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Experimental Studies of Hydrothermal Fluid

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Part of the Springer Mineralogy book series (MINERAL)

Abstract

Structural features of pure water and aqueous solutions of the electrolytes NaCl, NaCO3 and Zn[NO3]2 were comprehensively studied using the X-ray diffraction, infrared absorption spectroscopy and Raman spectroscopy methods. Spectral in situ measurements of the test samples at pressures up to 1000 bar and temperatures 25–500 °C were performed with the use of the high-temperature high-pressure cells with transparent sapphire windows. It was experimentally determined a temperature and pressure impact on the infinite clusters of the hydrogen-bound molecules that is inherent to the liquid water. Therewith, the critical isotherm of the liquid water is defined as the conditional boundary of the percolation threshold below which the clusters of finite sizes can exist only. An evaluation of the effect of the electrolytes, dissolved in water, onto the hydrogen bonds and structural features of water of the aqueous solutions as well as determination of the polyatomic anions stability under high temperatures and pressures was also performed. The vibrational spectra of NaCl are not revealed a significant difference between the properties of the aqueous solution and pure water under the test conditions.

Keywords

Supercritical water Fluids Critical isotherm Percolation threshold Hydrogen bonds Correlation functions Molecular spectroscopy 

Notes

Acknowledgements

The study was support by the draft AAAA-A18-118020590149-0

References

  1. Akiya N, Savage PE (2002) Roles of water for chemical reaction in high temperature water. Chem Rev 102(8):2725–2750CrossRefGoogle Scholar
  2. Barlow SJ, Bondarenko GV, Gorbaty YE, Yamaguchi T, Poliakoff M (2002) An IR study of hydrogen bonding in liquid and supercritical alcohols. J Phys Chem A 106(43):10452–10460CrossRefGoogle Scholar
  3. Bermejo MD, Cocero MJ (2006) Supercritical water oxidation: a technical review. AlChE J 52(11):3933–3951CrossRefGoogle Scholar
  4. Bernal J, Fowler RH (1933) A theory of water and ionic solution with particular reference to hydrogen and hydroxyl ions. Chem Phys 1:515–548Google Scholar
  5. Bondarenko GV, Gorbaty YE (1997) In situ Raman spectroscopic study of sulphur-saturated water at 1000 bar between 200 and 500 °C. Geochim et Cosmochim Acta 61(7):1413–1420CrossRefGoogle Scholar
  6. Bondarenko GV, Gorbaty YE (2011) Hydrogen bonding in aqueous solution of NaClO4. Mol Phys 109(5):783–788CrossRefGoogle Scholar
  7. Bondarenko GV, Gorbaty YE, Okhulkov AV, Kalinichev AG (2006) Structure and hydrogen bonding in liquid and supercritical aqueous NaCl solutions at a pressure of 1000 bar and temperature up to 500 C: a comprehensive experimental and computational study. J Phys Chem A 110(11):4042–4052CrossRefGoogle Scholar
  8. Cabanas A, Poliakoff M (2001) The continuous hydrothermal synthesis of nano-particulate ferrites in near critical and supercritical water. J Mater Chem 11:1408–1416Google Scholar
  9. Driesner T (1996) The effect of pressure on deuterium-hydrogen fractionation in high temperature. Science 277:791–794Google Scholar
  10. Fedyaeva ON, Vostricov AA, Sokol MY, Fedorova NI (2013) Hydrogenezation of bitumen in supercritical water flow and the effect of zinc addition. Russ J Phys Chem B7(7):820–828Google Scholar
  11. Franck EU (1987) Fuids at high pressure and temperature. Pure Appl Chem 59(1):25–29CrossRefGoogle Scholar
