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Spark Plasma Sintering of Graphene Nanoplatelets Reinforced Aluminium 6061 Alloy Composites

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Light Metals 2020

Abstract

Over the years, high performance lightweight aluminium matrix composites have, mainly due to their excellent mechanical properties , found wide applications in automobile and aerospace applications. In the present study, Graphene NanoPlatelets based reinforced aluminium alloy AA6061 composites have been prepared through spark plasma sintering with four different loadings, i.e. 0.1, 0.5, 1 and 3 wt%. Through property characterisation of the obtained composites, it was established that a higher content of nano reinforcement had a substantial effect on the resulting microstructure , as well as on the electrical conductivity that proved to increase due to uniform distribution of the graphene network around the grains. An increase in the hardness and compressive strength was also obtained. The associated strengthening mechanism is discussed. A 2-dimensional physical model based on the bridging effect of graphene nanoplatelets in a composite matrix is presented, and its correlation with experimental results is discussed.

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References

  1. Geim, A.K., and Novoselov, K.S.: ‘The rise of graphene’, Nature Materials, 2007, 6, pp. 183.

    Google Scholar 

  2. Yang, W., Zhao, Q., Xin, L., Qiao, J., Zou, J., Shao, P., Yu, Z., Zhang, Q., and Wu, G.: ‘Microstructure and mechanical properties of graphene nanoplates reinforced pure Al matrix composites prepared by pressure infiltration method’, Journal of Alloys and Compounds, 2018, 732, (Supplement C), pp. 748–758.

    Google Scholar 

  3. Lee, C., Wei, X., Kysar, J.W., and Hone, J.: ‘Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene’, Science, 2008, 321, (5887), pp. 385–388.

    Google Scholar 

  4. Alexander, A. Balandin, S.G., Wenzhong Bao, Irene Calizo, Desalegne Teweldebrhan, Feng Miao and Chun Ning Lau: ‘Superior Thermal Conductivity of Single-Layer Graphene’, NANO LETTERS, 2008, 8, (3), pp. 902–907.

    Google Scholar 

  5. Khan, M., Zulfaqar, M., Ali, F., and Subhani, T.: ‘Hybrid aluminium matrix composites containing boron carbide and quasicrystals: manufacturing and characterisation’, Materials Science and Technology, 2017, 33, (16), pp. 1955–1963.

    Google Scholar 

  6. Khan, M., Zulfaqar, M., Ali, F., and Subhani, T.: ‘Microstructural and mechanical characterization of hybrid aluminum matrix composite containing boron carbide and Al–Cu–Fe quasicrystals’, Metals and Materials International, 2017, 23, (4), pp. 813–822.

    Google Scholar 

  7. Khan, M., Rehman, A., Aziz, T., Naveed, K., Ahmad, I., and Subhani, T.: ‘Cold formability of friction stir processed aluminum composites containing carbon nanotubes and boron carbide particles’, Materials Science and Engineering: A, 2017, 696, pp. 552–557.

    Google Scholar 

  8. Khan, M., Syed, W.H., Akhtar, S., and Aune, R.E.: ‘Friction Stir Processing (FSP) of Multiwall Carbon Nanotubes and Boron Carbide Reinforced Aluminum Alloy (Al 5083) Composites’, in Editor (Ed.)^(Eds.): ‘Book Friction Stir Processing (FSP) of Multiwall Carbon Nanotubes and Boron Carbide Reinforced Aluminum Alloy (Al 5083) Composites’ (Springer International Publishing, 2019, edn.), pp. 217–232.

    Google Scholar 

  9. Khan, M., Ud Din, R., Wadood, A., Syed, W.H., Akhtar, S., and Aune, R.E.: ‘Effect of graphene nanoplatelets on the physical and mechanical properties of Al6061 in fabricated and T6 thermal conditions’, Journal of Alloys and Compounds, 2019, 790, pp. 1076–1091.

    Google Scholar 

  10. Huang, X., Qi, X., Boey, F., and Zhang, H.: ‘Graphene-based composites’, Chemical Society Reviews, 2012, 41, (2), pp. 666–686.

    Google Scholar 

  11. Jeon, C.-H., Jeong, Y.-H., Seo, J.-J., Tien, H.N., Hong, S.-T., Yum, Y.-J., Hur, S.-H., and Lee, K.-J.: ‘Material properties of graphene/aluminum metal matrix composites fabricated by friction stir processing’, International Journal of Precision Engineering and Manufacturing, 2014, 15, (6), pp. 1235–1239.

