Abstract
This chapter deals with condensable/liquid compounds produced during biomass and waste thermal degradation processes. These compounds include a huge number of species, mainly organic, but also inorganic. These species may vary according to biomass or waste type, and even more according to process operating conditions, namely temperature, heating rate, reactive gas or pressure. For instance, liquids obtained during torrefaction and their related yields will be strongly different from those obtained during slow pyrolysis, fast pyrolysis or gasification. A general overview is therefore firstly given of the condensable/liquid compounds produced in each of the main thermal processes together with their typical mass yields. Then the emphasis is put on the challenging task of determination of composition in organic and inorganic species. The most common measurement techniques of these condensable/liquid compounds are detailed. For each technique, the principle and a typical experimental procedure are given, as well as the main advantages and drawbacks, notably regarding species detected, accuracy limits and thus suitability with the different thermal processes. Both online analysis methods, and offline methods are considered. In the case of offline analysis, particular attention is paid to the sample collection step, for instance through condensation in staged cooled vessels.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Libra, J.A., Ro, K.S., Kammann, C., Funke, A., Berge, N.D., Neubauer, Y., Titirici, M.M., Fühner, C., Bens, O., Kern, J., Emmerich, K.H.: Hydrothermal carbonization of biomass residuals: a comparative review of the chemistry, processes and applications of wet and dry pyrolysis. Biofuels 2, 71–106 (2011)
Nocquet, T., Dupont, C., Commandre, J.M., Grateau, M., Thiery, S., Salvador, S.: Volatile species release during torrefaction of wood and its macromolecular constituents: part 1—experimental study. Energy 72, 180–187 (2014)
Bridgwater, A.V.: Review of fast pyrolysis of biomass and product upgrading. Biomass Bioenergy 38, 68–94 (2012)
Kaltschmitt, M., Thrän, D.: Chapter 7. Biomass-based green energy generation. In: Hofer, R. (ed.) Sustainable Solutions for Modern Economies, pp. 86–124. RSC Publishing, Cambridge (2009)
Mohan, D., Pittman, C.U., Steele, P.H.: Pyrolysis of wood/biomass for bio-oil: a critical review. Energy Fuels 20, 848–889 (2006)
Stoytcheva, M.: Pesticides in the Modern World—Pesticides Use and Management. InTechOpen (2011)
Pyro Wiki: Welcome to PyroWiki. http://pyrowiki.pyroknown.eu/index.php?title=Welcome_to_PyroWiki (2018). 12 Jan 2018
Balat, M., Kırtay, E., Balat, H.: Main routes for the thermo-conversion of biomass into fuels and chemicals. Part 1: pyrolysis systems. Energy Convers. Manag. 50, 3147–3157 (2009)
Vitasari, C.R., Meindersma, G.W., de Haan, A.B.: Conceptual process design of an integrated bio-based acetic acid, glycolaldehyde, and acetol production in a pyrolysis oil-based biorefinery. Chem. Eng. Res. Des. 95, 133–143 (2015)
Oasmaa, A., van de Beld, B., Saari, P., Elliott, D.C., Solantausta, Y.: Norms, standards, and legislation for fast pyrolysis bio-oils from lignocellulosic biomass. Energy Fuels 29, 2471–2484 (2015)
Anca-Couce, A., Mehrabian, R., Scharler, R., Obernberger, I.: Kinetic scheme of biomass pyrolysis considering secondary charring reactions. Energy Convers. Manag. 87, 687–696 (2014)
