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Hybrid Organic–Inorganic and Composite Materials

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Introduction to Sol-Gel Processing

Abstract

This chapter is devoted to the relatively recent sol-gel-derived materials, characterized by a complex structure or texture. These comprise hybrid organic–inorganic sol-gel materials and the composite materials in which the matrix is made by sol-gel processing. The various types of structures of hybrid materials and their possible classification are first summarized. Typical examples are next described, made with silica or other inorganic components as well as various organic components, including the carbon nanotube-based aerogel composites and also various types of hybrid architectures. A few original properties of these new materials, essentially mechanical, are then outlined. Composite materials are also briefly introduced, and their main difference with hybrid gels is summarized.

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References

  • A. Aboulaich, O. Lorret, B. Boury, P.H. Mutin, Chem. Mater. 21, 2577–2579 (2009)

    Article  CAS  Google Scholar 

  • D. Adler, H.K. Henisch, N.F. Mott, Rev. Mod. Phys. 50, 209–220 (1978)

    Article  CAS  Google Scholar 

  • S. Amberg-Schwab, Functional barrier coatings on the basis of hybrid polymers, in Handbook of Sol-Gel Science and Technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer International Publishing, Cham, 2016)

    Google Scholar 

  • M. Arima, M. Kakihana, Y. Nakamura, M. Yashima, M. Yoshimura, J. Am. Ceram. Soc. 79, 2847–2856 (1996)

    Article  CAS  Google Scholar 

  • A. Arkhireeva, J.N. Hay, J.M. Lane, M. Manzano, H. Masters, W. Oware, S.J. Shaw, J. Sol-Gel Sci. Technol. 31, 31–36 (2004)

    Article  CAS  Google Scholar 

  • T.S. Asche, M. Duderstaedt, P. Behrens, A.M. Schneider, Atomistic simulation of sol–gel-derived hybrid materials, in Handbook of sol-gel science and technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer International Publishing, Cham, 2016)

    Google Scholar 

  • D. Avnir, D. Levy, R. Reisfeld, J. Phys. Chem. 88, 5956 (1984)

    Article  CAS  Google Scholar 

  • T.F. Baumann et al., Adv. Mater. 17, 1546–1548 (2005)

    Article  CAS  Google Scholar 

  • A. Belamie, B. Alonso, Hybrid nanocomposites through colloidal interactions between crystalline polysaccharide nanoparticles and oxide precursors, in Handbook of sol-gel science and technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer International Publishing, Cham, 2016)

    Google Scholar 

  • F. Ben, B. Boury, R.J.P. Corriu, V. Le Strat, Chem. Mater. 12, 3249–3252 (2000)

    Article  CAS  Google Scholar 

  • A. Berkefeld, M. Heyer, B. Milow, J. Sol-Gel Sci. Technol. 84, 486–495 (2017)

    Article  CAS  Google Scholar 

  • S. Berthon-Fabry, C. Hildenbrand, P. Ilbizian, Eur. Polym. J. 78, 25–37 (2016)

    Article  CAS  Google Scholar 

  • S. Berthon-Fabry, C. Hildenbrand, P. Ilbizian, Eur. Polym. J. 93, 403–416 (2017)

    Article  CAS  Google Scholar 

  • F. Blanchard, B. Pommier, J.P. Reymond, S.J. Teichner, Stud. Surf. Sci. Catal. 16, 395–407 (1983)

    Article  CAS  Google Scholar 

  • D.J. Boday, R.J. Stover, B. Muriithi, M.W. Keller, J.T. Wertz, K.A. deFriend Obrey, D.A. Loy, ACS Appl. Mater. Interfaces 1, 1364–1369 (2009)

    Article  CAS  Google Scholar 

  • L. Brigo, G. Della Giustina, G. Brusatin, Hybrid materials for micro- and nanofabrication, in Handbook of sol-gel science and technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer International Publishing, Cham, 2016)

    Google Scholar 

  • M. J. Buehler, P. Rabu, A. Taubert (eds.), Advanced hybrid materials: design and applications (Wiley-VCH, Weinheim, 2012)

    Google Scholar 

  • R. Campostrini, M. Ischia, G. Carturan, L. Armelao, J. Sol-Gel Sci. Technol. 23, 107–117 (2002)

    Article  CAS  Google Scholar 

  • S. Cao, N. Yao, K.L. Yeung, J. Sol-Gel Sci. Technol. 46, 323–333 (2008)

    Article  CAS  Google Scholar 

  • M. Carraro, S. Gross, Materials 7, 3956–3989 (2014)

    Article  CAS  Google Scholar 

  • G. Carturan, G. Facchini, V. Gottardi, M. Guglielmi, G. Navazio, J. Non-Cryst. Solids 48, 219–226 (1982)

    Article  CAS  Google Scholar 

  • M. Catauro, F. Papale, F. Bollino, M. Gallicchio, S. Pacifico, Mater. Sci. Eng. C 40, 253–259 (2014)

    Article  CAS  Google Scholar 

  • K. Chen, Z. Bao, A. Du, X. Zhu, J. Shen, G. Wu, Z. Zhang, B. Zhou, J. Sol-Gel Technol. 62, 294–303 (2012)

