Abstract
Extensive research on ferrite-based materials and their application in field of electronics is of great importance in near future. In the last decade, several experiments have been conducted for developing different forms of ferrite-based materials through controlling its size, composition, and morphology. Such studies indicate that the chemical and physical properties of these materials can in principle be manipulated based on the desired application and are highly relevant from the technological point of view. However, the relationship between the closed structure and the composition of these advanced nanoscale materials is still debatable. In this chapter, the chemical structure of spinel ferrite nanoparticles has been studied using crystal engineering. It is quite evident that the change in the morphology of its particles and in the degree of defects alter their magnetic, optical and catalytic properties significantly. This makes these materials suitable for use in electronic devices such as high-density recording media and as a medical guide.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Naseri, M.G., Saion, E.B., Ahangar, H.A., Hashim, M., Shaari, A.H.: Simple preparation and characterization of nickel ferrite nanocrystals by a thermal treatment method. Powder Technol. 212(1), 80–88 (2011)
Editors of Encyclopaedia Britannica: Ferrite—Iron Oxide Compound [Online]. Available: https://www.britannica.com/science/ferrite-iron-oxide-compound
Joy, D.C.: Chemical analysis of ferrites. Talanta Rev. 30, 299–315 (1983)
Chen, C.H.: Magnetism and Metallurgy of Solt Magnetic Materials. Courier Dover Publications (1986)
Cullity, B.D.: Introduction to Magnetic Materials. Addison-Wesley, MA (1972)
Griffiths, D.J.: Introdution to Electrodynamics, 3rd edn. N. J. Prentice Hall, Upper Saddle River (1999)
Jiles, D.: Introduction to Magnetism and Magnetic Materials (1991)
Moskowitz, B.M.: Hitchhiker Guide to Magnetism, 3rd edn. (2006)
Sinnecker, J., Grossinger, R., Turtelli, R.S., Exel, G., Greifeneder, G., Kuss, C.: J. Magn. Magn. Mater., 194 (1994)
Hsu, C., McGuire, T.R.: Magnetism and Magnetic Materials. Academic Press, New York (1968)
Airimioaei, M., et al.: Synthesis and functional properties of the Ni1−xMnxFe2O4 ferrites. J. Alloys Compd. 509(31), 8065–8072 (2011)
González-Carreño, T., Morales, M.P., Serna, C.J.: Barium ferrite nanoparticles prepared directly by aerosol pyrolysis. Mater. Lett. 43(3), 97–101 (2000)
Bate, G.: Magnetic recording materials since 1975. J. Magn. Magn. Mater. 100(1–3), 413–424 (1991)
Joseyphus, R.J., Narayanasamy, A., Nigam, A.K., Krishnan, R.: Effect of mechanical milling on the magnetic properties of garnets. J. Magn. Magn. Mater. 296(1), 57–64 (2006)
Garskaite, E., et al.: On the synthesis and characterization of iron-containing garnets (Y3Fe5O12, YIG and Fe3Al5O12, IAG). Chem. Phys. 323(2–3), 204–210 (2006)
Niaz Akhtar, M., et al.: Y3Fe5O12 nanoparticulate garnet ferrites: comprehensive study on the synthesis and characterization fabricated by various routes. J. Magn. Magn. Mater. 368, 393–400 (2014)
Andersen, H.L., Saura-Múzquiz, M., Granados-Miralles, C., Canévet, E., Lock, N., Christensen, M.: Crystalline and magnetic structure-property relationship in spinel ferrite nanoparticles. Nanoscale 10(31), 14902–14914 (2018)
Lazarević, Z.Ž., et al.: Nanodimensional spinel NiFe2O4 and ZnFe2O4 ferrites prepared by soft mechanochemical synthesis. J. Appl. Phys. 113(18), 0–11 (2013)
Smit, J.: Ferrites: Physical Properties of Ferrimagnetic Oxides in Relation to Their Technical Application (1959)