    Google Scholar 

  12. Bisht, A., Srivastava, M., Kumar, R.M., Lahiri, I., and Lahiri, D.: ‘Strengthening mechanism in graphene nanoplatelets reinforced aluminum composite fabricated through spark plasma sintering’, Materials Science and Engineering: A, 2017, 695, pp. 20–28.

    Google Scholar 

  13. Li, J.L., Xiong, Y.C., Wang, X.D., Yan, S.J., Yang, C., He, W.W., Chen, J.Z., Wang, S.Q., Zhang, X.Y., and Dai, S.L.: ‘Microstructure and tensile properties of bulk nanostructured aluminum/graphene composites prepared via cryomilling’, Materials Science and Engineering: A, 2015, 626, (0), pp. 400–405.

    Google Scholar 

  14. Pérez-Bustamante, R., Bolaños-Morales, D., Bonilla-Martínez, J., Estrada-Guel, I., and Martínez-Sánchez, R.: ‘Microstructural and hardness behavior of graphene-nanoplatelets/aluminum composites synthesized by mechanical alloying’, Journal of Alloys and Compounds, 2014, 615, pp. S578–S582.

    Google Scholar 

  15. Khan, M., Amjad, M., Khan, A., Ud-Din, R., Ahmad, I., and Subhani, T.: ‘Microstructural evolution, mechanical profile, and fracture morphology of aluminum matrix composites containing graphene nanoplatelets’, Journal of Materials Research, 2017, pp. 1–12.

    Google Scholar 

  16. Li, Q., Rottmair, C.A., and Singer, R.F.: ‘CNT reinforced light metal composites produced by melt stirring and by high pressure die casting’, Composites Science and Technology, 2010, 70, (16), pp. 2242–2247.

    Google Scholar 

  17. Khan, M., Ud-Din, R., Syed, W.H., Akhtar, S., and Aune, R.E.: ‘Spark plasma sintering of boron carbide reinforced aluminum alloy (Al6061) matrix composites’, in Editor (Ed.)^(Eds.): ‘Book Spark plasma sintering of boron carbide reinforced aluminum alloy (Al6061) matrix composites’ (IEEE, 2019, edn.), pp. 35–41.

    Google Scholar 

  18. Khan, M., Rehman, A., Aziz, T., Shahzad, M., Naveed, K., and Subhani, T.: ‘Effect of inter-cavity spacing in friction stir processed Al 5083 composites containing carbon nanotubes and boron carbide particles’, Journal of Materials Processing Technology, 2018, 253, pp. 72–85.

    Google Scholar 

  19. Dixit, S., Mahata, A., Mahapatra, D.R., Kailas, S.V., and Chattopadhyay, K.: ‘Multi-layer graphene reinforced aluminum – Manufacturing of high strength composite by friction stir alloying’, Composites Part B: Engineering, 2018, 136, (Supplement C), pp. 63–71.

    Google Scholar 

  20. Alipour, M., and Eslami-Farsani, R.: ‘Synthesis and characterization of graphene nanoplatelets reinforced AA7068 matrix nanocomposites produced by liquid metallurgy route’, Materials Science and Engineering: A, 2017, 706, (Supplement C), pp. 71–82.

    Google Scholar 

  21. Wang, J., Li, Z., Fan, G., Pan, H., Chen, Z., and Zhang, D.: ‘Reinforcement with graphene nanosheets in aluminum matrix composites’, Scripta Materialia, 2012, 66, (8), pp. 594–597.

    Google Scholar 

  22. Zakharchenko, K.V., Annalisa, F., Los, J.H., and Katsnelson, M.I.: ‘Melting of graphene: from two to one dimension’, Journal of Physics: Condensed Matter, 2011, 23, (20), pp. 202202.

    Google Scholar 

  23. Sajjadi, S.A., Torabi Parizi, M., Ezatpour, H.R., and Sedghi, A.: ‘Fabrication of A356 composite reinforced with micro and nano Al2O3 particles by a developed compocasting method and study of its properties’, Journal of Alloys and Compounds, 2012, 511, (1), pp. 226–231.

    Google Scholar 

  24. Nieto, A., Lahiri, D., and Agarwal, A.: ‘Synthesis and properties of bulk graphene nanoplatelets consolidated by spark plasma sintering’, Carbon, 2012, 50, (11), pp. 4068–4077.

    Google Scholar 

  25. Munir, Z.A., Anselmi-Tamburini, U., and Ohyanagi, M.: ‘The effect of electric field and pressure on the synthesis and consolidation of materials: A review of the spark plasma sintering method’, JOURNAL OF MATERIALS SCIENCE, 2006, 41, (3), pp. 763–777.