    Article  CAS  Google Scholar 

  • S.F. Chin, A.N.B. Romainor, S.C. Pang, Mater. Lett. 115, 241–243 (2014)

    Article  CAS  Google Scholar 

  • J.-H. Choy, J.S. Yoo, J.C. Park, S.G. Kang, W. Kim, S.G. Kang, Physica C 185–189, 511–512 (1991)

    Article  Google Scholar 

  • A. Corma, M.T. Navarro, L. Perez-Pariente, J. Chem. Soc. Chem. Commun. 1994, 147–148 (1994)

    Article  Google Scholar 

  • K. Deguchi, K. Tsuru, T. Hayashi, M. Takaishi, M. Nagahara, S. Nagotani, Y. Sehara, G. Jin, H. Zhang, S. Hayakawa, M. Shoji, M. Miyazaki, A. Osaka, N.-H. Huh, K. Abe, J. Cereb. Blood Flow Metab. 26, 1263–1273 (2006)

    Article  CAS  Google Scholar 

  • A. Demilecamps, G. Reichenauer, A. Rigacci, T. Budtova, Cellulose 21, 2625–2636 (2014)

    Article  CAS  Google Scholar 

  • A. Demilecamps, C. Beauger, C. Hildenbrand, A. Rigacci, T. Budtova, Carbohydydr. Polym. 122, 293–300 (2015)

    Article  CAS  Google Scholar 

  • A. Demilecamps, M. Alves, A. Rigacci, G. Reichenauer, T. Budtova, J. Non-Cryst. Solids 452, 259–265 (2016)

    Article  CAS  Google Scholar 

  • K.L. Ding et al., J. Mater. Chem. 19, 3725–3731 (2009)

    Article  CAS  Google Scholar 

  • S. Dire, F. Babonneau, G. Carturan, J. Livage, J. Non-Cryst. Solids 147/148, 62–66 (1992)

    Article  Google Scholar 

  • S. Dire, F. Babonneau, C. Sanchez, J. Livage, J. Mater. Chem. 2, 239–244 (1992b)

    Article  CAS  Google Scholar 

  • X.-H. Dong, B. Ni, M. Huang, C.-H. Hsu, Z. Chen, Z. Lin, et al., Macromolecules 48, 7172–7179 (2015)

    Article  CAS  Google Scholar 

  • P. Dou, Z. Liu, Z.Z. Cao, J. Zheng, C. Wang, X.H. Xu, J. Mater. Sci. 51, 4274–4282 (2016)

    Article  CAS  Google Scholar 

  • A. Douy, P. Odier, Mater. Res. Bull. 24, 1119–1126 (1989)

    Article  CAS  Google Scholar 

  • C. Durucan, G. Carlo, C.G. Pantano, Hybrid sol/gels for DNA arrays and other lab-on-a-chip applications, in Handbook of sol-gel science and technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer International Publishing, Cham, 2016)

    Google Scholar 

  • C.A. Dyke, J.M. Tour, J. Phys. Chem. A 108, 11151–11159 (2004)

    Article  CAS  Google Scholar 

  • J.E. ten Elshof, Hybrid materials for molecular sieves, in Handbook of Sol-Gel Science and Technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer International Publishing, Cham, 2016)

    Google Scholar 

  • Q. Fu, C.G. Lu, J. Liu, Nano Lett. 2, 329–332 (2002)

    Article  CAS  Google Scholar 

  • G. Garnweitner, L.M. Goldenberg, O.V. Sakhno, M. Antonietti, M. Niederberger, J. Stumpe, Small 3, 1626–1632 (2007)

    Article  CAS  Google Scholar 

  • F.J. Gator, P. Odier, M. Gervais, J. Choisnet, P. Mond, Physica C 218, 429–436 (1993)

    Article  Google Scholar 

  • R. Gavillon, T. Budtova, Biomacromolecules 9, 269–277 (2008)

    Article  CAS  Google Scholar 

  • N. Gharbi, C. Sanchez, J. Livage, L. Lemerle, L. Nejem, J. Lefebvre, Inorg. Chem. 21, 2758–2765 (1982)

    Article  CAS  Google Scholar 

  • P. Gomez-Romero, C. Sanchez (eds.), Functional hybrid materials (Wiley-VCH, Weinheim, 2004)

    Google Scholar 

  • M.A. Gülgün, O.O. Popoola, W.M. Kriven, J. Mater. Res. 10, 1565–1571 (1995)

    Article  Google Scholar 

  • T.S. Haddad, J.D. Lichtenhan, Macromolecules 29, 7302–7304 (1996)

    Article  CAS  Google Scholar 

  • L.L. Hench, J.K. West, B.F. Zhu, R. Ochoa, Proc. SPIE 1328, 230–240 (1990)

    Article  CAS  Google Scholar 

  • K. Hernadi et al., Acta Mater. 51, 1447–1452 (2003)

    Article  CAS  Google Scholar 

  • H.-H. Huang, B. Orler, G.L. Wilkes, Polym. Bull. 14, 557–564 (1985)

    Article  CAS  Google Scholar 

  • S. Illescas, A. Arostegui, High Perform Polym. 26, 307–318 (2014)