Zhang, Y., Shi, Q., Schliesser, J., Woodfield, B.F., Nan, Z.: Magnetic and thermodynamic properties of nanosized Zn ferrite with normal spinal structure synthesized using a facile method. Inorg. Chem. 53(19), 10463–10470 (2014)
Thomas, J.J., Shinde, A.B., Krishna, P.S.R., Kalarikkal, N.: Temperature dependent neutron diffraction and Mössbauer studies in zinc ferrite nanoparticles. Mater. Res. Bull. 48(4), 1506–1511 (2013)
Pottker, W.E., et al.: Influence of order-disorder effects on the magnetic and optical properties of NiFe2O4 nanoparticles. Ceram. Int. 44(14), 17290–17297 (2018)
Chen, D., Chen, D., Jiao, X., Zhao, Y., He, M.: Hydrothermal synthesis and characterization of octahedral nickel ferrite particles. Powder Technol. 133(1–3), 247–250 (2003)
Sutka, A., Mezinskis, G.: Sol-gel auto-combustion synthesis of spinel-type ferrite nanomaterials. Front. Mater. Sci. 6(2), 128–141 (2012)
Hessien, M.M., Rashad, M.M., El-Barawy, K.: Controlling the composition and magnetic properties of strontium hexaferrite synthesized by co-precipitation method. J. Magn. Magn. Mater. 320(3–4), 336–343 (2008)
Chen, D., Jiao, X., Cheng, G.: Hydrothermal synthesis of zinc oxide powders with different morphologies. Solid State Commun. 113(6), 363–366 (1999)
Sapieszko, R.S., Matijevic, E.: Preparation of well defined colloidal particles by thermal decomposition of metal chelates—2. Cobalt and nickel. Corrosion 36(10), 522–530 (1980)
Dell’Agli, G.M.G.: Hydrothermal synthesis of ZrO2-Y2O3 solid solutions at low temperature. J. Eur. Ceram. Soc. 20, 139–145 (2000)
Burda, C., Chen, X., Narayanan, R., El-sayed, M.A.: Chemistry and Properties of Nanocrystals of Different Shapes (2005)
Wang, X., Zhuang, J., Peng, Q., Li, Y.: A general strategy for nanocrystal synthesis. Nature 437(7055), 121–124 (2005)
Lu, A.H., Salabas, E.L., Schüth, F.: Magnetic nanoparticles: synthesis, protection, functionalization, and application. Angew. Chem. Int. Ed. 46(8), 1222–1244 (2007)
Wang, J.: Prepare highly crystalline NiFe2O4 nanoparticles with improved magnetic properties. Mater. Sci. Eng. B Solid-State Mater. Adv. Technol. 127(1), 81–84 (2006)
Xie, H., Shen, D., Wang, X., Shen, G.: Microwave hydrothermal synthesis and visible-light photocatalytic activity of γ-Bi2MoO6 nanoplates. Mater. Chem. Phys. 110(2–3), 332–336 (2008)
Verma, S., Joy, P.A., Khollam, Y.B., Potdar, H.S., Deshpande, S.B.: Synthesis of nanosized MgFe2O4 powders by microwave hydrothermal method. Mater. Lett. 58(6), 1092–1095 (2004)
Kim, C.K., Lee, J.H., Katoh, S., Murakami, R., Yoshimura, M.: Synthesis of Co-, Co-Zn and Ni-Zn ferrite powders by the microwave-hydrothermal method. Mater. Res. Bull. 36(12), 2241–2250 (2001)
Khollam, Y.: Microwave hydrothermal preparation of submicron-sized spherical magnetite (Fe3O4) powders. Mater. Lett. 56(October), 571–577 (2002)
Bensebaa, F., Zavaliche, F., L’Ecuyer, P., Cochrane, R.W., Veres, T.: Microwave synthesis and characterization of Co-ferrite nanoparticles. J. Colloid Interface Sci. 277(1), 104–110 (2004)
Kumada, N.K.N., Komarneni, S.: Microwave hydrothermal synthesis of ABi2O6 (A = Mg, Zn). Mater. Lett. 33(9), 1411–1414 (1998)
Khollam, Y.B., Deshpande, S.B., Khanna, P.K., Joy, P.A., Potdar, H.S.: Microwave-accelerated hydrothermal synthesis of blue white phosphor: Sr2CeO4. Mater. Lett. 58(20), 2521–2524 (2004)
Abothu, I.R., Liu, S.F., Komarneni, S., Li, Q.H.: Processing of Pb(Zr0.52Ti0.48)O3 (PZT) ceramics from microwave and conventional hydrothermal powders. Mater. Res. Bull. 34(9), 1411–1419 (1999)