    Google Scholar 

  26. Tian, W.-m., Li, S.-m., Wang, B., Chen, X., Liu, J.-h., and Yu, M.: ‘Graphene-reinforced aluminum matrix composites prepared by spark plasma sintering’, International Journal of Minerals, Metallurgy, and Materials, 2016, 23, (6), pp. 723–729.

    Google Scholar 

  27. Chang, Y.-h., Huang, D., Jia, C.-c., Cui, Z.-w., Wang, C.-c., and Liang, D.: ‘Influence of plasma on the densification mechanism of SPS under multi-field effect’, International Journal of Minerals, Metallurgy, and Materials, 2014, 21, (9), pp. 906–912.

    Google Scholar 

  28. Liu, W.-W., Xia, B.-Y., Wang, X.-X., and Wang, J.-N.: ‘Exfoliation and dispersion of graphene in ethanol-water mixtures’, Frontiers of Materials Science, 2012, 6, (2), pp. 176–182.

    Google Scholar 

  29. Asgharzadeh, H., and Sedigh, M.: ‘Synthesis and mechanical properties of Al matrix composites reinforced with few-layer graphene and graphene oxide’, Journal of Alloys and Compounds, 2017, 728, pp. 47–62.

    Google Scholar 

  30. Ju, J.-M., Wang, G., and Sim, K.-H.: ‘Facile synthesis of graphene reinforced Al matrix composites with improved dispersion of graphene and enhanced mechanical properties’, Journal of Alloys and Compounds, 2017, 704, (Supplement C), pp. 585–592.

    Google Scholar 

  31. Ipekoglu, M., Nekouyan, A., Albayrak, O., and Altintas, S.: ‘Mechanical characterization of B 4 C reinforced aluminum matrix composites produced by squeeze casting’, Journal of Materials Research, 2017, pp. 1–7.

    Google Scholar 

  32. Rashad, M., Pan, F., Tang, A., and Asif, M.: ‘Effect of Graphene Nanoplatelets addition on mechanical properties of pure aluminum using a semi-powder method’, Progress in Natural Science: Materials International, 2014, 24, (2), pp. 101–108.

    Google Scholar 

  33. Alam, S.N., and Kumar, L.: ‘Mechanical properties of aluminium based metal matrix composites reinforced with graphite nanoplatelets’, Materials Science and Engineering: A, 2016, 667, pp. 16–32.

    Google Scholar 

  34. Liu, J., Khan, U., Coleman, J., Fernandez, B., Rodriguez, P., Naher, S., and Brabazon, D.: ‘Graphene oxide and graphene nanosheet reinforced aluminium matrix composites: Powder synthesis and prepared composite characteristics’, Materials & Design, 2016, 94, pp. 87–94.

    Google Scholar 

  35. Saboori, A., Pavese, M., Badini, C., and Fino, P.: ‘Microstructure and Thermal Conductivity of Al–Graphene Composites Fabricated by Powder Metallurgy and Hot Rolling Techniques’, Acta Metallurgica Sinica (English Letters), 2017, 30, (7), pp. 675–687.

    Google Scholar 

  36. Oppenheim, T., Tewfic, S., Scheck, T., Klee, V., Lomeli, S., Dahir, W., Youngren, P., Aizpuru, N., Clark, R., Lee, E.W., Ogren, J., and Es-Said, O.S.: ‘On the correlation of mechanical and physical properties of 6061-T6 and 7249-T76 aluminum alloys’, Engineering Failure Analysis, 2007, 14, (1), pp. 218–225.

    Google Scholar 

  37. Pouraliakbar, H., Jandaghi, M.R., and Khalaj, G.: ‘Constrained groove pressing and subsequent annealing of Al-Mn-Si alloy: Microstructure evolutions, crystallographic transformations, mechanical properties, electrical conductivity and corrosion resistance’, Materials & Design, 2017, 124, pp. 34–46.

    Google Scholar 

  38. Xu, C.L., Wei, B.Q., Ma, R.Z., Liang, J., Ma, X.K., and Wu, D.H.: ‘Fabrication of aluminum–carbon nanotube composites and their electrical properties’, Carbon, 1999, 37, (5), pp. 855–858.

    Google Scholar 

  39. Tewari, A., Böhm, S., Gandla, S., McNeill, C.R., and Gupta, D.: ‘Graphene-MWNTs composite coatings with enhanced electrical conductivity’, FlatChem, 2017, 4, pp. 33–41.