    Article  CAS  Google Scholar 

  • P. Innocenzi, G. Brusatin, M. Guglielmi, F. Babonneau, Structural characterization of hybrid organic–inorganic materials, in Handbook of sol-gel science and technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer International Publishing, Cham, 2016)

    Google Scholar 

  • S. Iswar, G. Snellings, S. Zhao, R. Erni, K. Bahk, J. Wang, M. Lattuada, M. Koebel, W. Malfait, Acta Mater. 147, 322–328 (2018)

    Article  CAS  Google Scholar 

  • J. Jaxel, G. Markevicius, A. Rigacci, T. Budtova, Compos. A Appl. Sci. Manuf. 103, 113–121 (2017)

    Article  CAS  Google Scholar 

  • A.R. Jennings, S.T. Iacono, J.M. Mabry, Polyhedral silsesquioxanes, in Handbook of sol-gel science and technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer, Cham, 2016)

    Google Scholar 

  • J.Y. Ji, X.H. Yu, P. Cheng, Q. Zhang, F.P. Du, L. Li, S.M. Shang, J. Macromol. Sci. B 54, 1122–1131 (2015)

    Article  CAS  Google Scholar 

  • J.R. Jones, Acta Biomater. 9, 4457–4486 (2013). and (2015) 23: 553–582

    Article  CAS  Google Scholar 

  • P. Judeinstein, C. Sanchez, J. Mater. Chem. 6, 511–525 (1996)

    Article  CAS  Google Scholar 

  • M. Kakihana, J. Sol-Gel Sci. Technol. 6, 7–55 (1996)

    Article  CAS  Google Scholar 

  • M. Kakihana, M. Yoshimura, Bull. Chem. Soc. Jpn. 72, 1427–1443 (1999)

    Article  CAS  Google Scholar 

  • M. Kakihana, T. Okubo, M. Arima, O. Uchiyama, M. Yashima, M. Yoshimura, Y. Nakamura, Chem. Mater. 9, 451–456 (1997)

    Article  CAS  Google Scholar 

  • K. Kanamori, Hybrid aerogels, in Handbook of Sol-Gel Science and Technology., ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer International Publishing, Cham, 2016)

    Google Scholar 

  • P. Karen, A. Kjekshus, J. Am. Ceram. Soc. 77, 547–552 (1994)

    Article  CAS  Google Scholar 

  • M. Kato, A. Sakuma, T. Noji, Y. Koike, Physica C 266, 109–114 (1996)

    Article  CAS  Google Scholar 

  • E. Kemnitz, Fluorolytic sol-gel processes, in Handbook of sol-gel science and technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer, Cham, 2016)

    Google Scholar 

  • K.K. Kim, K.Y. Jang, J. Am. Ceram. Soc. 74, 1987–1992 (1991)

    Article  CAS  Google Scholar 

  • M. Kim, M. Kobayashi, H. Kato, M. Kakihana, J. Ceram. Soc. Jpn. 122, 626–629 (2014)

    Article  CAS  Google Scholar 

  • M. Kobayashi, H. Kato, M. Kakihana, Water–dispersed silicates and water–soluble phosphates, and their use in sol–gel synthesis of silicate-and phosphate-based materials, in Handbook of sol-gel science and technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer, 2016)

    Google Scholar 

  • M.Y. Koh, C. Ohtsuki, T. Miyazaki, J. Biomater. Appl. 25, 581–594 (2011)

    Article  CAS  Google Scholar 

  • D. Koziej, F. Fischer, N. Kranzlin, W.R. Caseri, M. Niederberger, ACS Appl. Mater. Interfaces 1, 1097–1104 (2009)

    Article  CAS  Google Scholar 

  • J. Kramer, R.K. Prud’homme, P. Wiltzius, J. Colloid Interface Sci. 118, 294–296 (1987)

    Article  CAS  Google Scholar 

  • S.O. Kucheyev et al., J. Electron Spectrosc. Relat. Phenom. 144, 609–612 (2005)

    Article  CAS  Google Scholar 

  • J. Kuhn, T. Gleissner, M.C. Aruini-Schuster, S. Korder, J. Fricke, J. Non-Cryst. Solids 186, 291–295 (1995)

    Article  CAS  Google Scholar 

  • M.M. Kulkarni, R. Bandyopadhyaya, B. Bhattacharya, A. Sharma, Acta Mater. 54, 5231–5240 (2006)

    Article  CAS  Google Scholar 

  • W.J. Lackey, R.E. Blanco, A.L. Lotts, Nucl. Technol. 49, 321–324 (1980)

    Article  CAS  Google Scholar 

  • C.J.T. Landry, B.K. Coltrain, J.A. Wesson, N. Zambulyadis, Polymer 33, 1496–1506 (1992)

    Article  CAS  Google Scholar 

  • A. Lee, J.D. Lichtenhan, Macromolecules 31, 4970–4974 (1998)

    Article  CAS  Google Scholar 

  • A. Lee, J.D. Lichtenhan, W.A. Reinerth, Epoxy-POSS and epoxy-clay nanocomposites: thermal and viscoelastic comparison, in Am Ceram. Soc. Meeting Abstract 128-PMSE (2000) U485 Part 2

