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Polyethylene Terephthalate

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Non-Intentionally Added Substances in PET-Bottled Mineral Water

Part of the book series: SpringerBriefs in Molecular Science ((BRIEFSCHEFO))

Abstract

Polyethylene terephthalate is the most widely used packaging material worldwide for bottled water and other non-alcoholic refreshment beverages. However, in recent years, concerns are rising about the safety of polyethylene terephthalate food packaging due to the possible migration of chemical compounds from polyethylene terephthalate bottles into the water contained in it which may pose health risk to consumers. In Europe, the EU Regulation No 10/2011 on food packaging materials establishes a positive list of the compounds authorised for use in plastic materials intended to come into contact with food and provides migration limits for several molecules. In the United States, the Food and Drug Administration regulates food contact substances, materials and articles. All existing regulations are published in the United States Code of Federal Regulation.

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Notes

  1. 1.

    Materials and articles, including active and intelligent materials and articles, shall be manufactured in compliance with good manufacturing practice so that, under normal or foreseeable conditions of use, they do not transfer their constituents to food in quantities which could endanger human health, or bring about an unacceptable change in the composition of the food, or bring about a deterioration in the organoleptic characteristics thereof (European Parliament and Council 2004, Article 3).

Abbreviations

MXD-6:

1,3-benzenedimethanamine

CHDM:

1,4-cyclohexanedimethanol

DEHP:

Bis(2-ethylhexyl) phthalate

BHET:

Bis-hydroxyethyl-terephthalate

BHT:

Butylated hydroxytoluene

CFR:

Code of Federal Regulations

DoC:

Declaration of Compliance

DBP:

Dibutyl phthalate

DEP:

Diethyl phthalate

DiisoBP:

Diisobutyl phthalate

DMP:

Dimethyl phthalate

DMT:

Dimethyl terephthalate

EA:

Environmental Assessment

EIS:

Environmental Impact Statement

EPA:

Environmental Protection Agency

EG:

Ethylene glycol

EFSA:

European Food Safety Authority

EU:

European Union

FONSI:

Finding of No Significant Impact

FDA:

Food and Drug Administration

FCM:

Food Contact Material

FCS:

Food Contact Substance

IBWA:

International Bottled Water Association

IPA:

Isophthalic acid

MTR:

Melt to Resin

MEG:

Monoethylene glycol

NIAS:

Non-Intentionally Added Substance

OML:

Overall Migration Limit

PhA:

Phthalic acid

PA:

Polyamide

PET:

Polyethylene terephthalate

PVC:

Polyvinyl chloride

PIA:

Purified isophthalic acid

SSP:

Solid-state polymerisation

SML:

Specific migration limit

TPA:

Terephthalic acid

Tg:

Transition temperature

UV:

Ultraviolet

U.S.:

United States of America

References

  • Andra SS, Makris KC, Shine JP (2011) Frequency of use controls chemical leaching from drinking water containers subject to disinfection. Water Res 45(20):6677–6687. https://doi.org/10.1016/j.watres.2011.10.001

    Article  CAS  PubMed  Google Scholar 

  • Bach C, Dauchy W, Severin I, Munoz J-F, Etiennne S, Chagnon M-C (2013) Effect of temperature on the release of intentionally and non-intentionally added substances from polyethylene terephthalate (PET) bottles into water: chemical analysis and potential toxicity. Food Chem 139(1–4):672–680. https://doi.org/10.1016/j.foodchem.2013.01.046

    Article  CAS  PubMed  Google Scholar 

  • Bhunia K, Sablani SS, Tang J, Rasco B (2013) Migration of chemical compounds from packaging polymers during microwave, conventional heat treatment, and storage. Compr Rev Food Sci Food Saf 12(5):523–545. https://doi.org/10.1111/1541-4337.12028

    Article  CAS  Google Scholar 

  • Bradley E, Coulier L (2007) Report FD 07/01: an investigation into the reaction and breakdown products from starting substances used to produce food contact plastics. Food Standards Agency, London

    Google Scholar 

  • Brody AL, Marsh KS (eds) (1997) The Wiley encyclopedia of packaging tecnology. Wiley, New York

    Google Scholar 

  • Chen DQ, Wang YZ, Hu XP, Wang DY, Qu MH, Yang B (2005) Flame-retardant and anti-dripping effects of a novel char-forming flame retardant for the treatment of poly (ethylene terephthalate) fabrics. Polym Degrad Stabil 88(2):349–356. https://doi.org/10.1016/j.polymdegradstab.2004.11.010

    Article  CAS  Google Scholar 

  • Commission European (2006) Commission Regulation (EC) No 2023/2006 of 22 December 2006 on good manufacturing practice for materials and articles intended to come into contact with food. Off J Eur Union L384:75–78

    Google Scholar 

  • Commission European (2009) Commission Regulation (EC) No 450/2009 of 29 May 2009 on active and intelligent materials and articles intended to come into contact with food. Off J Eur Union L135:3–11

    Google Scholar 

  • Commission European (2011a) Commission Regulation (EU) No 10/2011 of 14 January 2011 on plastic materials and articles intended to come into contact with food. Off J Eur Union L12:1–89

    Google Scholar 

  • Commission European (2011b) Commission Recommendation (EU) 2019/794 of 15 May 2019 on a coordinated control plan with a view to establishing the prevalence of certain substances migrating from materials and articles intended to come into contact with food. Off J Eur Union L48:28–32