Vadivel Murugan, A., Sonawane, R.S., Kale, B.B., Apte, S.K., Kulkarni, A.V.: Microwave-solvothermal synthesis of nanocrystalline cadmium sulfide. Mater. Chem. Phys. 71(1), 98–102 (2001)
Khollam, Y.B., Deshpande, A.S., Patil, A.J., Potdar, H.S., Deshpande, S.B., Date, S.K.: Synthesis of yttria stabilized cubic zirconia (YSZ) powders by microwave-hydrothermal route. Mater. Chem. Phys. 71(3), 235–241 (2001)
Selvan, R.K., Augustin, C.O., Berchmans, L.J., Saraswathi, R.: Combustion synthesis of CuFe2O4. Mater. Res. Bull. 38(1), 41–54 (2003)
Sertkol, M., Köseoǧlu, Y., Baykal, A., Kavas, H., Toprak, M.S.: Synthesis and magnetic characterization of Zn0.7Ni0.3Fe2O4 nanoparticles via microwave-assisted combustion route. J. Magn. Magn. Mater. 322(7), 866–871 (2010)
Yu, L., Cao, S., Liu, Y., Wang, J., Jing, C., Zhang, J.: Thermal and structural analysis on the nanocrystalline NiCuZn ferrite synthesis in different atmospheres. J. Magn. Magn. Mater. 301(1), 100–106 (2006)
Wu, K.H., Ting, T.H., Li, M.C., Ho, W.D.: Sol-gel auto-combustion synthesis of SiO2-doped NiZn ferrite by using various fuels. J. Magn. Magn. Mater. 298(1), 25–32 (2006)
Costa, A.C.F.M., Morelli, M.R., Kiminami, R.H.G.A.: Microstructure and magnetic properties of Ni1−xZnxFe2O4 synthesized by combustion reaction. J. Mater. Sci. 42(3), 779–783 (2007)
George, M., Mary John, A., Nair, S.S., Joy, P.A., Anantharaman, M.R.: Finite size effects on the structural and magnetic properties of sol-gel synthesized NiFe2O4 powders. J. Magn. Magn. Mater. 302(1), 190–195 (2006)
Mukasyan, A.S., Epstein, P., Dinka, P.: Solution combustion synthesis of nanomaterials solution combustion synthesis of nanomaterials. Proc. Combust. Inst. 31(Jan 2007), 1789–1795 (2016)
Cao, G.: Nanostructures & Nanomaterials, 2nd edn. Imperial College Press, University of Washington, USA (2004)
Masip, E.M.: Síntesis electroquímica de nanopartículas de ferrita de cobalto, caracterizacíon y aplicaciones biomédicas. Dissertação, p. 220 (2015)
Goldman, A.: Modem Ferrite Technology, 2nd edn. Springer, Pittsburgh, PA, USA (2006)
Snelling, E.C.: Soft Ferrites: Properties and Applications, 1a edn. Iliffe (1969)
Buschow, K.H.J. (ed.) Handbook of Magnetic Materials, p. 542. Van der Waals-Zeeman Institute University of Amsterdam; Elsevier, Netherlands (2006)
Sivakumar, N., Narayanasamy, A., Shinoda, K., Chinnasamy, C.N., Jeyadevan, B., Greneche, J.M.: Electrical and magnetic properties of chemically derived nanocrystalline cobalt ferrite. J. Appl. Phys. 102(1), 013916 (2007)
Shiau, F.-S., Fang, T.-T., Leu, T.-H.: Effect of particle-size distribution on the microstructural evolution in the intermediate stage of sintering. J. Am. Ceram. Soc. 80(2), 286–290 (2005)
Naidu, K.C.B., Madhuri, W.: Hydrothermal synthesis of NiFe2O4 nano-particles: structural, morphological, optical, electrical and magnetic properties. Bull. Mater. Sci. 40(2), 417–425 (2017)
Huo, J., Wei, M.: Characterization and magnetic properties of nanocrystalline nickel ferrite synthesized by hydrothermal method. Mater. Lett. 63(13–14), 1183–1184 (2009)
Moradmard, H., Farjami Shayesteh, S., Tohidi, P., Abbas, Z., Khaleghi, M.: Structural, magnetic and dielectric properties of magnesium doped nickel ferrite nanoparticles. J. Alloys Compd. 650, 116–122 (2015)
Wang, J., Ren, F., Yi, R., Yan, A., Qiu, G., Liu, X.: Solvothermal synthesis and magnetic properties of size-controlled nickel ferrite nanoparticles. J. Alloys Compd. 479(1–2), 791–796 (2009)
Hamdeh, H.H., Mahmoud, M.H., Elshahawy, A.M., Makhlouf, Salah A.: Synthesis of highly ordered 30 nm NiFe2O4 particles by the microwave-combustion method. J. Magn. Magn. Mater. 369, 55–61 (2014)