    Google Scholar 

  • S.A. Lermontov, A.N. Malkova, N.A. Sipyagina, E.A. Straumal, A.E. Baranchikov, V.K. Ivanov, J. Sol-Gel Sci. Technol. 84, 377–381 (2017)

    Article  CAS  Google Scholar 

  • N. Leventis, in Interpenetrating organic/inorganic networks of resorcinol-formaldehyde/metal oxide aerogels, ed. by M. A. Aegerter, N. Leventis, M. E. Koebel, (Springer Science + Publishing Media, New York, 2011), pp. 287–313

    Google Scholar 

  • N. Leventis, H. Lu, Polymer-cross-linked aerogels, in Aerogel handbook, ed. by M. A. Aegerter, N. Leventis, M. E. Koebel, (Springer Science + Publishing Media, New York, 2011), pp. 251–285

    Chapter  Google Scholar 

  • N. Leventis, C. Sortiriou-Leventis, G. Zhang, A.-M.M. Rawashdeh, Nano Lett. 2, 295–300 (2002)

    Article  CAS  Google Scholar 

  • N. Leventis, N. Chandrasekaran, A. Sadekar, C. Sotiriou-Leventis, H. Lu, J. Am. Chem. Soc. 131, 4576–4577 (2009)

    Article  CAS  Google Scholar 

  • D. Levy, D. Avnir, J. Phys. Chem. 92, 4734–4738 (1988)

    Article  CAS  Google Scholar 

  • D. Levy, S. Einhorn, D. Avnir, J. Non-Cryst. Solids 113, 137–145 (1989)

    Article  CAS  Google Scholar 

  • G.A. Li, T.L. Zhu, Z.X. Deng, Y.J. Zhang, F. Jiao, H.R. Zheng, Chin. Sci. Bull. 56, 685–690 (2011)

    Article  CAS  Google Scholar 

  • X. Li, Q. Wang, H. Li, H. Ji, X. Sun, J. He, J. Sol-Gel Sci. Technol. 67, 646–653 (2013)

    Article  CAS  Google Scholar 

  • X.T. Liang, B. Qu, J.R. Li, H.N. Xiao, B.H. He, L.Y. Qian, React. Funct. Polym. 86, 1–6 (2015)

    Article  CAS  Google Scholar 

  • M.H. Lim, A. Stein, Chem. Mater. 11, 3285–3295 (1999)

    Article  CAS  Google Scholar 

  • S.L. Liu, Q.F. Yan, D.D. Tao, T.F. Yu, X.Y. Liu, Carbohyd. Polym. 89, 551–557 (2012)

    Article  CAS  Google Scholar 

  • J. Livage, T. Coradin, C. Roux, Bioactive sol–gel hybrids (Wiley-VCH, Weinheim, 2004), pp. 387–404

    Google Scholar 

  • D.A. Loy, Mesoporous polysilsesquioxanes: preparation, properties, and applications, in Handbook of sol-gel science and technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer, Cham, 2016)

    Google Scholar 

  • D.A. Loy, K.J. Shea, E.M. Russick, Mater. Res. Soc. Symp. Proc. 271, 699–704 (1992)

    Article  CAS  Google Scholar 

  • D.A. Loy, B.M. Baugher, C.R. Baugher, D.A. Schneider, K. Rahimian, Chem. Mater. 12, 3624–3632 (2000)

    Article  CAS  Google Scholar 

  • A. Lungu, N.M. Florea, M. Manea, E. Vasile, H. Iovu, J. Appl. Polym. Sci. 133, 42912 (2016)

    Article  CAS  Google Scholar 

  • H. Luo, G. Churu, E.F. Fabrizio, J. Schnobrich, A. Hobbs, A. Dass, S. Mulik, Y. Zhang, B.P. Grady, A. Capecelatro, et al., J. Sol-Gel Sci. Technol. 48, 113–134 (2008)

    Article  CAS  Google Scholar 

  • J. Ma, L. Lv, G. Zou, Q. Zhang, ACS Appl Mater Interfaces 7, 241–249 (2015)

    Article  CAS  Google Scholar 

  • J.M. Mabry, A. Vij, S.T. Iacono, B.D. Viers, Angew. Chem. Int. Ed. 47, 4137–4140 (2008)

    Article  CAS  Google Scholar 

  • G.J. MacCarthy, R. Roy, J.M. Mackay, J. Am. Ceram. Soc. 54, 639–640 (1971)

    Article  Google Scholar 

  • J.D. Mackenzie, E.P. Bescher, in Handbook of Sol-Gel Science and Technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer International Publishing, Cham, 2016). Mechanical properties of organic–inorganic hybrids

    Google Scholar 

  • O. Mahony, O. Tsigkou, C. Ionescu, C. Minelli, L. Ling, R. Hanly, M.E. Smith, M.M. Stevens, J.R. Jones, Adv. Funct. Mater. 20, 3835–3845 (2010)

    Article  CAS  Google Scholar 

  • T.K. Mandai, S. Ram, Synthesis of PbZr0.7Ti0.3O3. Mater Lett. 57, 2432–2442 (2003)

    Article  CAS  Google Scholar 

  • T.V. Mani, H.K. Varma, K.G.K. Warrier, A.D. Damodaran, Br. Ceram. Trans. J. 91, 120–123 (1992)

    CAS  Google Scholar 

  • R.A. Mantz, P.F. Jones, K.P. Chaffee, J.D. Lichtenhan, J.W. Gilman, I.M.K. Ismail, et al., Chem. Mater. 8, 1250 (1996)

    Article  CAS  Google Scholar 

  • G. Markevicius, R. Ladj, P. Niemeyer, T. Budtova, A. Rigacci, J. Mater. Sci. 52, 2210–2221 (2017)

    Article  CAS  Google Scholar 

  • S. Marzouk, F. Rachdi, M. Fourati, J. Bouaziz, Colloid Surf. A 234, 109–116 (2004)

    Article  CAS  Google Scholar 

  • P.T. Mather, H.G. Jeon, A. Romo-Uribe, T.S. Haddad, J.D. Lichtenhan, Macromolecules 32, 1194–1203 (1999)

    Article  CAS  Google Scholar 

  • R.B. Mathur et al., Polym. Compos. 29, 717–727 (2008)

    Article  CAS  Google Scholar 

  • K.A. Mauritz, J. Appl. Polym. Sci. 40, 1401–1420 (1990)

    Article  CAS  Google Scholar 

  • M.A.B. Meador, Improving elastic properties of polymer-reinforced aerogels, in Aerogel Handbook, ed. by M. A. Aegerter, N. Leventis, M. E. Koebel, (Springer Science + Publishing Media, New York, 2011), pp. 315–334

    Chapter  Google Scholar 

  • M.A. Meador, E.F. Fabrizio, F. Ilhan, A. Dass, G. Zhang, P. Vassilarias, J.C. Johnston, N. Leventis, Chem. Mater. 17, 1085–1098 (2005)

    Article  CAS  Google Scholar 

  • M.A.B. Meador, A.S. Weber, A. Hindi, M. Naumenko, L. McCorkle, D. Quade, S.L. Vivod, G.L. Gould, S. White, K. Deshpande, Appl. Mater. Interface 1, 894–906 (2009)

    Article  CAS  Google Scholar 

  • N. Menshutina, S. Ivanov, P.I. Tsygankov, L. Khudeev, J. Sol-Gel Sci. Technol. 84, 382–390 (2017)

    Article  CAS  Google Scholar 

  • P.R. Miller, A. Ovsianikov, A. Koroleva, S.D. Gittard, B.N. Chichkov, R. Narayan, Am. Ceram. Soc. Bull. 90, 24–29 (2011)

    CAS  Google Scholar 

  • T. Miyazaki, Front. Biosci. E 5, 333–340 (2013)

    Article  Google Scholar 

  • Y. Mizushima, M. Hori, J. Non-Cryst. Solids 170, 215–222 (1994)

    Article  CAS  Google Scholar 

  • G. Monchâtre, Actual Chim. 108, 11–21 (1984)

    Google Scholar 

  • V. Morales-Florez, J.A. Toledo-Fernandez, N. Rosa-Fox, M. Pinero, L. Esquivias, J. Sol-Gel Sci. Technol. 50, 170–175 (2009)

    Article  CAS  Google Scholar 

  • D. Morselli, F. Bondioli, M. Fiorini, M. Messori, J. Mater. Sci. 47, 7003–7012 (2012a)

    Article  CAS  Google Scholar 

  • D. Morselli, F. Bondioli, M. Sangermano, M. Messori, Polymer 53, 283–290 (2012b)

    Article  CAS  Google Scholar 

  • S.P. Mukherjee, J. Zarzycki, J.P. Traverse, J. Mater. Sci. 11, 341–355 (1976)

    Article  CAS  Google Scholar 

  • M. Nandi, J.A. Conklin, L. Salvati Jr., A. Sen, Chem. Mater. 3, 201–206 (1991)

    Article  CAS  Google Scholar 

  • B.N. Nguyen, M.A.B. Meador, M.E. Tousley, B. Shonkwiler, L. McCorkle, D.A. Scheiman, A. Palczer, Appl. Mater. Interface 1, 621–630 (2009)

    Article  CAS  Google Scholar 

  • Y.-P. Ning, J.E. Mark, Polymer. Bull. 12, 407–411 (1984)

    CAS  Google Scholar 

  • F. Nishida, B. Dunn, E.T. Knobbe, P.D. Fuqua, R.B. Kaner, B.R. Mattes, Mater. Res. Soc. Symp. Proc. 180, 747–752 (1990)

    Article  CAS  Google Scholar 

  • J. Noack, C. Fritz, C. Flugel, F. Hemmann, H.J. Gläsel, O. Kahle, C. Dreyer, M. Bauer, E. Kemnitz, Dalton Trans. 42, 5706–5710 (2013)

    Article  CAS  Google Scholar 

  • B.M. Novak, C. Davies, Macromolecules 24, 5481–5483 (1991)

    Article  CAS  Google Scholar 

  • F.J. O’Brien, B.A. Harley, I.V. Yannas, L. Gibson, Biomaterials 25, 1077–1086 (2004)