  12. Giessen BC, Gordon GE (1968) X-ray diffraction new high-speed technique based on X-ray spectrography. Science 159(3818):973–975CrossRefGoogle Scholar
  13. Gorbaty YE (2007) Spectroscopic techniques for studying liquids and supercritical fluids at high temperature and pressure. Sverhcriticheskie fluidy Teoriya Pract 2(1):40–53Google Scholar
  14. Gorbaty YE, Bodarenko GV (1995) High-pressure high-temperature Raman cell for corrosive liquids. Rev Sci Instrum 66(8):4347–4349CrossRefGoogle Scholar
  15. Gorbaty YE, Bodarenko GV (1999) Experimental technique for quantitative IR studies of highly absorbing substances at high temperature and pressure. Appl Spectoscopy 53(8):908–913CrossRefGoogle Scholar
  16. Gorbaty YE, Bodarenko GV (2007) Water in supercritical state. Sverhcriticheskie fluidy Teoriya Pract 2(2):5–18Google Scholar
  17. Gorbaty YE, Bodarenko GV (2017) Transition of liquid water to the supercritical state. J Mol Liq 239:5–9CrossRefGoogle Scholar
  18. Gorbaty YE, Bondarenko GV (1998) The physical state of supercritical fluids. J Supercrit Fluids 14:1–8CrossRefGoogle Scholar
  19. Gorbaty YE, Kalinichev AG (1995) Hydrogen bonding in supercritical water. 1. Experimental results. J Phys Chem 99(15):5336–5340Google Scholar
  20. Gorbaty YE, Okhulkov AV (1994) High-pressure x-ray cell for studying the structure of fluids with the energy-dispersive technique. Rev Sci Instrum 65(7):2195–2198CrossRefGoogle Scholar
  21. Gorbaty YE, Bodarenko GV Venardow E, Barlow S, Garsia-Verdugo E, Poliakoff M (2004) Experimental spectroscopic high-temperature high-pressure techniques for studying liquids and supercritical fluids. Vibr Spectrosc 35:97–101Google Scholar
  22. Kalinashev AG, Churakov SV (1999) Size and topology of molecular clusters in supercritical water: a molecular dynamic simulation. Chem Phys Lett 302(5–6):411–417CrossRefGoogle Scholar
  23. Krishtal S, Kiselev M, Puhovski Y, Kerdcharoen T, Hannongbua S, Heinzinger K (2001) Study of hydrogen bond network in sub- and supercritical water by molecular dynamics simulation. Z Naturforsch 56a:579–584Google Scholar
  24. Okhulkov AV, Gorbaty YE (2001) The pair correlation functions of 1.1 M NaCl aqueous solution at constant pressure of 1000 bar in the temperature range 20–500 °C. J Mol Liq 93:39–42CrossRefGoogle Scholar
  25. Poliakoff M, King P (2001). Phenomenal fluids. Nature 412:125–125Google Scholar
  26. Purcarova E, Ciahotny K, Svab M, Skoblia S, Beno Z (2018) Supercritical water gasification of wastes from the paper industry. J Supercrit Fluids 135:130–136CrossRefGoogle Scholar
  27. Stanley HE, Teixeira J (1980) Interpretation of the unusual behavior of H2O and D2O at temperatures: test of a percolation model. J Chem Phys 73(7):3404–3422CrossRefGoogle Scholar
  28. Viswanathan R, Gupta RB (2003) Formation of zinc oxide nanoparticles in supercritical water. J Supercrit Fluids 27(2):187–193CrossRefGoogle Scholar
  29. Wang J, Zhang Y, Zheng W, Chou I-M, Pan Z (2018) Using Raman spectroscopy and a fused quartz tube reactor to study the oxidation of o-dichlorobenzene in hot compressed water. J Supercrit Fluids 140:380–386CrossRefGoogle Scholar
  30. Yukhnevich GV (1997) The mechanism of occurrence of cooperative properties in conjugate hydrogen-bonds. Spectrs Lett 30(5):901–914CrossRefGoogle Scholar

Copyright information

© The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Switzerland AG 2020

Authors and Affiliations

  1. 1.D.S. Korzhinskii Institute of Experimental Mineralogy, Russian Academy of ScienceChernogolovkaRussia

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