Anca-Couce, A., Brunner, T., Kanzian, W., Obernberger, I., Trattner, K.: Characterization and condensation behaviour of gravimetric tars produced during spruce torrefaction. J. Anal. Appl. Pyrol. 119, 173–179 (2016)
Oasmaa, A., Fonts, I., Pelaez-Samaniego, M.R., Garcia-Perez, M.E., Garcia-Perez, M.: Pyrolysis oil multiphase behavior and phase stability: a review. Energy Fuels 30, 6179–6200 (2016)
Bayerbach, R., Meier, D.: Characterization of the water-insoluble fraction from fast pyrolysis liquids (pyrolytic lignin). Part IV: structure elucidation of oligomeric molecules. J. Anal. Appl. Pyrol. 85, 98–107 (2009)
Anca-Couce, A.: Reaction mechanisms and multi-scale modelling of lignocellulosic biomass pyrolysis. Prog. Energy Combust. Sci. 53, 41–79 (2016)
Nachenius, R.W., Ronsse, F., Venderbosch, R.H., Prins, W.: Biomass pyrolysis. In: Murzin, D.Y. (ed.) Chemical Engineering for Renewables Conversion, pp. 75–139. Academic Press, Burlington (2013)
Branca, C., Di Blasi, C.: Kinetics of the isothermal degradation of wood in the temperature range 528–708 K. J. Anal. Appl. Pyrol. 67, 207–219 (2003)
Neves, D., Thunman, H., Matos, A., Tarelho, L., Gómez-Barea, L.: Characterization and prediction of biomass pyrolysis products. Prog. Energy Combust. Sci. 37, 611–630 (2011)
Evans, R.J., Milne, T.A.: Molecular characterization of the pyrolysis of biomass. Energy Fuels 1, 123–137 (1987)
Koppejan, J., Sokhansanj, S., Melin, S.: Status overview of torrefaction technologies (2012)
van der Stelt, M.J.C., Gerhauser, H., Kiel, J.H.A., Ptasinski, K.J.: Biomass upgrading by torrefaction for the production of biofuels: a review. Biomass Bioenergy (2011). https://doi.org/10.1016/j.biombioe.2011.06.023
Anca-Couce, A., Obernberger, I.: Application of a detailed biomass pyrolysis kinetic scheme to hardwood and softwood torrefaction. Fuel 167, 158–167 (2016)
González Martínez, M., Dupont, C., Thiéry, S., Meyer, X.M., Gourdon, C.: Impact of biomass diversity on torrefaction: study of solid conversion and volatile species formation through an innovative TGA-GC/MS apparatus. Biomass Bioenergy 119, 43–53 (2018)
Heidenreich, S., Foscolo, P.U.: New concepts in biomass gasification. Prog. Energy Combust. Sci. 46, 72–95 (2015)
Basu, P.: Biomass Gasification and Pyrolysis. Academic Press, Burlington (2010)
Staš, M., Chudoba, J., Kubička, D., Blažek, J., Pospíšil, M.: Petroleomic characterization of pyrolysis bio-oils: a review. Energy Fuels 31, 10283–10299 (2017)
ChemLibretexts: How an FTIR spectrometer operates. https://chem.libretexts.org/Core/Physical_and_Theoretical_Chemistry/Spectroscopy/Vibrational_Spectroscopy/Infrared_Spectroscopy/How_an_FTIR_Spectrometer_Operates (2018). Accessed on 1 Mar 2018
Ma, Z., Chen, D., Gu, J., Bao, B., Zhang, Q.: Determination of pyrolysis characteristics and kinetics of palm kernel shell using TGA–FTIR and model-free integral methods. Energy Convers. Manag. 89, 251–259 (2015)
Singh, S., Wu, C., Williams, P.T.: Pyrolysis of waste materials using TGA-MS and TGA-FTIR as complementary characterisation techniques. J. Anal. Appl. Pyrol. 94, 99–107 (2012)
Biagini, E., Barontini, F., Tognotti, L.: Devolatilization of biomass fuels and biomass components studied by TG/FTIR technique. Ind. Eng. Chem. Res. 45, 4486–4493 (2006)