    Article  CAS  Google Scholar 

  • S.V. Patwardhan, N. Mukherjee, M.F. Durstock, L.Y. Chiang, S.J. Clarson, J. Inorg. Organomet. P. 12, 49–55 (2002)

    Article  CAS  Google Scholar 

  • V. Petrykin, M. Kakihana, Chemistry and applications of polymeric gel precursors, in Handbook of Sol-Gel Science and Technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer, Cham, 2016)

    Google Scholar 

  • A.C. Pierre, Biomaterials obtained by gelation, in Handbook of Sol-Gel Science and Technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer International Publishing, Cham, 2016)

    Google Scholar 

  • G. Poologasundarampillai, B. Yu, O. Tsigkou, E.M. Valliant, S. Yue, P.D. Lee, R.W. Hamilton, M.M. Stevens, T. Kasuga, J.R. Jones, Soft Matter 8, 4822–8432 (2012)

    Article  CAS  Google Scholar 

  • M.J.T. Raaijmakers, M.A. Hempenius, P.M. Schön, G.J. Vancso, A. Nijmeijer, M. Wessling, et al., J. Am. Chem. Soc. 136, 330–335 (2014)

    Article  CAS  Google Scholar 

  • P. Ragesh, S.V. Nair, A.S. Nair, RSC Adv. 4, 38498–38504 (2014)

    Article  CAS  Google Scholar 

  • S.M. Ramirez, Y.J. Diaz, C.M. Sahagun, M.W. Duff, O.B. Lawal, S.T. Iacono, et al., Polym. Chem. 4, 2230–2234 (2013)

    Article  CAS  Google Scholar 

  • G.V.R. Rao, D.S.S. Narayana, U.V. Varadaraju, G.V.N. Rao, S. Venkadesan, J. Alloy Compd. 217, 200–208 (1995)

    Article  Google Scholar 

  • R. Reisfeld, D. Brusilovsky, M. Eyal, E. Miron, Z. Bursheim, J. lvri, Chem. Phys. Lett. 160, 43–44 (1989)

    Article  CAS  Google Scholar 

  • L. Ren, K. Tsuru, S. Hayakawa, A. Osaka, Biomaterials 23, 4765–4773 (2002)

    Article  CAS  Google Scholar 

  • L. Ren, J. Wang, F.-Y. Yang, L. Wang, D. Wang, T.-X. Wang, M.-M. Tian, Mater. Sci. Eng. C 30, 437–444 (2010)

    Article  CAS  Google Scholar 

  • S.H. Rhee, Y.K. Lee, B.S. Lim, Biomacromolecules 5, 1575–1579 (2004)

    Article  CAS  Google Scholar 

  • R. Roy, J. Am. Ceram. Soc. 52, 344–345 (1969)

    Article  CAS  Google Scholar 

  • E. Ruiz-Hitzky, Adv. Mater. 5, 334–340 (1993)

    Article  CAS  Google Scholar 

  • E. Ruiz-Hitzky, K. Ariga, Y. Lvov (eds.), Bio-inorganic hybrid nanomaterials; strategies, syntheses, characterization and applications (Wiley-VCH, Weinheim, 2008)

    Google Scholar 

  • T. Saegusa, Y. Chujo, J. Macromol. Sci. A 27, 1603–1612 (1990)

    Article  Google Scholar 

  • B. Samuneva, P. Djambaski, E. Kashchieva, G. Chernev, L. Kabaivanova, E. Emanuilova, I.M.M. Salvado, M.H.V. Fernandes, A. Wu, J. Non-Cryst. Solids 354, 733–740 (2008)

    Article  CAS  Google Scholar 

  • C. Sanchez, M. In, J. Non-Cryst. Solids 147(/148), 1–12 (1992)

    Article  Google Scholar 

  • A. Sanchez, D.A. Loy, Sol-gel chemistry of aminopropyltrialkoxy silanes. Polym Prepr (ACS Div Polym. Chem.) 42, 182–183 (2001)

    CAS  Google Scholar 

  • C. Sanchez, F. Ribot, New J. Chem. 18, 1007–1047 (1994)

    CAS  Google Scholar 

  • C. Sanchez, M. In, P. Toledano, P. Griesmar, Mater. Res. Soc. Symp. Proc. 271, 669–680 (1992)

    Article  CAS  Google Scholar 

  • C. Sanchez, B. Alonso, F. Chapusot, F. Ribot, P. Audebert, J. Sol-Gel Sci. Technol. 2, 161–166 (1994)

    Article  CAS  Google Scholar 

  • C. Sanchez, P. Belleville, M. Popall, L. Nicole, Chem. Soc. Rev. 40, 696–753 (2011)

    Article  CAS  Google Scholar 

  • A.Y. Sane, Refractory metal borides, carbides and nitrides, and composites containing them, European Patent 0115745, Eltech Systems Corporation (1984) 26pp

    Google Scholar 

  • A. Santos, M. Ajbary, J.A. Toldeo-Fernandez, V. Morales-Florez, A. Kherbeche, L. Esquivias, J. Sol-Gel Sci. Technol. 48, 224–230 (2008)

    Article  CAS  Google Scholar 

  • H. Schmidt, J. Non-Cryst. Solids 73, 681–691 (1985)

