Abstract
For the metrological assurance of the high-precision inductively coupled plasma (ICP) mass spectrometry and optical emission spectroscopy methods, the All-Russian Scientific Research Institute of Physical Technical and Radio Technical Measurements (VNIIFTRI) has launched works on the development of reference materials (RMs) of the mass fraction of metals in solutions specifically intended for measurements using inductively coupled plasma methods (ICP-CRM). The ICP-CRM under development was represented by a solution with the certified value of the lead mass fraction. The ICP-CRM was packed in high-density polyethylene bottles with the capacity of 4, 8, 15, 30, 60 and 125 cm3. The certified value of the lead mass fraction in the solution was established by the preparation method and confirmed by the GET 217-2018 State Primary Standard for units of the mass fraction and mass (molar) concentration of inorganic components in aqueous solutions based on gravimetric and spectral methods. The permissible certified values of the lead mass fraction in the developed IСP-CRM are shown to range from 800 mg/kg to 1200 mg/kg. The uncertainty in the certified value is expressed as expanded uncertainty, U = 0.5%, at 95% confidence and is calculated in accordance with ISO/IEC17025 according to GUM (Guidelines to Uncertainty in Measurement). The developed ICP-CRM solution of the lead mass fraction can be used for ensuring the metrological traceability of measurements in inorganic analyses using ICP-MS and ICP-OES to the GET 217-2018.
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Abbreviations
- GET 217-2018:
-
the State Primary Standard for units of the mass fraction and mass (molar) concentration of inorganic components in aqueous solutions based on gravimetric and spectral methods
- ICP CRM:
-
Reference materials intended for use in measurements using inductively coupled plasma
- ICP-MS:
-
Inductively coupled plasma mass spectrometry
- ICP-OES:
-
Inductively coupled plasma optical emission spectrometry
References
De Bièvre P, Dybkaer R, Fajgelj A, Hibbert DB (2011) Metrological traceability of measurement results in chemistry: Concepts and implementation (IUPAC technical report). Pure Appl Chem 83(10):1873–1935. https://doi.org/10.1351/PAC-REP-07-09-39
Federal law On ensuring the uniformity of measurements. No FZ-102 of 26.06.2008. http://fundmetrology.ru/depository/01_npa/102-fz_2015.pdf (in Russ.)
Turner BL, Bielnicka AW, Dalling JW, Wolf JA (2013) Interference by iron in the determination of boron by ICP-OES in mehlich-III extracts and total element digests of tropical forest soils. Commun Soil Sci Plant Anal 47(21):2378–2386
Mozafar A, Oertli JJ, Tuor D, Roesch T (1990) Calibration of ICP to reduce the interference of Na with the determination of K. Commun Soil Sci Plant Anal 21(13):1607–1617
Zbíral J (1996) Determination of potentially dangerous elements in soil extracts by atomic emission spectrophotometry-ICP: Correction of interferences. Commun Soil Sci Plant Anal 27(5):1527–1536
Morgalla MH, Mettenleiter H, Katzenberger T (1999) ICP measurement accuracy: the effect of temperature drift. Design of a laboratory test for assessment of ICP transducers. J Med Eng Technol 23(1):10–14. https://doi.org/10.1080/030919099294375
Zhong J, Dujovny M, Park HK, Perez E, Perlin AR, Diaz FG (2003) Advances in ICP monitoring techniques. Neurol Res 25(4):339–350
Pupyshev A, Surikov VT (2006) Inductively coupled plasma–Mass spectrometry. Formation of ions. UrO RAN, Ekaterinburg
Chung YS, Chung YJ, Cho KH, Lee JH Determination of trace and toxic elements in Korean rice CRM by INAA, ICP and AAS. J Radioanal Nucl Chem 215(1):129–134. https://doi.org/10.1007/bf02109888
Fernández-Turiel JL, Llorens JF, Roig A, Carnicero M, Valero F (2000) Monitoring of drinking water treatment plants using ICP-MS. Toxicol Environ Chem 74(1–2):87–103. https://doi.org/10.1080/02772240009358871
Št’astná M, Nĕmcová I, Zýka J (1999) ICP-MS for the determination of trace elements in clinical samples. Anal Lett 32(13):2531–2543
Masson P, Dalix T, Bussière S (2010) Determination of major and trace elements in plant samples by inductively coupled plasma–mass spectrometry. Commun Soil Sci Plant Anal 41(3):231–243. https://doi.org/10.1080/00103620903460757
Konda SK, Kiran B, Hardaway CJ, Sneddon J (2014) Determination of copper, iron, lead, magnesium, manganese, and potassium in rice from India and United States by inductively coupled plasma-optical emission spectrometry. Instrum Sci Technol 42(6):646–651. https://doi.org/10.1080/10739149.2014.919510
Stepin BD, Tsvetkov AA (1994) Inorganic chemistry. Higher school, Moscow
Ellison R, Williams A (eds) (2012) Quantifying uncertainty in analytical measurement. In: Eurachem/CITAC guide, 3rd edn. https://www.eurachem.org/index.php/publications/guides/quam
GOST R 54500.3-2011. Uncertainty of measurement. Part 3. Guide to the expression of uncertainty in measurement. Standardinform, Moscow, 2012 (in Russ.)
Author Contribution Statement
Stakheev A. A.: development of the research concept and the article concept, critical revision of the manuscript.
Stolboushkina T. P.: conducting experiments, obtaining experimental data, development of preparation and measurement methods, literature review.
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Stakheev, A.A., Stolboushkina, T.P. (2020). Development and Testing of a Certified Reference Material of the Lead Mass Fraction in Solutions for Measurements Using Inductively Coupled Plasma Methods. In: Medvedevskikh, S., Kremleva, O., Vasil’eva, I., Sobina, E. (eds) Reference Materials in Measurement and Technology. RMMT 2018. Springer, Cham. https://doi.org/10.1007/978-3-030-32534-3_12
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DOI: https://doi.org/10.1007/978-3-030-32534-3_12
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