De Jong, W., Pirone, A., Wojtowicz, M.: Pyrolysis of Miscanthus giganteus and wood pellets: TG-FTIR analysis and reaction kinetics. Fuel 82, 1139–1147 (2003)
Gao, N., Li, A., Quan, C., Du, L., Duan, Y.: TG–FTIR and Py–GC/MS analysis on pyrolysis and combustion of pine sawdust. J. Anal. Appl. Pyrol. 100, 26–32 (2013)
Giuntoli, J., de Jong, W., Arvelakis, S., Spliethoff, H., Verkooijen, A.H.M.: Quantitative and kinetic TG-FTIR study of biomass residue pyrolysis: dry distiller’s grains with solubles (DDGS) and chicken manure. J. Anal. Appl. Pyrol. 85, 301–312 (2009)
Tsamba, A.J., Yang, W., Blasiak, W., Wójtowicz, M.A.: Cashew nut shells pyrolysis: individual gas evolution rates and yields. Energy Fuels 21, 2357–2362 (2007)
Liu, Q., Zhong, Z., Wang, S., Luo, Z.: Interactions of biomass components during pyrolysis: a TG-FTIR study. J. Anal. Appl. Pyrol. 90, 213–218 (2011)
Bennadji, H., Smith, K., Shabangu, S., Fisher, E.M.: Low-temperature pyrolysis of woody biomass in the thermally thick regime. Energy Fuels 27, 1453–1459 (2013)
Anca-Couce, A., Sommersacher, P., Scharler, R.: Online experiments and modelling with a detailed reaction scheme of single particle biomass pyrolysis. J. Anal. Appl. Pyrol. 127, 411–425 (2017)
Colantoni, A., Evic, N., Lord, R., Retschitzegger, S., Proto, A.R., Gallucci, F., Monarca, D.: Characterization of biochars produced from pyrolysis of pelletized agricultural residues. Renew. Sustain. Energy Rev. 64, 187–194 (2016)
Chen, D., Liu, D., Zhang, H., Chen, Y., Li, Q.: Bamboo pyrolysis using TG–FTIR and a lab-scale reactor: analysis of pyrolysis behavior, product properties, and carbon and energy yields. Fuel 148, 79–86 (2015)
Lakowicz, J.R.: Principles of Fluorescence Spectroscopy, 3rd edn. Springer, New York (2006)
Skoog, D.A., Holler, F.J., Crouch, S.R.: Principles of Instrumental Analysis, 6th edn. Brooks Cole, Belmont (2007)
Kohse-Höinghaus, K., Jefferies, J.B.: Applied Combustion Diagnostics. CRC Press, New York (2002)
Brackmann, C., Sjöholm, J., Rosell, J., Richter, M., Bood, J., Aldén, M.: Picosecond excitation for reduction of photolytic effects in two-photon laser-induced fluorescence of CO. Proc. Combust. Inst. 34, 3541–3548 (2013)
Prins, M.J., Li, Z.S., Bastiaans, R.J.M., van Oijen, J.A., Aldén, M., de Goey, L.P.H.: Biomass pyrolysis in a heated-grid reactor: visualization of carbon monoxide and formaldehyde using laser-induced fluorescence. J. Anal. Appl. Pyrol. 92, 280–286 (2011)
Kohse-Höinghaus, K.: Laser techniques for the quantitative detection of reactive intermediates in combustion systems. Prog. Energy Combust. Sci. 20, 203–279 (1994)
Keller-Rudek, H., Moortgat, G.K., Sander, R., Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest. Earth Syst. Sci. Data 5, 365–373 (2013)
Grosch, H., Sárossy, Z., Egsgaard, H., Fateev, A.: UV absorption cross-sections of phenol and naphthalene at temperatures up to 500 °C. J. Quant. Spectrosc. Radiat. Transf. 156, 17–23 (2015)
Thöny, A., Rossi, M.J.: Gas-phase UV spectroscopy of anthracene, xanthone, pyrene, 1-bromopyrene and 1,2,4-trichlorobenzene at elevated temperatures. J. Photochem. Photobiol. Chem. 104, 25–33 (1997)
Gratien, A., Nilsson, E., Doussin, J.F., Johnson, M.S., Nielsen, C.J., Stenstrøm, Y., Picquet-Varrault, B.: UV and IR absorption cross-sections of HCHO, HCDO, and DCDO. J. Phys. Chem. A 111, 11506–11513 (2007)
