Skip to main content

The Redox Behavior of Biological Quinones and its Relation With the Mitochondrial Respiratory Chain

  • Chapter

Part of the book series: Experientia Supplementum ((EXS,volume 18))

Summary

The electrochemical behavior of ubiquinone 6, of vitamin K3 and dihydrovitamin K3 has been studied on a platinum electrode in acetonitrile. The oxidation and reduction mechanisms have been determined under various proton availabilities of the medium. The significance of the results regarding the respiratory chain is briefly discussed.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. F.L. Crane, in T.P. Singer ed. Biological Oxidations, Interscience, New York, 1968, p. 533.

    Google Scholar 

  2. D.E. Green et al., in T.E. King, H.S. Mason and M. Morrison ed., Oxidases and Related Redox System, Wiley, New York, 1965, vol. II, p. 1003.

    Google Scholar 

  3. See for exemple: K.J. Vetter, Z. Electrochem. 56, 797 (1952); M.E. Peover, J. Chem. Soc. 4540 (1962)

    Google Scholar 

  4. B.R. Eggins and J.Q. Chambers, J. Electrochem. Soc. 117(2), 186 (1970).

    Article  Google Scholar 

  5. J. Bessard, G. Cauquis and D. Serve, Tetrahedron Letters 35, 3103 (1970).

    Article  Google Scholar 

  6. M. Klingenberg and A. Kroger, in D.R. Sanadi ed., Current topics in bioenergetics, Academic Press, New York, 1967, vol. 2, p. 186.

    Google Scholar 

  7. J.P. Billon, J. Electroanal. Chem. 1, 486 (1960).

    Google Scholar 

  8. L.F. Fieser, W.P. Campbell, E.M. Fry and M.D. Gates Jr., J. Am. Chem. Soc. 61, 3216 (1939).

    Article  Google Scholar 

  9. I.F. Vladmirtsev and A.G. Stromberg, Zh. Obshch. Khim. 27, 1029 (1957).

    Google Scholar 

  10. K. Wallenfels and W. Mohle, Ber. Deut. Chem. Ges. 76B, 924 (1943).

    Article  Google Scholar 

  11. I. Tashi and R. Takahashi, Agr. Biol. Chem. (Tokio) 26, 238 (1962).

    Google Scholar 

  12. S.W. Wawzonek, R. Berkey, E.W. Blaha and M.E. Runner, J. Electrochem. Soc. 103, 456 (1956).

    Article  Google Scholar 

  13. F.L. O’Brien, A study of the electrochemistry of ubiquinone and 2,3-dimethoxy 5-methyl 1,4-benzoquinone, Ph. D., University of Massachusetts, 1969.

    Google Scholar 

  14. G.J. Hoijtink, J. Van Schooten, E. de Boer and W.Y. Aalbersberg, Rec. Trav. Chim. Pays Bas 73, 355 (1954).

    Article  Google Scholar 

  15. G. Demange-Guerin et J. Badoz-Lambling, C.R.H. Acad. Sci. 256, 784 (1968).

    Google Scholar 

  16. M.E. Peover and J.D. Davies, Polarography 1964 MacMillan, London, 1966, p. 1003.

    Google Scholar 

  17. G. Cauquis and G. Marbach, Bull. Soc. Chim. Fr., 1971, 1968.

    Google Scholar 

  18. A.L. Lehninger, The Mitochondrion, Benjamin, New York, 1964.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1971 Springer Basel AG

About this chapter

Cite this chapter

Cauquis, G., Marbach, G. (1971). The Redox Behavior of Biological Quinones and its Relation With the Mitochondrial Respiratory Chain. In: Milazzo, G., Jones, P.E., Rampazzo, L. (eds) Biological Aspects of Electrochemistry. Experientia Supplementum, vol 18. Birkhäuser, Basel. https://doi.org/10.1007/978-3-0348-5848-9_15

Download citation

  • DOI: https://doi.org/10.1007/978-3-0348-5848-9_15

  • Publisher Name: Birkhäuser, Basel

  • Print ISBN: 978-3-0348-5850-2

  • Online ISBN: 978-3-0348-5848-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics