Abstract
Besides hybrid organic-inorganic sol-gel materials, surfactant-templated sol-gel materials constitute a family of solids with very original textural and structural characteristics, quite interesting for some applications. In this chapter, the main properties of surfactant solutions are first described, in particular their various micellar organizations and the way they were applied to design ordered mesoporous gels. Their chemical composition mainly concerned aluminosilicate gels in a first step, which are described in more details. But since then it was extended to other compositions which are briefly summarized. Some copolymers also present interesting amphiphilic characteristics, due to different functionalities along their polymeric chain. Recent developments in their use as templating substrates are also summarized.
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References
I.A. Aksay, M. Trau, S. Manne, I. Honma, N. Yao, L. Zhou, P. Fenter, P.M. Eisenberger, S.M. Gruner, Science 273, 892–898 (1996)
P.C.A. Alberius, K.L. Frindell, R.C. Hayward, E.J. Kramer, G.D. Stucky, B.F. Chmelka, Chem. Mater. 14, 3284–3294 (2002)
D.M. Antonelli, J.Y. Ying, Chem. Int. Ed. EngI. 34, 2014–2017 (1995)
A. Arafat, J.C. Jansen, A.R. Ebaid, H. van Bekkum, Zeolites 13, 162–165 (1993)
G.S. Attard, J.C. Glyde, C.G. Göltner, Nature 378, 366–368 (1995)
S.A. Bagshaw, T.J. Pinavaia, Angew. Chem. Int. Ed. EngI. 35, 1102–1105 (1996)
S.A. Bagshaw, S.A. Prouzet, T.J. Pinnavaia, Science 269, 1242–1244 (1995)
M.H. Bartl, B.J. Scott, H.C. Huang, G. Wirnsberger, A. Popitsch, B.F. Chmelka, G.D. Stucky, Chem. Commun. (21), 2474–2475 (2002)
E.A. Barringer, N. Jubb, B. Fegley, R.L. Pober, H.K. Bowen, in Ultrastructure Processing of Ceramics, Glasses and Composites, ed. by L.L. Hench, D.R. Ulrich, Wiley, New York, 315–333 (1984)
J.S. Beck, J.C. Vartulli, W.J. Roth, M.E. Leonowicz, C.T. Kresge, K.D. Schmitt, C.T.-W. Chu, D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins, J.L. Schlenker, J. Am. Chem. Soc. 114, 10834–10843 (1992)
J.S. Beck, J.C. Vartulli, G.J. Kennedy, C.T. Kresge, W.J. Roth, S.E. Schramm, Chem. Mater. 6, 1816–1821 (1994)
A.M. Bellocq, D. Bourdon, B. Lemanceau, J. Colloid Interface Sci. 79, 419–431 (1981)
A. Berthod, J. Chim. Phys. 80, 407–424 (1983)
D. Brandhuber, H. Peterlik, N. Huesing, Small 2, 503–506 (2006)
C.J. Brinker, Y. Lu, A. Sellinger, H. Fan, Adv. Mater. 11, 579–585 (1999)
S.W. Cao, Y.J. Zhu, M.Y. Ma, L. Li, L. Zhang, J. Phys. Chem. C. 112, 1851–1856 (2008)
M. Chatterjee, M.K. Naskar, J. Am. Ceram. Soc. 89, 1443–1446 (2006)
C.Y. Chen, S.L. Burkett, H.X. Li, M.E. Davis, Micropor. Mater. 2, 27–34 (1993)
E.-B. Cho, K. Char, Chem. Mater. 16, 270–275 (2004)
Y.S. Cho, G.R. Yi, S.H. Kim, D.J. Pine, S.M. Yang, Chem. Mater. 17, 5006–5013 (2005)
E.-B. Cho, D. Kim, J. Gorka, M. Jaroniec, J. Mater. Chem. 19, 2076–2081 (2009)
E.-B. Cho, D. Kim, M. Mandal, C.A. Gunathilake, M. Jaroniec, J. Phys. Chem. C 116, 16023–16029 (2012)
U. Ciesla, D. Demuth, R. Leon, P. Petroff, G. Stucky, K. Unger, F. Schüth, J. Chem. Soc. Chem. Commun. (11), 1387–1388 (1994)
A. Corma, Chem. Rev. 97, 2373–2420 (1997)
A. Corma, M.T. Navarro, J. Perez-Pariente, J. Chem. Soc. Chem. Commun. (2), 147–148 (1994)
Y.H. Deng, C.C. Wang, J.H. Hu, W.L. Yang, S.K. Fu, Colloid Surf. A 262, 87–93 (2005)
K.J. Edler, Formation of ordered mesoporous thin films through templating, in Handbook of Sol-Gel Science and Technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer, Cham, 2016)
P. Ekwall, L. Mandell, K. Fontell, Mol. Cryst. Liq. 8, 157–213 (1969)
J. Esquena, R. Pons, N. Azemar, J. Caelles, C. Solans, Colloid Surf. A 123–124, 575–586 (1997)
Y. Goto, S. Inagaki, Chem. Commun. 2, 2410–2411 (2002)
W.C. Griffin, J. Soc. Cosmet. Chem. 5, 249–256 (1954)
R.M. Grudzien, S. Pikus, M. Jaroniec, J. Phys. Chem. B 110, 2972–2975 (2006)
X. Guo, G. Hao, Y. Xie, W. Cai, H. Yang, J. Sol-Gel. Sci. Technol. 76, 651–657 (2015)
N. Hao, Y. Yang, H. Wang, P.A. Webley, D. Zhao, J. Colloid Interface Sci. 346, 429–435 (2010)
T.T. Hao, J.Y. Shi, T.Y. Zhuang, W.D. Wang, F.C. Li, W. Wang, RSC Adv. 2, 2010–2014 (2012)
P.C. Hiemenz, Principles of Colloid and Surface Science (Marcel Dekker, New York, 1976)
P.C. Hiemenz, R. Rajagopalan, Principles of Colloid and Surface Chemistry, revised and expanded 3rd edn. (CRC Press, Boca Raton, 1997), pp. 672
L.-C. Hu, K.J. Shea, Chem. Soc. Rev. 40, 688–695 (2011)
M.J. Hudson, J.A. Knowles, J. Mater. Chem. 6, 89–95 (1996)
Q. Huo, D.I. Margolese, U. Ciesla, P. Feng, P. Sieger, R. Leon, P. Petroff, F. Schüth, G.D. Stucky, Nature 368, 317–321 (1994)
S. Inagaki, Y. Fukushima, K. Kuroda, Stud. Surf. Sci. Catal. 84, 125–132 (1994)
S. Inagaki, S. Guan, T. Ohsuna, O. Terasaki, Nature 416(6878), 304–307 (2002)
J.N. Israelachvili, Thermodynamic and geometric aspects of amphiphile aggregation into micelles, vesicles and bilayers and the interactions between them, in Physics of Amphiphiles: Micelles, Vesicles and Microemulsions, ed. by X. C. Corso, (Soc. Italiana di Fisica, Bologna, 1985), pp. 24–58
J.N. Israelachvili, Surfactants in Solution (Plenum, New York, 1987)
J.N. Israelachvili, D.L. Mitchell, B.W. Ninham, J. Chem. Soc. Faraday Trans. 2(72), 1525–1568 (1976)
T. Jiang, B. Zhu, S.-J. Ding, Z. Fan, D.W. Zhang, J. Mater. Chem. C 2, 6502–6510 (2014)
S.K. Jones, J.G. Winter, Phys. Med. Biol. 46, 385–398 (2001)
K. Kanamori, K. Nakanishi, Chem. Soc. Rev. 40, 754–770 (2011)
K. Kanamori, K. Nakanishi, T. Hanada, Soft Matter 5, 3106–3113 (2009)
K. Kanamori, Y. Kodera, G. Hayase, K. Nakanishi, T. Hanada, J. Colloid Interface Sci. 357, 336–344 (2011)
M.P. Kapoor, N. Setoyama, Q. Yang, M. Ohashi, S. Inagaki, Langmuir 21, 443–449 (2005)
M. Kawashita, T. Miyazaki, Microparticles preparation using water-in-oil emulsion, in Handbook of Sol-Gel Science and Technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer, Cham, 2016)
M. Kawashita, M. Tanaka, T. Kokubo, Y. Inoue, T. Yao, S. Hamada, T. Shinjo, Biomaterials. 26, 2231–2238 (2005)
M. Kawashita, Y. Tanaka, S. Ueno, G. Liu, Z. Li, T. Miyazaki, Mater. Sci. Eng. C 50, 317–323 (2015)
A. Kim, P. Bruinsma, Y. Chen, L.Q. Wang, J. Liu, J. Chem. Soc. Chem. Commun. (2), 161–162 (1997)
L. Kong, C. Zhang, J. Wang, W. Qiao, L. Ling, D. Long, Sci. Rep. 6, 21177 (2016)
F. Krafft, H. Wiglow, Ber. Dtsch. Chem. Ges. 28, 2566–2573 (1895)
C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartulli, J.S. Beck, Nature 359, 710–712 (1992)
D. Lavy, M. Zayat, The sol-gel handbook, vol 1, synthesis and processing. Weinheim, Wiley-VCH (2015)
M.H. Lee, C.Y. Tai, C.H. Lu, J. Eur. Ceram. Soc. 19, 2593–2603 (1999)
W. Li, X. Sha, W. Dong, Z. Wang, Chem. Commun. 20, 2434–2435 (2002)
Z. Li, M. Kawashita, N. Araki, M. Mitsumori, M. Hiraoka, M. Doi, Biomed. Mater. 5, 065010 (2010)
Z. Li, M. Kawashita, M. Doi, J. Ceram. Soc. Jpn. 118, 467–473 (2010b)
Z. Li, M. Kawashita, T. Kudo, H. Kanetaka, J. Mater. Sci. Mater. Med. 23, 2461–2469 (2012)
Y. Liang, M. Hanzlik, R. Anwander, J. Mater. Chem. 15, 3919–3928 (2005)
M.H. Lim, A. Stein, Chem. Mater. 11, 3285–3295 (1999)
M.H. Lim, C.F. Blanford, A. Stein, J. Am. Chem. Soc. 119, 4090–4091 (1997)
D. Lin, L. Hu, H. You, S.H. Tolbert, D.A. Loy, J. Non-Cryst. Solids 406, 139–143 (2014)
S. Lin, L. Shi, H. Yoshida, M. Li, X. Zou, J. Solid. State. Chem. 199, 15–20 (2013)
B. Lindman, H. Wennerstrom, Top. Curr. Chem. 87, 1–87 (1980)
J.G. Liu, D.L. Wilcox, J. Mater. Res. 10, 84–94 (1995)
N. Liu, R.A. Assink, C.J. Brinker, Chem. Commun. (9), 370–371 (2003)
G. Liu, M. Kawashita, Z. Li, T. Miyazaki, H. Kanetaka, J. Sol-Gel Sci. Technol. 5, 90–97 (2015)
D.A. Loy, Mesoporous polysilsesquioxanes: preparation, properties, and applications, in Handbook of Sol-Gel Science and Technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer, Cham, 2016)
D.A. Loy, B.M. Baugher, C.R. Baugher, D.A. Schneider, K. Rahimian, Chem. Mater. 12, 3624–3632 (2000)
Y. Lu, H. Fan, N. Doke, D.A. Loy, R.A. Assink, D.A. LaVan, C.J. Brinker, J. Am. Chem. Soc. 122, 5258–5261 (2000)
N. Lufimpadio, J.B. Nagy, E.G. Derouane, Preparation of colloidal iron boride particles in the CTAB-n hexanol-water reversed micellar system, in Surfactants in Solution, ed. by K. L. Mittal, B. Lindman, vol. 3, (Plenum Press, New York, 1984), pp. 1483–1497
A.S. Manchanda, M. Kruk, Micropor. Mesopor. Mater. 222, 153–159 (2016)
M. Mandal, M. Kruk, J. Phys. Chem. C 114, 20091–20,099 (2010)
K. L. Mittal (ed.), Micellization, Solubilization and Microemulsions, vol 2 (Plenum Press, New York, 1979)
K. L. Mittal, E. J. Fendler (eds.), Solution Behavior of Surfactants, vol 2 (Plenum Press, New York, 1982)
H. Miyata, K. Kuroda, Chem. Mater. 11, 1609–1614 (1999)
H. Miyata, K. Kuroda, Chem. Mater. 12, 49–54 (2000)
T. Miyazaki, S. Anan, E. Ishida, M. Kawashita, J. Mater. Sci. Mater. Med. 24, 1125–1129 (2013)
T. Miyazaki, T. Kai, E. Ishida, M. Kawashita, M. Hiraoka, J. Ceram. Soc. Jpn. 118, 479–482 (2010)
T. Miyazaki, A. Miyaoka, E. Ishida, Z. Li, M. Kawashita, M. Hiraoka, Mater. Sci. Eng. C. 32, 692–696 (2012)
T. Miyazaki, T. Suda, Y. Shirosaki, M. Kawashita, J. Med. Biol. Eng. 34, 14–17 (2014)
N. Mizoshita, T. Tani, S. Inagaki, Chem. Soc. Rev. 40, 789–800 (2011)
K. Moller, T. Bein, R.X. Fischer, Chem. Mater. 11, 665–673 (1999)
A. Monnier, F. Schüth, Q. Huo, D. Kumar, D. Margolese, R.S. Maxwell, G.D. Stucky, M. Krishnamurty, P. Petroff, A. Firouzi, M. Janicke, B.F. Chmelka, Science 261, 1299–1303 (1993)
A.L. Morel, S.I. Nikitenko, K. Gionnet, A. Wattiaux, J. Lai-Kee-Him, C. Labrugere, B. Chevalier, G. Deleris, C. Petibois, A. Brisson, M. Simonoff, ACS Nano. (5), 847–856 (2008)
P. Mukerjee, in Solution Chemistry of Surfactants, ed. by K. L. Mittal, vol. 1, (Plenum Press, New York, 1979), p. 153
A. Mushiake, K. Kanamori, K. Nakanishi, Int. J. Polym. Sci. 2012, 1 (2012)
J.B. Nagy, A. Gourgue, E.G. Derouane, Stud. Surf. Sci. Catal. 16, 193–202 (1983)
K. Nakanishi, K. Kanamori, J. Mater. Chem. 15, 3776–3786 (2005)
M. Ogawa, J. Am. Chem. Soc. 116, 7941–7942 (1994)
S.S. Park, B. An, C.-S. Ha, Micropor. Mesopor. Mater. 111, 367–378 (2008)
R. Perron, Physicochimie des composes amphiphiles (Editions du CNRS, Paris, 1979)
J. Polleux, M. Rasp, I. Louban, N. Plath, A. Feldhoff, J.P. Spatz, ACS Nano. 5, 6355–6364 (2011)
V. Rebbin, A. Rothkirch, U. Vainio, S.S. Funari, J. Phys. Conf. Ser. 351, 012011–012017 (2012)
l. D. Robb (ed.), Microemulsions (Plenum Press, New York, 1982)
R. Ryoo, J.M. Kim, C.H. Ko, C.H. Shin, J. Phys. Chem. 100, 17718–17,721 (1996)
C. Sanchez, M. In, J. Non Cryst. Solids 147/148, 1–12 (1992)
A. Sayari, S. Hamoudi, Y. Yang, I.L. Moudrakovski, J.R. Ripmeester, Chem. Mater. 12, 3857–3863 (2000)
R. Schmidt, H. Junggreen, M. Stöcker, O.H. Ellestad, J. Chem. Soc. Chem. Commun., 875–876 (1996)
B. Siladitya, M. Chatterjee, D. Ganguli, J. Sol-Gel. Sci. Technol. 15, 271–277 (1999)
