Abstract
Disposable or point-of-care sensors are a promising tool for low-cost and rapid sensing of analytes including pesticides. They find important applications in pesticide-contaminated food, agro-products, and water quality monitoring. This chapter highlights the implication and significance of pesticide residue identification in foodstuffs and overviews the most frequently engaged analytical techniques, and finally their benefits and limitations are discussed. Disposable strip-based biosensors have their intrinsic advantages and some disadvantages, but their cost-effectiveness and portability have turned them as a potential possibility for point-of-care (POC) testing of various pesticides. The fabrication of robust, low-cost, reliable, and sensitive sensors with the aid of both simple naked eye-based and portable readout-based detectors is the driving factor in this sensor’s technology area. The pending limitations can be overcome by adapting new specific recognition elements and better signal generative particles or systems. The integration of these devices with card readers or smartphones can make them more user-friendly and will provide more accurate quantitative information.
The development of LFAs and paper sensors with multiplexing capabilities will further add to their practical utility. In the future, it is expected that LFAs and portable user-friendly sensors will be made available to the general public for POC testing of complex parameters, e.g., dengue, chikungunya, typhoid, etc. These tools have immense significance toward the screening of food and water samples for pollutants like pesticides, heavy metals, pathogens, etc. In overall, future successes and adoption of LFA paper sensors in a wide range of environmental monitoring application call for the realization of more stable devices capable of handling multiple analytes with high sensitivity without sacrificing the simplicity and cost advantages. The possibilities of future research and development in the field of colorimetric-/fluorescence-based assays are deliberated.
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Abbreviations
- 2,4,5-T:
-
2,4,5-Trichlorophenoxyacetic acid
- 2,4-D:
-
2-(2,4-Dichlorophenoxy)acetic acid
- AChE:
-
Acetylcholinesterase enzyme
- AMP:
-
p-(Aminomethyl)phenyl
- ASE:
-
Accelerated solvent extraction
- ATChI:
-
Acetylthiocholine iodide
- BC:
-
Before Christ year
- BSA:
-
Bovine serum albumin
- C:
-
Control
- CE:
-
Capillary electrophoresis
- CLC:
-
Capillary liquid chromatography
- CNS:
-
Central nervous system
- CPE:
-
Cloud point extraction
- c-SWCNTs:
-
Carboxyl-functionalized single walled-carbon nanotubes
- DDT:
-
Dichlorodiphenyltrichloroethane
- DNA:
-
Deoxyribonucleic acid
- DPV:
-
Differential pulse voltammetry
- dSPE:
-
Dispersive solid-phase extraction
- DTNB:
-
5,5′-Dithiobis(2-nitrobenzoic) acid
- ECD:
-
Electron capture detectors
- ELCD:
-
Electrolytic conductivity detectors
- EPA:
-
Environmental Protection Agency
- EU:
-
European Union
- FAM:
-
Carboxyfluorescein
- FAO:
-
Agriculture Organization of United Nations
- FAO/WHO:
-
World Health Organization
- FID:
-
Flame ionization detectors
- FPD:
-
Flame photometric detectors
- GC:
-
Gas chromatography
- GCE:
-
Glassy carbon electrode
- GCxGC:
-
Comprehensive two-dimensional gas chromatography
- GNPs:
-
Colloidal gold nanoparticles
- GO:
-
Graphene oxide
- GUP:
-
General use pesticides
- hCG:
-
Human chorionic gonadotropin
- HILIC:
-
Hydrophilic interaction liquid chromatography
- HIV:
-
Human immunodeficiency virus
- HPLC:
-
High-performance liquid chromatography
- IAA:
-
Indole acetic acid
- IFE:
-
Inner-filter effect
- LC x LC:
-
Two-dimensional liquid chromatography
- LC:
-
Liquid chromatography
- LD 50:
-
Lethal dose
- LFA:
-
Lateral flow immunoassay
- LFIA:
-
Lateral flow immunochromatographic assay
- LOD:
-
Limit of detection
- LOQ:
-
Limit of quantification
- LP-GC:
-
Low-pressure gas chromatography
- LPME:
-
Liquid-phase microextraction
- MAE:
-
Microwave-assisted extraction
- MB:
-
Methylene blue
- MCPA:
-
2-(4-Chloro-2-methylphenoxy)acetic acid
- MIP:
-
Molecularly imprinted polymers
- μLC:
-
Micro-liquid chromatography
- MRLs:
-
Maximum residue limits
- MS:
-
Mass spectrophotometers
- MW:
-
Microwave
- nano-LC:
-
Nanoliquid chromatography
- NC:
-
Nitrocellulose
- NHS:
-
N-Hydroxysuccinimide
- NIST:
-
National Institute of Standards and Technology
- NPD:
-
Nitrogen-phosphorus detectors
- OPH:
-
Organophosphate hydrolase
- PAHs:
-
Polyaromatic hydrocarbons
- PCR:
-
Polymerase chain reaction
- PID:
-
Photoionization detectors
- PM:
-
Protamine molecules
- POC:
-
Point-of-care
- POP:
-
Persistent organic pollutant
- PTV:
-
Programmed temperature vaporization
- QuEChERS:
-
Quick, easy, cheap, effective, rugged, and safe
- RF-QDs:
-
Ratiometric fluorescent quantum dots
- RNA:
-
Ribonucleic acid
- RPLC:
-
Reversed-phase liquid chromatography
- SBSE:
-
Stir bar sorptive extraction
- SELEX:
-
Systematic evolution of ligands by exponential enrichment
- SERS:
-
Surface-enhanced Raman scattering
- SPE:
-
Solid-phase extraction
- SPME:
-
Solid-phase microextraction
- SPR:
-
Surface plasmon resonance
- ssDNA:
-
Single-stranded DNA
- T:
-
Test
- TCD:
-
Thermal conductivity detectors
- TLC:
-
Thin-layer chromatography
- UHPLC:
-
Ultrahigh-performance liquid chromatography
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Acknowledgment
Dr. Satish Kumar acknowledges the Council of Scientific and Industrial Research (CSIR), New Delhi, for his research grant. Dr. Akash Deep thanks the Department of Science and Technology, New Delhi, for funding his research project.
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Mohanta, G.C., Bhatt, D., Deep, A., Pandey, S.K. (2020). Development of Optical Sensor Strips for Point-of-Care Testing for Pesticide. In: Kumar Tuteja, S., Arora, D., Dilbaghi, N., Lichtfouse, E. (eds) Nanosensors for Environmental Applications. Environmental Chemistry for a Sustainable World, vol 43. Springer, Cham. https://doi.org/10.1007/978-3-030-38101-1_7
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