    Google Scholar 

  40. Latief, F.H., Sherif, E.-S.M., Almajid, A.A., and Junaedi, H.: ‘Fabrication of exfoliated graphite nanoplatelets-reinforced aluminum composites and evaluating their mechanical properties and corrosion behavior’, Journal of Analytical and Applied Pyrolysis, 2011, 92, (2), pp. 485–492.

    Google Scholar 

  41. Bisht, A., Kumar, V., Li, L.H., Chen, Y., Agarwal, A., and Lahiri, D.: ‘Effect of warm rolling and annealing on the mechanical properties of aluminum composite reinforced with boron nitride nanotubes’, Materials Science and Engineering: A, 2018, 710, pp. 366–373.

    Google Scholar 

  42. Yamaguchi, M., Meng, F., Firestein, K., Tsuchiya, K., and Golberg, D.: ‘Powder metallurgy routes toward aluminum boron nitride nanotube composites, their morphologies, structures and mechanical properties’, Materials Science and Engineering: A, 2014, 604, (0), pp. 9–17.

    Google Scholar 

  43. Zhou, W., Bang, Sora, Kurita, Hiroki, Miyazaki, Takamichi, Fan, Yuchi, Kawasaki, Akira: ‘Interface and interfacial reactions in multi-walled carbon nanotube-reinforced aluminum matrix composites’, Carbon, 2016, 96, pp. 919–928.

    Google Scholar 

  44. Sharma, V., Prakash, U., and Kumar, B.V.M.: ‘Surface composites by friction stir processing: A review’, Journal of Materials Processing Technology, 2015, 224, (0), pp. 117–134.

    Google Scholar 

  45. Hu, Z., Tong, G., Lin, D., Chen, C., Guo, H., Xu, J., and Zhou, L.: ‘Graphene-reinforced metal matrix nanocomposites–a review’, Materials Science and Technology, 2016, 32, (9), pp. 930–953.

    Google Scholar 

  46. Khodabakhshi, F., Arab, S.M., Švec, P., and Gerlich, A.P.: ‘Fabrication of a new Al-Mg/graphene nanocomposite by multi-pass friction-stir processing: Dispersion, microstructure, stability, and strengthening’, Materials Characterization, 2017, 132, (Supplement C), pp. 92–107.

    Google Scholar 

  47. Li, Z., Guo, Q., Li, Z., Fan, G., Xiong, D.-B., Su, Y., Zhang, J., and Zhang, D.: ‘Enhanced Mechanical Properties of Graphene (Reduced Graphene Oxide)/Aluminum Composites with a Bioinspired Nanolaminated Structure’, Nano Letters, 2015, 15, (12), pp. 8077–8083.

    Google Scholar 

  48. Yang, W., Chen, G., Qiao, J., Liu, S., Xiao, R., Dong, R., Hussain, M., and Wu, G.: ‘Graphene nanoflakes reinforced Al-20Si matrix composites prepared by pressure infiltration method’, Materials Science and Engineering: A, 2017, 700, (Supplement C), pp. 351–357.

    Google Scholar 

  49. Zhao, M., Xiong, D.-B., Tan, Z., Fan, G., Guo, Q., Guo, C., Li, Z., and Zhang, D.: ‘Lateral size effect of graphene on mechanical properties of aluminum matrix nanolaminated composites’, Scripta Materialia, 2017, 139, pp. 44–48.

    Google Scholar 

  50. Zhang, L., Hou, G., Zhai, W., Ai, Q., Feng, J., Zhang, L., Si, P., and Ci, L.: ‘Aluminum/graphene composites with enhanced heat-dissipation properties by in-situ reduction of graphene oxide on aluminum particles’, Journal of Alloys and Compounds, 2018, 748, pp. 854–860.

    Google Scholar 

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Acknowledgements

The authors acknowledge the financial support of the Higher Education Commission of Pakistan (Grant No. 213-53249-2EG2-102) provided under the PhD indigenous fellowship; Phase-II Batch-II, as well as the Norwegian University of Science and Technology (NTNU), Norway, for the use of their laboratory facilities for characterisation of all material properties.

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Correspondence to Mahmood Khan .

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Khan, M., Ud-Din, R., Wadood, A., Syed, W.H., Akhtar, S., Aune, R.E. (2020). Spark Plasma Sintering of Graphene Nanoplatelets Reinforced Aluminium 6061 Alloy Composites. In: Tomsett, A. (eds) Light Metals 2020. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-36408-3_44

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