Lang, N., Rupp, C., Almuina-Villar, H., Dieguez-Alonso, A., Behrendt, F., Röpcke, J.: Pyrolysis behavior of thermally thick wood particles: time-resolved characterization with laser based in-situ diagnostics. Fuel 210, 371–379 (2017)
Borgmeyer, Y., Neubauer, J.: Continuous on-line tar monitoring for process control. In: Proceedings of 24th European Biomass Conference and Exhibition (2016)
Borgmeyer, J., Continuous on-line tar monitoring in hot process gases from biomass gasification by means of fluorescence spectroscopy. PhD thesis, Technische Universität Berlin, Mar 2019, unpublished
Sun, R., Zobel, N., Neubauer, Y., Cardenas Chavez, C., Behrendt, F.: Analysis of gas-phase polycyclic aromatic hydrocarbon mixtures by laser-induced fluorescence. Opt. Lasers Eng. 48, 1231–1237 (2010)
Mitsakis, M.: Online analysis of the tar content of biomass gasification producer gas. Technische Universität München (2011)
Meng, X., Mitsakis, P., Mayerhofer, M., de Jong, W., Gaderer, M., Verkooijen, A.H.M., Spliethoff, H.: Tar formation in a steam-O2 blown CFB gasifier and a steam blown PBFB gasifier (BabyHPR): comparison between different on-line measurement techniques and the off-line SPA sampling and analysis method. Fuel Process. Technol. 100, 16–29 (2012)
Baumhakl, C., Karellas, S.: Tar analysis from biomass gasification by means of online fluorescence spectroscopy. Opt. Lasers Eng. 49, 885–891 (2011)
Dieguez-Alonso, A., Anca-Couce, A., Zobel, N.: On-line tar characterization from pyrolysis of wood particles in a technical-scale fixed-bed reactor by applying laser-induced fluorescence (LIF). J. Anal. Appl. Pyrol. 102, 33–46 (2013)
Dieguez-Alonso, A., Anca-Couce, A., Zobel, N., Behrendt, F.: Understanding the primary and secondary slow pyrolysis mechanisms of holocellulose, lignin and wood with laser-induced fluorescence. Fuel 153, 102–109 (2015)
Zobel, N., Anca-Couce, A.: Slow pyrolysis of wood particles: characterization of volatiles by laser-induced fluorescence. Proc. Combust. Inst. 34, 2355–2362 (2013)
Karellas, S., Karl, J.: Analysis of the product gas from biomass gasification by means of laser spectroscopy. Opt. Lasers Eng. 45, 935–946 (2007)
Bontemps, A.: Condensation de mélanges de vapeurs—Transfert de chaleur et de masse. Techniques de l’Ingénieur. BE9910 v1 (2001)
Tumuluru, J.S., Sokhansanj, S., Wright, C.T., Kremer, T.: GC analysis of volatiles and other products from biomass torrefaction process. Adv. Gas Chromatogr. Prog. Agr. Biomed. Ind. Appl. 211–234 (2012)
Robson, A.: Dynamotive 2000. Progress report. PyNe Newsletter (2000)
Bridgwater, A.: Renewable fuels and chemicals by thermal processing of biomass. Chem. Eng. J. 91, 87–102 (2003)
Chen, T., Deng, C., Liu, R.: Effect of selective condensation on the characterization of bio-oil from pine sawdust fast pyrolysis using a fluidized-bed reactor. Energy Fuels 24, 6616–6623 (2010)
Westerhof, R.J.M., Kuipers, N.J.M., Kersten, S.R.A., van Swaaij, W.P.M.: Controlling the water content of biomass fast pyrolysis oil. Ind. Eng. Chem. Res. 46, 9238–9247 (2007)
Jendoubi, N., Broust, F., Commandre, J.M., Mauviel, G., Sardin, M., Lédé, J.: Inorganics distribution in bio oils and char produced by biomass fast pyrolysis: the key role of aerosols. J. Anal. Appl. Pyrol. 92, 59–67 (2011)
