberg, H.W., and Dyrssen, D., Trace metal levels in the eastern Arctic Ocean. Sci. tot. Envir. 39 (1984) 1–14.

    Article  Google Scholar 

  36. Mart, L., Nürnberg, H. W., and Rützel, H., Comparative studies on cadmium levels in the North Sea, Norwegian Sea, Barents Sea and the eastern Arctic Ocean. Fresenius Z. analyt. Chem. 317 (1984) 201–209.

    Article  Google Scholar 

  37. Mart, L., Nürnberg, H. W., and Rützel, H., Levels of heavy metals in the tidal Elbe and its estuary and heavy metal input into the sea. Sci. tot. Envir. 44 (1985) 35–49.

    Article  Google Scholar 

  38. Mart, L., Nürnberg, H.W., Valenta, P., and Stoeppler, H., Determination of levels of toxic trace metals dissolved in sea water and inland waters by differential pulse anodic stripping voltammetry. Thalassiajugosl. 14 (1978) 171–188.

    Google Scholar 

  39. Mart, L., Rützel, H., Klahre, P., Sipos, L., Platzek, U., Valenta, P., and Nürnberg, H.W., Comparative studies on the distribution of heavy metals in the oceans and coastal waters. Sci. tot. Envir. 26 (1982) 1–17.

    Article  Google Scholar 

  40. Martin, J. H., Bruland, K. W., and Broenkow, W. W., ‘Marine pollutant transfer’, Eds H. L. Windom, and R. A. Duce. Health, Lexington, Mass., 1976.

    Google Scholar 

  41. Martincic, D., Nürnberg, H.W., Stoeppler, M., and Branica, M., Toxic metal levels in bivalves and their ambient water from the Lim Channel. Thalassia jugosl. 16 (1980) 297–315.

    Google Scholar 

  42. Martincic, D., Nürnberg, H.W., Stoeppler, M., and Branica, M., Bioaccumulation of heavy metals by bivalves from Lim Fjord (North Adriatic Sea). Mar. Biol. 81 (1984) 177–188.

    Article  Google Scholar 

  43. Moore, R. M., Océanographie distribution of zinc, cadmium, copper and aluminium in waters of the central Arctic. Geochim. cosmochim. Acta 45 (1981) 2475–2482.

    Article  Google Scholar 

  44. Nürnberg, H.W., Potentialities and applications of advanced Polarographic and voltammetric methods in aquatic and marine trace metal chemistry. Acta Univ. Upsaliensis Annum Quingentesimum Celebrantis 12 (1978) 270–287, Almquist and Wiksell Internat., Stockholm.

    Google Scholar 

  45. Nürnberg, H. W., Investigations on heavy metal speciation in natural waters by voltammetric procedures, Fresenius Z. analyt. Chem. 316 (1983) 557–565.

    Article  Google Scholar 

  46. Nürnberg, H. W., The voltammetric approach in trace metal chemistry of natural waters and atmospheric precipitates. Analyt. chim. Acta 164 (1984) 1–21.

    Article  Google Scholar 

  47. Nürnberg, H. W., Trace analytical procedures with modem voltammetric determination methods for the investigation and monitoring of ecotoxic heavy metals in natural waters and atmospheric precipitates. Sci. tot. Envir. 37 (1984) 9–34.

    Article  Google Scholar 

  48. Nürnberg, H.W., Potentialities of voltammetry for the study of physicochemical aspects of heavy metal complexation in natural waters, in: Complexation of Trace Metals in Natural Waters, pp. 95–115. Eds C.J.M. Kramer and J.C. Duinker. Martinus Nijhoff/W. Junk Publ., The Hague—Boston—Lancaster 1984.

    Google Scholar 

  49. Nürnberg, H.W., and Mart, L., Distribution and Fate of Heavy Metals with Ecotoxic Significance in the Sea, Topics in Current Chemistry. Springer-Verlag, Heidelberg—Berlin—New York, to appear 1986.

    Google Scholar 

  50. Nürnberg, H. W., Mart, L., Rützel, H., and Sipos, L., Investigations on the distribution of heavy metals in the Atlantic and Pacific oceans. Chem. Geol. 40 (1983) 97–116.

    Article  Google Scholar 

  51. Nürnberg, H.W., Valenta, P., Mart, L., Raspor, B., and Sipos, L., The Polarographic approach to the determination and speciation of toxic metals in the marine environment. Fresenius Z. analyt. Chem. 282 (1976) 357–367.

