Skip to main content

Luminescence Properties of a Novel Eu3+ Dinuclear Coordination Compound

  • Conference paper
  • First Online:
4th International Conference on Nanotechnologies and Biomedical Engineering (ICNBME 2019)

Part of the book series: IFMBE Proceedings ((IFMBE,volume 77))

  • 1263 Accesses

Abstract

The paper presents experimental results on a novel Eu3+ dinuclear coordination compound [Eu(µ2-OC2H5)(NO)3(phen)]2·phen with high emission quantum yield. The complex has been characterized by photoluminescence (PL) spectroscopy. The absolute PL quantum yield, and the sensitization efficiency were determined to be 49.2% and 78.7% respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Hanninen, P., Harma, H. (eds.): Lanthanide luminescence. Photophysical, analytical and biological aspects. In: Wolfbeis, O.S. (Series ed.), Springer Series on Fluorescence, Methods and Applications, vol. 7. Springer-Verlag, Berlin Heidelberg (2011)

    Google Scholar 

  2. Lakowicz, J.R.: Principles of Fluorescence Spectroscopy, 2nd edn. Kluwer Academic Plenum Publishers, New York, Boston, Dordrrecht, London (1999)

    Google Scholar 

  3. Blasse, G., Grabmaier, B.C.: Luminescent Materials. Springer (1994)

    Google Scholar 

  4. Eliseeva, V., Bunzli, J.-C.G.: Lanthanide luminescence for functional materials and bio-sciences. Chem. Soc. Rev. 39, 189–227 (2010)

    Article  Google Scholar 

  5. Demchenko, A.P.: Introduction to Fluorescence Sensing, 2nd edn. Springer International Publishing Switzerland (2015). ISBN 978-3-319-20779-7 ISBN 978-3-319-20780-3 (eBook), https://doi.org/10.1007/978-3-319-20780-3

    Book  Google Scholar 

  6. Bordian, O., Verlan, V., Culeac, I., Iovu, M., Bulhac, I., Zubarev, V., Enachescu, M.: Cerere de brevet de invenţie, Nr deposit a2018 0063 din data 2018.08.17

    Google Scholar 

  7. Bordian, O., Verlan, V., Culeac, I., Iovu, M., Bulhac, I., Zubarev, V.: Synthesis, absorption and photoluminescence properties of the new coordination compound Eu(DBM)3(Ph3PO)1H2O. In: Vladescu, M., Tamas, R., Cristea, I. (eds.), Advanced Topics in Optoelectronics, Microelectronics, and Nanotechnologies IX, Proc. of SPIE vol. 10977, 109771E ©2018 SPIE CCC code: 0277-786X/18/$18, https://doi.org/10.1117/12.2323761

  8. Obtaining Absolute Quantum Yields Using an Integrating Sphere, Application Note FP-0008, Application Library: http://www.jascoinc.com/applications

  9. Rurack, K.: Fluorescence Quantum Yields: Methods of Determination and Standards. In: Springer Ser. Fluoresc., vol. 5, pp. 101–145 (2008). Springer, Berlin Heidelberg Published online: 11 March 2008. https://doi.org/10.1007/4243_2008_019

    Google Scholar 

  10. http://www.otsukael.com/product/detail/productid/9/category1id/3/category2id/8/category3id/10

  11. Binnemans, K.: Review: Interpretation of europium(III) spectra. Coord. Chem. Rev. 295, 1–45 (2015)

    Article  Google Scholar 

  12. Binnemans, K., Van Deun, R., Gorller-Walrand, C., Collinson, S.R., Martin, F., Bruce, D.W., Wickleder, C.: Spectroscopic behaviour of lanthanide(III) coordination compounds with Schiff base ligands. Phys. Chem. Chem. Phys. 2, 3753–3757. https://doi.org/10.1039/b003379k

    Article  Google Scholar 

  13. Jean, C.G.: Bünzli and Georges Olivier Pradervand, The Eu(III) ion as luminescent probe: Laser spectroscopic investigation of the metal ion sites in an 18crown6 complex. J. Chem. Phys. 85, 2489 (1986). https://doi.org/10.1063/1.451057

    Article  Google Scholar 

  14. Bunzli, J.-C.G., Eliseeva, S.V.: Basics of Lanthanide Photophysics. In: Hanninen, P., Harma, H. (eds.), Lanthanide Luminescence: Photophysical, Analytical and Biological Aspects, Springer Ser Fluoresc. Springer-Verlag, Berlin Heidelberg (2010). https://doi.org/10.1007/4243_2010_3

    Google Scholar 

  15. Banski, M., Podhorodecki, A., Misiewicz, J.: Influence of sol-gel matrices on the optical excitation of europium ions. Mater. Scie. Poland 28(1) (2010)

    Google Scholar 

  16. Zhao, Z., Zenga, Q.G., Zhanga, Z.M., Ding, Z.J.: J. Lumin. 122, 862 (2007)

    Article  Google Scholar 

  17. Bunzil, J.C., Choppin, G.R. (eds.): Lanthanide Probes in Life, Chemical and Earth Sciences: Theory and Practice. Elsevier, Amsterdam-Oxford-New York–Tokyo (1989)

    Google Scholar 

  18. Culeac, I.P., Verlan, V.I., Bordian, O., Zubareva, V.E., Bulhac, I.F., Iovu, M.S., Enachescu, M., Siminel, N.A., Siminel, A.V.: Synthesis and Characterisation of Novel Photoluminescent Eu(III) Dinuclear Coordination Compound (to be published)

    Google Scholar 

Download references

Conflict of Interest

The authors declare that they have no conflict of interest.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to I. P. Culeac .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2020 Springer Nature Switzerland AG

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Verlan, V.I. et al. (2020). Luminescence Properties of a Novel Eu3+ Dinuclear Coordination Compound. In: Tiginyanu, I., Sontea, V., Railean, S. (eds) 4th International Conference on Nanotechnologies and Biomedical Engineering. ICNBME 2019. IFMBE Proceedings, vol 77. Springer, Cham. https://doi.org/10.1007/978-3-030-31866-6_33

Download citation

  • DOI: https://doi.org/10.1007/978-3-030-31866-6_33

  • Published:

  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-030-31865-9

  • Online ISBN: 978-3-030-31866-6

  • eBook Packages: EngineeringEngineering (R0)

Publish with us

Policies and ethics