Oasmaa, A., Sipilä, K., Solantausta, Y., Kuoppala, E.: Quality improvement of pyrolysis liquid: effect of light volatiles on the stability of pyrolysis liquids. Energy Fuels 19, 2556–2561 (2005)
Pollard, A.: Comparison of bio-oil produced in a fractionated bio-oil collection system. Iowa State University (2009)
AFNOR: Biomass gasification. Tar and particles in product gases. Sampling and analysis. DD CEN/TS 15439:2006 (2007)
Good, V., Ventress, L., Knoef, H., Zielke, U., Lyckhansen, P., van de Kamp, W., de Wild, P., Coda, S., van Paasen, S., Kiel, J., Sjöström, K., Liliedahl, T., Unger, C., Neeft, J., Suomalainen, M., Simel, L.: Sampling and analysis of tar and particles in biomass producer gases. Technical report prepared under CEN BT/TF 143 organic contaminants (“tar”) in biomass producer gases (2005)
Kern, S., Pfeifer, C., Hofbauer, H.: Gasification of wood in a dual fluidized bed gasifier: influence of fuel feeding on process performance. Chem. Eng. Sci. 90, 284–298 (2013)
Chromedia Analytical Sciences: Principles of SPME. http://www.chromedia.org/chromedia?waxtrapp=npuhcHsHiemBpdmBlIEcCKJ&subNav=abffyDsHiemBpdmBlIEcCtBDF (2018). Accessed on 2 Feb 2018
Comte, J.: Mise au point d’une méthodologie d’échantillonnage utilisant la micro-extraction sur phase solide pour la quantification de goudrons sur des procédés de thermolyse de la biomasse. Université Joseph Fourier, Grenoble I (2008)
Voinot, D.: Caractérisation des composés organiques volatils issus du séchage du bois. Application au chêne rouge et au pin gris. Université Laval (2007)
McGraw, G.W., Hemingway, R.W., Ingram, L.L., Canady, C.S., McGraw, W.B.: Thermal degradation of terpenes: camphene, Δ3-carene, limonene, and α-terpinene. Environ. Sci. Technol. 33, 4029–4033 (1999)
Tessini, C., Müller, N., Mardones, C., Meier, D., Berg, A., von Baer, D.: Chromatographic approaches for determination of low-molecular mass aldehydes in bio-oil. J. Chromatogr. A 1219, 154–160 (2012)
TurboMatrix: Turbomatrix series thermodesorbers. https://www.perkinelmer.com/lab-solutions/resources/docs/GDE_TurboMatrixTDATDUsersGuide.pdf (2015). Accessed on 30 June 2015
Simon, V., Riba, M.L., Waldhart, A., Torres, L.: Breakthrough volume of monoterpenes on Tenax TA: influence of temperature and concentration for α-pinene. J. Chromatogr. A 704, 465–471 (1995)
Dufour, A., Girods, P., Masson, E., Normand, S., Rogaume, Y., Zoulalian, A.: Comparison of two methods of measuring wood pyrolysis tar. J. Chromatogr. A 1164, 240–247 (2007)
Candelier, K., Dumarcay, S., Petrissans, A., Petrissans, M., Kamdem, P., Gerardin, P.: Thermodesorption coupled to GC-MS to characterize volatiles formation kinetic during wood thermodegradation. J. Anal. Appl. Pyrol. 101, 96–102 (2013)
Grob, R.L., Barry, E.F.: Modern Practice of Gas Chromatography. Wiley, Hoboken (2004)
Poole, C.F.: Ionization-based detectors for gas chromatography. J. Chromatogr. A 1421, 137–153 (2015)
Faiola, C.L., Erickson, M.H., Fricaud, V.L., Jobson, B.T., VanReken, T.M.: Quantification of biogenic volatile organic compounds with a flame ionization detector using the effective carbon number concept. Atmospheric Meas. Tech. 5, 1911–1923 (2012)
Wang, W.T., LeDonne, N.C., Ackerman, B., Sweeley, C.C.: Structural characterization of oligosaccharides by high-performance liquid chromatography, fast-atom bombardment-mass spectrometry, and exoglycosidase digestion. Anal. Biochem. 141, 366–381 (1984)