Issa, B., Obaidat, I.M., Albiss, B.A., Haik, Y.: Magnetic nanoparticles: Surface effects and properties related to biomedicine applications. Int. J. Mol. Sci. 14(11), 21266–21305 (2013)
Bean, C.P., Livingston, J.D.: Superparamagnetism. J. Appl. Phys. 30(4), S120–S129 (1959)
Kotnala, R.K., Shah, J.: Ferrite Materials: Nano to Spintronics Regime, vol. 23. Elsevier (2015)
Zhang, M., et al.: Size effects on magnetic properties of Ni0.5Zn0.5Fe2O4 prepared by sol-gel method. Adv. Mater. Sci. Eng. 044317(2010), 3–11 (2016)
Liu, C., Zhang, Z.J.: Size-dependent superparamagnetic properties of Mn spinel ferrite nanoparticles synthesized from reverse micelles. Chem. Mater. 13(6), 2092–2096 (2001)
Sechovský, V.: Magnetism in solids: general introduction. Encycl. Mater. Sci. Technol., 5018–5032 (2001)
Cullity, B.D.: Fine particles and thin films. In: Introduction to Magnetic Materials, p. 385. Addison-Wesley, Ed. London (1972)
Rikken, R.S.M., Nolte, R.J.M., Maan, J.C., Van Hest, J.C.M., Wilson, D.A., Christianen, P.C.M.: Manipulation of micro- and nanostructure motion with magnetic fields. Soft Matter 10(9), 1295–1308 (2014)
Li, L., et al.: Superparamagnetic iron oxide nanoparticles as MRI contrast agents for non-invasive stem cell labeling and tracking. Theranostics 3(8), 595–615 (2013)
Hutamaningtyas, E., Utari, Suharyana, Purnama, B., Wijayanta, A.T.: Effects of the synthesis temperature on the crystalline structure and the magnetic properties of cobalt ferrite nanoparticles prepared via coprecipitation. J. Korean Phys. Soc. 69(4), 584–588 (2016)
Šepelák, V., Schultze, D., Krumeich, F., Steinike, U., Becker, K.D.: Mechanically induced cation redistribution in magnesium ferrite and its thermal stability. Solid State Ionics 141–142, 677–682 (2001)
Maensiri, S., Masingboon, C., Boonchom, B., Seraphin, S.: A simple route to synthesize nickel ferrite (NiFe2O4) nanoparticles using egg white. Scr. Mater. 56(9), 797–800 (2007)
Lu, L.T., et al.: Synthesis of magnetic cobalt ferrite nanoparticles with controlled morphology, monodispersity and composition: the influence of solvent, surfactant, reductant and synthetic conditions. Nanoscale 7(46), 19596–19610 (2015)
El Maalam, K., et al.: The effects of synthesis conditions on the magnetic properties of zinc ferrite spinel nanoparticles. J. Phys. Conf. Ser. 758(1), 012008 (2016)
Berkowitz, A.E., Schuele, W.J.: Magnetic properties of some ferrite micropowders. J. Appl. Phys. 30(4), S134–S135 (1959)
Maaz, K., Mumtaz, A., Hasanain, S.K., Ceylan, A.: Synthesis and magnetic properties of cobalt ferrite (CoFe2O4) nanoparticles prepared by wet chemical route. J. Magn. Magn. Mater. 308(2), 289–295 (2007)
Lima, A.C., et al.: The effect of Sr2+ on the structure and magnetic properties of nanocrystalline cobalt ferrite. Mater. Lett. 145, 56–58 (2015)
Skomski, R.: Simple Models of Magnetism. New York (2008)
Qiu, J., Wang, C., Gu, M.: Photocatalytic properties and optical absorption of zinc ferrite nanometer films. Mater. Sci. Eng. B Solid State Mater. Adv. Technol. 112(1), 1–4 (2004)
Sapna, Budhiraja, N., Kumar, V., Singh, S.K.: Shape-controlled synthesis of superparamagnetic ZnFe2O4 hierarchical structures and their comparative structural, optical and magnetic properties. Ceram. Int. 45(1), 1067–1076 (2019)
Cao, Y., Qin, H., Niu, X., Jia, D.: Simple solid-state chemical synthesis and gas-sensing properties of spinel ferrite materials with different morphologies. Ceram. Int. 42(9), 10697–10703 (2016)