    Article  Google Scholar 

  52. Olafsson, J., Mercury concentrations in the North Atlantic in relation to cadmium, aluminium and oceanographic parameters, in: Trace Metals in Sea Water, pp. 475–485. Eds C. S. Wong, E. Boyle, K. W. Bruland, D. Burton and E. D. Goldberg. Plenum Press, New York-London 1983.

    Google Scholar 

  53. Raspor, B., Nürnberg, H.W., Valenta, P., and Branica, M., Significance of dissolved humic substances for heavy metal speciation in natural waters, in: Complexation of Trace Metals in Natural Waters, pp.317–327. Eds C.J.M. Kramer and J.C. Duinker. Martinus Nijhoff/W. Junk Publ., The Hague—Boston—Lancaster 1984.

    Google Scholar 

  54. Raspor, B., Nürnberg, H.W., Valenta, P., and Branica, M., Studies in sea water and lake water on interactions of trace metals with humic substances isolated from marine and estuarine sediments. Mar. Chem. 15 (1984) 217–230, 231-249.

    Article  Google Scholar 

  55. Schaule, B., and Patterson, C.C., The occurrence of lead in the Northeast Pacific and effects of anthropogenic input, in: Lead in the Marine Environment, pp. 31–43. Eds M. Branica and Z. Konrad. Pergamon Press, Oxford 1980.

    Google Scholar 

  56. Schmidt, D., Comparison of trace heavy metals from monitoring in the German Bight and the southwestern Baltic Sea. Helgoländer Meeresunters. 33 (1980) 576–586.

    Article  Google Scholar 

  57. Schmidt, D., Freimann, P., and Zehle, H., Changes of trace metal levels in waters through the coastal zone of the German Bight (North Sea). Symp. on contaminant fluxes through the coastal zone, Nantes, France, 1984.

    Google Scholar 

  58. Sipos, L., Rützel, H., and Thyssen, T.H.P., Performance of a new device for sampling sea water from the sea bottom. Thalassia jugosl. 16 (1980) 89–94.

    Google Scholar 

  59. Spivack, A.J., Huested, S.S., and Boyle, E.A., Copper, nickel, and cadmium in the surface waters of the Mediterranean, in: Trace Metals in Sea Water, pp.505–512. Eds C.S. Wong, E. Boyle, K.W. Bruland, J. D. Burton and E. D. Goldberg. Plenum Press, New York-London 1983.

    Google Scholar 

  60. Stoeppler, M., and Brandt, K., Comparative studies on trace metal levels in marine biota. II. Trace metals in krill, krill products and fish from the Antarctic Scotia Sea. Z. Lebensmittelunters.-Forsch. 169 (1979) 95–98.

    Google Scholar 

  61. Stoeppler, M., and Nürnberg, H.W., Comparative studies on trace metal levels in marine biota, III. Typical levels and accumulation of toxic trace metals in muscle tissue and organs of marine organisms from different European seas. Ecotox. envir. Safety 3 (1979) 335–351.

    Google Scholar 

  62. Valenta, P., Simoes-Goncalves, M. L. S., and Sugawara, M., Voltammetric studies on the speciation of Cd and Zn by amino acids in sea water, in: Complexation of Trace Metals in Natural Waters, pp. 357–366. C.J.M. Kramer and J.C. Duinker, Martinus Nijhoff/W. Junk Publ., The Hague—Boston—Lancaster 1984.

    Google Scholar 

  63. Whitfield, M., The salt sea—accident or design?, New Sci. 94 (1982) 14–17.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Applied Physical Chemistry, Nuclear Research Establishment (KFA), D-5170, Juelich, Federal Republic of Germany

    L. Mart & H. W. Nürnberg

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  1. L. Mart
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  2. H. W. Nürnberg
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Hans Mislin Oscar Ravera

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© 1986 Birkhäuser Verlag Basel

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Mart, L., Nürnberg, H.W. (1986). The distribution of cadmium in the sea. In: Mislin, H., Ravera, O. (eds) Cadmium in the Environment. Experientia Supplementum, vol 50. Birkhäuser Basel. https://doi.org/10.1007/978-3-0348-7238-6_5

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  • DOI: https://doi.org/10.1007/978-3-0348-7238-6_5

  • Publisher Name: Birkhäuser Basel

  • Print ISBN: 978-3-0348-7240-9

  • Online ISBN: 978-3-0348-7238-6

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