Sternberg, J.: Placental transfers: modern methods of study. Am. J. Obstet. Gynecol. 84, 1731–1748 (1962)
Dietz, A.J.: Biotransformation studies on 1-chloro-2, 3-propanediol dinitrate. J. Pharm. Sci. 56, 1664–1665 (1967)
Herthan, T., Moersch, O., Spliethoff, H., Berger, R.: The tar analyser—a suitable tool for the development and control of gasifiers and gas cleaning system. In: 1st World Conference on Biomass for Energy and Industry, Sevilla, Spain (2000)
Staš, M., Kubička, D., Chudoba, J., Pospíšil, M.: Overview of analytical methods used for chemical characterization of pyrolysis bio-oil. Energy Fuels 28(1), 385–402 (2014)
Snyder, L.R., Kirkland, J.J., Dolan, J.W.: Introduction to Modern Liquid Chromatography, 3rd edn. Wiley, Hoboken (2009)
Gennaro, M.C., Angelino, S.: Separation and determination of inorganic anions by reversed-phase high-performance liquid chromatography. J. Chromatogr. A 789, 181–194 (1997)
Chen, S.F., Mowery, R.A., Castleberry, V.A., van Walsum, G.P., Chambliss, C.K.: High-performance liquid chromatography method for simultaneous determination of aliphatic acid, aromatic acid and neutral degradation products in biomass pretreatment hydrolysates. J. Chromatogr. A 1104, 54–61 (2006)
Chheda, J.N., Román-Leshkov, Y., Dumesic, J.A.: Production of 5-hydroxymethylfurfural and furfural by dehydration of biomass-derived mono- and poly-saccharides. Green Chem. 9, 342–350 (2007)
Wheaton, R.M., Bauman, W.C.: Ion exclusion—a unit operation utilizing ion exchange materials. Ind. Eng. Chem. 45, 228–233 (1953)
Weiss, J., Schpigun, O.: Handbook of Ion Chromatography, 3 Volume Set, 4th edn. Wiley, Hoboken (2016)
Damay, J., Duret, X., Ghislain, T., Lalonde, O., Lavoie, J.M.: Steam explosion of sweet sorghum stems: optimisation of the production of sugars by response surface methodology combined with the severity factor. Ind. Crops Prod. 111, 482–493 (2018)
Scarlata, C.J., Hyman, D.A.: Development and validation of a fast high pressure liquid chromatography method for the analysis of lignocellulosic biomass hydrolysis and fermentation products. J. Chromatogr. A 1217, 2082–2087 (2010)
Tanaka, K., Haddad, P.R.: Ion exclusion chromatography: liquid chromatography. In: Wilson, I. (ed.) Encyclopedia of Separation Science, pp. 3193–3201. Academic Press, London (2000)
Tanaka, K., Ohta, K., Fritz, J.S., Lee, Y.S., Shim, S.B.: Ion-exclusion chromatography with conductimetric detection of aliphatic carboxylic acids on an H+-form cation-exchange resin column by elution with polyols and sugars. J. Chromatogr. A 706, 385–393 (1995)
Porath, J., Flodin, P.: Gel filtration: a method for desalting and group separation. Nature 183, 1657–1659 (1959)
Consultant, S.K.: The HPLC-MS Handbook for Practitioners. Wiley, Hoboken (2017)
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2020 Springer Nature Switzerland AG
About this chapter
Cite this chapter
Dupont, C. et al. (2020). Condensable and Liquid Compounds from Biomass and Waste Thermal Degradation. In: Nzihou, A. (eds) Handbook on Characterization of Biomass, Biowaste and Related By-products. Springer, Cham. https://doi.org/10.1007/978-3-030-35020-8_12
Download citation
DOI: https://doi.org/10.1007/978-3-030-35020-8_12
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-35019-2
Online ISBN: 978-3-030-35020-8
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)