    Article  CAS  Google Scholar 

  • U. Schubert, E. Arpac, W. Glaubitt, A. Helmerich, C. Chau, Chem. Mater. 4, 291–295 (1992)

    Article  CAS  Google Scholar 

  • F. Schwertfeger, N. Hüsing, U. Schubert, J. Sol-Gel Sci. Technol. 2, 103–108 (1994)

    Article  CAS  Google Scholar 

  • C. Sciancalepore, F. Bondioli, M. Messori, G. Barrera, P. Tiberto, P. Allia, Polymer 59, 278–289 (2015)

    Article  CAS  Google Scholar 

  • Y. Shi, X. Gao, D. Zhang, Y. Liu, G. Huang, RSC Adv. 4, 41453–41460 (2014)

    Article  CAS  Google Scholar 

  • H.S. Shin et al., Adv. Mater. 19, 2873 (2007)

    Article  CAS  Google Scholar 

  • Y. Shirosaki, A. Osaka, K. Tsuru, S. Hayakawa, Inorganic–organic sol–gel hybrids, vol 131 (Wiley, Hoboken, 2012), pp. 139–158

    Google Scholar 

  • Y. Shirosaki, Y. Nakamura, T. Yoshioka, A. Osaka, Inorganic-organic hybrids for biomedical applications, in Handbook of Sol-Gel Science and Technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer International Publishing, Cham, 2016)

    Google Scholar 

  • N.P. da Silveira, F. Ehrburger-Dolle, C. Rochas, A. Rigacci, F.V. Pereira, A.A. Merlo, H. Westfahl Jr., AIP Conf. Proc. 1092, 180–184 (2009)

    Article  CAS  Google Scholar 

  • A. Sin, P. Odier, M. Nez-Regueiro, Physica C 330, 9–18 (2000)

    Article  CAS  Google Scholar 

  • A. Sin, B.E. Montaser, P. Odier, J. Am. Ceram. Soc. 85, 1928–1932 (2002)

    Article  CAS  Google Scholar 

  • I. Smirnova, S. Suttiruengwong, W. Arlt, J. Non-Cryst. Solids 350, 54–60 (2004)

    Article  CAS  Google Scholar 

  • A. Sugino, T. Miyazaki, C. Ohtsuki, J. Mater. Sci. Mater. Med. 19, 2269–2274 (2008)

    Article  CAS  Google Scholar 

  • R. Sun, H.Y. Chen, Q.W. Li, Q.J. Song, X.T. Zhang, Nanoscale 6, 12912–12920 (2014)

    Article  CAS  Google Scholar 

  • G.S. Sur, J.E. Mark, Eur. Polym. J. 21, 1051–1052 (1985)

    Article  CAS  Google Scholar 

  • L.W. Tai, P.A. Lessing, J. Mater. Res. 7, 502–510 (1992a)

    Article  CAS  Google Scholar 

  • L.W. Tai, P.A. Lessing, J. Mater. Res. 7, 511–519 (1992b)

    Article  CAS  Google Scholar 

  • R. Tamaki, K. Naka, J. Chujo, Polym. J. 30, 60–65 (1998)

    Article  CAS  Google Scholar 

  • E.T. Thostenson, Z.F. Ren, T.W. Chou, Compos. Sci. Technol. 61, 1899–1912 (2001)

    Article  CAS  Google Scholar 

  • M. Toki, T.Y. Chow, T. Ohnaka, H. Samura, T. Saegusa, Polym. Bull. 29, 653–660 (1992)

    Article  Google Scholar 

  • A. Tsuchida, C. Bolln, F.G. Sernetz, H. Frey, R. Mulhaupt, Macromolecules 30, 2818 (1997)

    Article  CAS  Google Scholar 

  • E.M. Valliant, J.R. Jones, Soft Matter 7, 5083–5095 (2011)

    Article  CAS  Google Scholar 

  • A. Venkateswara Rao, G.M. Pajonk, D.Y. Nadargi, M.M. Koebel, Superhydrophobic and flexible aerogels, in Aerogels handbook, ed. by M. A. Aegerter, N. Leventis, M. M. Koebel, (Springer, Cham, 2011), pp. 79–101

    Google Scholar 

  • A. Venkatsewara Rao, S.D. Bhagat, H. Hirashima, G.M. Pajonk, J. Colloid Interface Sci. 300, 279–285 (2006)

    Article  CAS  Google Scholar 

  • M.A. Vicarini, G.A. Nicolaon, S.J. Teichner, Bull. Soc. Chim. Fr. 10, 3384–3387 (1970)

    Google Scholar 

  • J. Wang et al., Anal. Chem. 65, 2300–2303 (1993)

    Article  CAS  Google Scholar 

  • P. Wang, Y. Tang, Z. Yu, J. Gu, J. Kong, ACS Appl. Mater. Interfaces 7, 20144–20155 (2015)

    Article  CAS  Google Scholar 

  • G.L. Wilkes, B. Orler, H.H. Huang, Polym. Prep. 26, 300–301 (1985)

    CAS  Google Scholar 

  • K.I. Winey, T. Kashiwagi, M.F. Mu, MRS Bull. 32(4), 348–353 (2007)