R.K. Singh, A. Garg, R. Bandyopadhyaya, B.K. Mishra, Colloid Surf. A 310, 39–45 (2007)
D. Skoda, A. Styskalik, Z. Moravec, P. Bezdicka, C.E. Barnes, J. Pinkas, J. Sol-Gel Sci. Technol. 74, 810–822 (2015a)
D. Skoda, A. Styskalik, Z. Moravec, P. Bezdicka, J. Pinkas, J. Mater. Sci. 50, 3371–3382 (2015b)
A. Stein, B.J. Melde, R.C. Schroden, Adv. Mater. 12, 1403–1419 (2000)
T. Tago, T. Hatsuta, K. Miyajima, M. Kishida, S. Tashiro, K. Wakabayashi, J. Am. Ceram. Soc. 85, 2188–2194 (2002)
B. Tan, S.E. Rankin, J. Non-Cryst. Solids 352, 5453–5462 (2006)
P.T. Tanev, M. Chibwe, T.J. Pinnavaia, Nature 368, 321–323 (1994)
N. Ulagappan, C.N.R. Rao, J. Chem. Soc. Chem. Commun., 2759–2760 (1996)
N. Ulagappan, N. Battaram, U.N. Raju, C.N.R. Rao, J. Chem. Soc. Chem. Commun., 2243–2244 (1996)
P. Van Der Voort, D. Esquivel, E. De Canck, F. Goethals, I. Van Driessche, F.J. Romero-Salguero, Chem. Soc. Rev. 42, 3913–3955 (2013)
J.C. Vartulli, K.D. Schmitt, C.T. Kresge, W.J. Roth, M.E. Leonowicz, S.B. McCullen, S.D. Hellring, J.S. Beek, I.L. Schlenker, D.H. OIson, E.W. Sheppard, Stud. Surf. Sci. Catal. 84, 53–60 (1994)
Y.Q. Wang, C.M. Yang, B. Zibrowius, B. Spliethoff, M. Linden, F. Schueth, Chem. Mater. 15, 5029–5035 (2003)
W. Wei, G.H. Ma, G. Hu, D. Yu, T. Mcleish, Z.G. Su, Z.Y. Shen, J. Am. Chem. Soc. 130, 15808–15810 (2008)
P.A. Winsor, Solvent Properties of Amphiphilic Molecules (Butterworths, London, 1954)
L.Y. Xia, Y.C. Hu, M.Z. Rong, Y.J. Liang, RSC Adv. 4, 168–174 (2014)
Z. Xie, E.J. Henderson, O. Dag, W. Wang, J.E. Lofgreen, C. Kubel, T. Scherer, P.M. Brodersen, Z.-Z. Gu, G.A. Ozin, J. Am. Chem. Soc. 133, 5094–5102 (2011)
J. Xu, H.B. Yang, W.Y. Fu, K. Du, Y.M. Sui, J.J. Chen, Y. Zeng, M.H. Li, G. Zou, J. Magn. Magn. Mater. 309, 307–311 (2007)
M. Yada, M. Machida, T. Kijima, J. Chem. Soc. Chem. Commun., 769–770 (1996)
H. Yamashita, K. Nozaki, K. Toshinari, T. Mima, T.S. Maekawa, J. Ceram. Soc. Jpn. (in Japanese) 106, 1184–1189 (1998)
H. Yamashita, Y. Ogawa, T. Maekawa, Bunseki Kagaku (in Japanese) 56, 511–514 (2007)
H. Yang, A. Kuperman, N. Coombs, S. Mamiche-Mara, G.A. Ozin, Nature 379, 703–705 (1996)
H. Yang, N. Coombs, O. Dag, I. Sokolov, G.A. Ozin, J. Mater. Chem. 7, 1755–1761 (1997)
H. Yang, Y. Xie, G. Hao, W. Cai, X. Guo, New. J. Chem. 40, 589–595 (2016)
R. Zana, J. Frash, M. Soulard, B. Lebeau, J. Patarin, Langmuir 15, 2603–2606 (1999)
W. Zhang, T. Pinnavaia, Catal. Lett. 38, 261–265 (1996)
D. Zhao, D. Goldfarb, J. Chem. Soc. Chem. Commun., 875–876 (1995)
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Pierre, A.C. (2020). Surfactant-Templated Sol-Gel Materials. In: Introduction to Sol-Gel Processing. Springer, Cham. https://doi.org/10.1007/978-3-030-38144-8_11
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