Abstract
Some experiments chosen from given decomposition of hydrates, evaporation of liquids, sublimation of ice suggest that the problem of interpreting the kinetics of heterogeneous, endothermic reactions should be reconsidered taking into account the part played by transfers at the interface so as to give an expression of rate which in addition to the affinity extent, contains a term accounting for interface couplings.
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References
G. Bertrand, M. Lallemant, G. Watelle, J. Inorg. Nucl. Chenu, 36 (1974) 1303.
G. Bertrand, M. Lallemant, G. Watelle, J. Inorg, J. Inorg. Nucl. Chem., 40 (1978) 819.
G. Bertrand, R. Prud’homme, J. Non-Equilib. Thermodyn., 4 (1979) 1.
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Mokhlisse, A., Bertrand, G., Lallemant, M., Roudergues, N. (1980). Characteristics of Interface Endothermic Reactions Reconsidered from a Few Simple Experiments. In: Wiedemann, H.G. (eds) Thermal Analysis. Birkhäuser, Basel. https://doi.org/10.1007/978-3-0348-6719-1_11
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DOI: https://doi.org/10.1007/978-3-0348-6719-1_11
Publisher Name: Birkhäuser, Basel
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