    Article  CAS  Google Scholar 

  • T. Woignier et al., J. Non-Cryst. Solids 241, 45 (1998)

    Article  CAS  Google Scholar 

  • J. Wong, H. Kaymak, P. Tingaut, S. Brunner, M. Koebel, Micropor. Mesopor. Mater 217, 150–158 (2015)

    Article  CAS  Google Scholar 

  • M.A. Worsley, T.F. Baumann, Carbon aerogels, in Handbook of Sol-Gel Science and Technology, ed. by L. Klein, M. Aparicio, A. Jitianu, (Springer, Cham, 2016), p. 18

    Google Scholar 

  • M.A. Worsley et al., J. Mater. Chem. 19, 3370–3372 (2009)

    Article  CAS  Google Scholar 

  • M.A. Worsley, S.O. Kucheyev, J.D. Kuntz, T.Y. Olson, T.Y.-J. Han, A.V. Hamza, J.H. Satecher, T.F. Baumann, Chem. Mater. 23, 3054–3061 (2011)

    Article  CAS  Google Scholar 

  • Y.B. Wu, Y.X. Chen, J.H. Yan, S.H. Yang, P. Dong, P. Soman, J. Mater. Chem. B 3, 5352–5360 (2015)

    Article  CAS  Google Scholar 

  • A. Xie, F. Wu, Z.H. Xu, M.Y. Wang, Compos. Sci. Technol. 117, 32–38 (2015)

    Article  CAS  Google Scholar 

  • X.C. Xiong, N. Ji, C.F. Song, Q.L. Liu, Preparation of functionalized graphene aerogels as air cleaner filter, in 9th International Symposium on Heating, Ventilation and Air Conditioning (ISHVAC) Joint with the 3rd International Conference on Building Energy and Environment (COBEE), Book Series: Proc. Eng., vol. 121, ed. by Y. Sun, J. Pei, (2015) pp. 957–979

    Google Scholar 

  • C.J. Yao, X. Liu, W. Rien, Biopolymer-containing aerogels: Chitosan-silica hybrid aerogels, in Aerogels handbook, ed. by M. A. Aegerter, N. Leventis, M. E. Koebel, (Springer Science + Publishing Media, New-York, 2011), pp. 385–401

    Chapter  Google Scholar 

  • S.B. Ye, J.C. Feng, ACS Appl. Mater. Inter. 6, 9671–9679 (2014)

    Article  CAS  Google Scholar 

  • T.-J. Yim, S.Y. Kim, K.-P. Yoo, Korean J. Chem. Eng. 19, 159–166 (2002)

    Article  CAS  Google Scholar 

  • B.E. Yoldas, J. Mater. Sci. 14, 1843–1849 (1979)

    Article  CAS  Google Scholar 

  • M. Zhang et al., J. Mater. Chem. 20, 5835–5842 (2010)

    Article  CAS  Google Scholar 

  • H. Zhang, J. Ding, X. Chen, H. Zhang, X. Liu, Combination Control, Nanomagnetism, and Biomedical Applications of Inorganic Multicomponent Hybrid Nanomaterials (Pan Stanford Publishing, Singapore, 2012), pp. 421–454

    Google Scholar 

  • Z.Y. Zhang, M.Y. Liang, X.H. Liu, F. Zhao, B.F. Wang, W.J. Li, Q.G. Wang, RSC Adv. 5, 88419–88424 (2015a)

    Article  CAS  Google Scholar 

  • J.T. Zhang, Z.H. Zhao, Z.H. Xia, L.M. Dai, Nat. Nanotechnol. 10, 444–452 (2015b)

    Article  CAS  Google Scholar 

  • S.Y. Zhao, W.J. Malfait, A. Demilecamps, Y.C. Zhang, S. Brunner, L. Huber, P. Tingaut, A. Rigacci, T. Budtova, M.M. Koebel, Angew. Chem. Int. Ed. 54, 14282–14286 (2015)

    Article  CAS  Google Scholar 

  • S. Zhao, M.S. Manic, F. Ruiz-Gonzalez, M.M. Koebel, Aerogels, in The Sol–Gel Handbook: Synthesis, Characterization and Applications, ed. by D. Levy, M. Zayat, (Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2015b), pp. 519–574

    Chapter  Google Scholar 

  • S. Zhao, Z. Zheng, G. Sèbe, R. Wu, R.V. Rivera Virtudazo, P. Tingaut, M. Koebel, Adv. Func. Mater. 25, 2326–2334 (2015c)

    Article  CAS  Google Scholar 

  • G. Zu, T. Shimizu, K. Kanamori, Y. Zhu, A. Maeno, H. Kaji, J. Shen, K. Nakanishi, ACS Nano 12, 521–532 (2018)

    Article  CAS  Google Scholar 

  • A. Zubrowska, E. Piorkowska, A. Kowalewska, M. Cichorek, Colloid Polym. Sci. 293, 23–33 (2015)

    Article  CAS  Google Scholar 

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Pierre, A.C. (2020). Hybrid Organic–Inorganic and Composite Materials. In: Introduction to Sol-Gel Processing. Springer, Cham. https://doi.org/10.1007/978-3-030-38144-8_10

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