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La Préparation et Quelques Propriétés Thermiques des Mono- et Dihalogénures de L’Hydrazine

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Abstract

Modified syntheses of hydrazinium mono- and dihalogenides are described. DTA of these compounds showed an exothermic effect in the temperature region between 125° and 270°C. This effect was found to be consequence of the disproportionation reaction of hydrazinium ion.The formed products were identified by chemical analysis and infrared spectra. On the basis of the observed thermal properties of the mentioned halogenides the use of hydrazinium chloride or bromide for the preparation of inorganic halogen compounds in the melt is suggested.

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Bibliographie

  1. Th. Curtius et H. Schultz, J.Prakt.Chem., 42, 521 (1890)

    Article  Google Scholar 

  2. B.E. Christensen et E.C. Gilbert, J.Am.Chem.Soc., 56, 393 (1934)

    Article  Google Scholar 

  3. E.C. Gilbert et J.C. Decius, J.Am.Chem.Soc., 80, 3871 (1958)

    Article  Google Scholar 

  4. P. Glavic et J. Slivnik, Monats.Chem., 28, 1878 (1967)

    Google Scholar 

  5. A.A. Opalovskii et A.S. Nazarov, Izv.Sib.Otd.Akad.Nauk SSSR, Ser. Him., 3 (1964)

    Google Scholar 

  6. E.C. Gilbert et V.C. Bushnell, J.Am.Chem.Soc., 21, 2611 (1935)

    Article  Google Scholar 

  7. M.L. Kronberg et H. Haraker, J.Chem.Phys., 10, 309 (1942)

    Article  Google Scholar 

  8. J.C. Decius et D.P. Pearson, J.Am.Chem.Soc., 75, 2436 (1953)

    Article  Google Scholar 

  9. R.P. Seward, J.Phys.Chem., 66, 1125 (1962)

    Article  Google Scholar 

  10. W.R. McBride, R.A. Henry et S. Skolnik, Anal.Chem., 23, 890 (1951)

    Article  Google Scholar 

  11. W. Fresenius et G. Jander, Handbuch der Anal.Chem., Teil 3, Bd. Va, Springer Verlag, Berlin 1957

    Google Scholar 

  12. I. Filipovic et P. Sabioncello, Lab.Prirucnik, I/1, Tehn. knjiga, Zagreb 1962

    Google Scholar 

  13. G. Pietzka et P. Ehrlich, Angew.Chem., 62, 131 (1953)

    Article  Google Scholar 

  14. B.S. Brcic et coil., 3rd Int.Conf. on Peaceful Uses of At.Energy, Genève 1962, 11, P/702

    Google Scholar 

  15. J. Slivnik et B. Volavsek, Inorg.Fluorine Conf. (EUCHEM), Leicester, April 1967, NIJS Rept. R-548

    Google Scholar 

  16. L.G. Berg, Vvedenie v Termografiju, Izd. Nauka, Moskva 1969

    Google Scholar 

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© 1972 Springer Basel AG

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Milojević, M., Slivnik, J. (1972). La Préparation et Quelques Propriétés Thermiques des Mono- et Dihalogénures de L’Hydrazine. In: Wiedemann, H.G. (eds) Thermal Analysis. Birkhäuser, Basel. https://doi.org/10.1007/978-3-0348-5775-8_2

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  • DOI: https://doi.org/10.1007/978-3-0348-5775-8_2

  • Publisher Name: Birkhäuser, Basel

  • Print ISBN: 978-3-0348-5777-2

  • Online ISBN: 978-3-0348-5775-8

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