    Google Scholar 

  • European Parliament and Council (2004) Regulation (EC) No 1935/2004 of the European Parliament and of the Council of 27 October 2004 on materials and articles intended to come into contact with food and repealing Directives 80/590/EEC and 89/109/EEC. Off J Eur Union L338:4–17

    Google Scholar 

  • FDA (1992) Points to consider for the use of recycled plastics in food packaging: chemistry considerations. U. S. Food and Drug Administration, Center for Food Safety and Applied Nutrition, Washington, DC

    Google Scholar 

  • Higuchi A, Yoon BO, Kaneko T, Hara M, Maekawa M, Nohmi T (2004) Separation of endocrine disruptors from aqueous solutions by pervaporation: dioctylphthalate and butylated hydroxytoluene in mineral water. J Appl Polymer Sci 94:1737–1742

    Article  CAS  Google Scholar 

  • Holland BJ, Hay JN (2002) Analysis of comonomer content and cyclic oligomers of poly(ethylene terephthalate). Polymer 43(6):1797–1804

    Article  CAS  Google Scholar 

  • IBWA (2009) Bottled water code practice. International Bottled Water Association (IBWA), Alexandria. https://www.bottledwater.org/files/IBWA%20Code%20of%20Practice%20Updated%202009%20Final_3.pdf. Accessed 21 Nov 2019

  • Kassouf A, Maalouly J, Chebib H, Rutledge DN, Ducruet V (2013) Chemometric tools to highlight non-intentionally added substances (NIAS) in polyethyleneterephthalate (PET). Talanta 115:928–937. https://doi.org/10.1016/j.talanta.2013.06.029

    Article  CAS  PubMed  Google Scholar 

  • Kattas L, Gastrock F, Levin I, Cacciatore A (2000) Plastics additives. In: Modern plastics handbook, 4th edn. McGraw-Hill, New York

    Google Scholar 

  • Montuori P, Jover E, Morgantini M, Bayona JM, Triassi M (2008) Assessing human exposure to phthalic acid and phthalate esters from mineral water stored in polyethylene terephthalate and glass bottles. Food Addit Contam Part A Chem Anal Control Expo Risk Assess 25(4):511–518. https://doi.org/10.1080/02652030701551800

    Article  CAS  PubMed  Google Scholar 

  • Pfaendner R (2013) Polymer additives. In: Saldìvar-Guerra E, Vivaldo-Lima E (eds) Handbook of polymer synthesis, characterization, and processing, 1st edn. Wiley, Hoboken. https://doi.org/10.1002/9781118480793.ch11

    Chapter  Google Scholar 

  • Plastics Insight (2016) Plastic insight global PET resin production capacity. Plastic Inside, Noida. https://www.plasticsinsight.com/global-pet-resin-production-capacity/. Accessed 21 Nov 2019

  • Sablani SS, Rahman MS (2007) Food packaging interaction. In: Rahmna MS (ed) Handbook of food preservation. CRC Press, Boca Raton

    Google Scholar 

  • Tadmor Z, Gogos CG (2006) Principles of polymer processing. Wiley Interscience, 2nd edn. Wiley, Hoboken

    Google Scholar 

  • Villain F, Coudane J, Vert M (1995) Thermal degradation of polyethlylene terephthalate: study of polymer stabilization. Polym Degrad Stab 49(3):393–397. https://doi.org/10.1016/0141-3910(95)00121-2

    Article  CAS  Google Scholar 

  • Webb H, Arnott J, Crawford R, Ivanova E (2013) Plastic degradation and its environmental implications with special reference to poly(ethylene terephthalate. Polymers 5(1):1–18. https://doi.org/10.3390/polym5010001

    Article  CAS  Google Scholar 

  • Welle F, Franz R (2011) Migration of antimony from PET bottles to beverages: determination of the activation energy of diffusion and migration modeling compared with literature data. Food Addit Contam Part A Chem Anal Control Expo Risk Assess 28(1):115–126. https://doi.org/10.1080/19440049.2010.530296

    Article  CAS  PubMed  Google Scholar 

  • Yilmaz MA, Temel H (2016) Screening of Polymer Additives in Drinking Water Stored in PET Bottles by UHPLC-ESI-IT-TOF MS. J Environ Sci Eng A 5:59–64. https://doi.org/10.17265/2162-5298/2016.02.001

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Medical, Surgical Sciences and Advanced Technologies “G.F. Ingrassia”, University of Catania, Catania, Italy

    Maria Anna Coniglio

  2. Police Headquarters, General Prevention & Public Aid Office, Catania, Italy

    Cristian Fioriglio

  3. Department of Biomedical and Dental Sciences and Morphofunctional Imaging, University of Messina, Messina, Italy

    Pasqualina Laganà

Authors
  1. Maria Anna Coniglio
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  2. Cristian Fioriglio
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  3. Pasqualina Laganà
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Correspondence to Maria Anna Coniglio .

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Coniglio, M.A., Fioriglio, C., Laganà, P. (2020). Polyethylene Terephthalate. In: Non-Intentionally Added Substances in PET-Bottled Mineral Water. SpringerBriefs in Molecular Science(). Springer, Cham. https://doi.org/10.1007/978-3-030-39134-8_3

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