Singh, A., Singh, A., Singh, S., Tandon, P., Yadav, B.C., Yadav, R.R.: Synthesis, characterization and performance of zinc ferrite nanorods for room temperature sensing applications. J. Alloys Compd. 618, 475–483 (2015)
Spaldin, N.: Magnetic Material: Fundamentals and Device Applications (2003)
Aakash, A., Chowdhury, R., Das, D., Mukherjee, S.: Effect of doping of manganese ions on the structural and magnetic properties of nickel ferrite. Ceram. Int. 42(6), 7742–7747 (2016)
Zhang, C.F., Zhong, X.C., Yu, H.Y., Liu, Z.W., Zeng, D.C.: Effects of cobalt doping on the microstructure and magnetic properties of Mn-Zn ferrites prepared by the co-precipitation method. Phys. B Condens. Matter 404(16), 2327–2331 (2009)
Feng, J., Guo, L.Q., Xu, X., Qi, S.Y., Zhang, M.L.: Hydrothermal synthesis and characterization of Mn1−xZnxFe2O4 nanoparticles. Phys. B Condens. Matter 394(1), 100–103 (2007)
Justin Joseyphus, R., Narayanasamy, A., Shinoda, K., Jeyadevan, B., Tohji, K.: Synthesis and magnetic properties of the size-controlled Mn-Zn ferrite nanoparticles by oxidation method. J. Phys. Chem. Solids 67(7), 1510–1517 (2006)
Singh, A.K., Singh, A.K., Goel, T.C., Mendiratta, R.G.: High performance Ni-substituted Mn-Zn ferrites processed by soft chemical technique. J. Magn. Magn. Mater. 281(2–3), 276–280 (2004)
Singh, A.K., Goel, T.C., Mendiratta, R.G., Thakur, O.P., Prakash, C.: Magnetic properties of Mn-substituted Ni-Zn ferrites. J. Appl. Phys. 92(7), 3872–3876 (2002)
Naik, M.M., Naik, H.S.B., Nagaraju, G., Vinuth, M., Vinu, K., Rashmi, S.K.: Effect of aluminium doping on structural, optical, photocatalytic and antibacterial activity on nickel ferrite nanoparticles by sol–gel auto-combustion method. J. Mater. Sci.: Mater. Electron. 29(23), 20395–20414 (2018)
Lassoued, A., Lassoued, M.S., Dkhil, B., Ammar, S., Gadri, A.: Photocatalytic degradation of methyl orange dye by NiFe2O4 nanoparticles under visible irradiation: effect of varying the synthesis temperature. J. Mater. Sci.: Mater. Electron. 29(9), 7057–7067 (2018)
Jesudoss, S.K., et al.: Studies on the efficient dual performance of Mn1−xNixFe2O4 spinel nanoparticles in photodegradation and antibacterial activity. J. Photochem. Photobiol. B Biol. 165, 121–132 (2016)
Rashmi, S.K., Naik, H.S.B., Jayadevappa, H., Sudhamani, C.N., Patil, S.B., Naik, M.M.: Influence of Sm3+ ions on structural, optical and solar light driven photocatalytic activity of spinel MnFe2O4 nanoparticles. J. Solid State Chem. 255(June), 178–192 (2017)
Murashkina, A.A., Murzin, P.D., Rudakova, A.V., Ryabchuk, V.K., Emeline, A.V., Bahnemann, D.W.: Influence of the dopant concentration on the photocatalytic activity: Al-doped TiO2. J. Phys. Chem. C 119(44), 24695–24703 (2015)
Melo, R.S., Banerjee, P., Franco, A.: Hydrothermal synthesis of nickel doped cobalt ferrite nanoparticles: optical and magnetic properties. J. Mater. Sci.: Mater. Electron. 29(17), 14657–14667 (2018)
Brus, L.E.: Electron-electron and electron-hole interactions in small semiconductor crystallites: the size dependence of the lowest excited electronic state. J. Chem. Phys. 80(9), 4403–4409 (1984)
Ravindra, A.V., Padhan, P., Prellier, W.: Electronic structure and optical band gap of CoFe2O4 thin films. Appl. Phys. Lett. 101(16), 1–5 (2012)
Holinsworth, B.S., et al.: Chemical tuning of the optical band gap in spinel ferrites: CoFe2O4 vs NiFe2O4. Appl. Phys. Lett. 103(8), 2–6 (2013)
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2020 Springer Nature Switzerland AG
About this chapter
Cite this chapter
Silva, R.C., Pottker, W.E., Batista, A.S.A., Araujo, J.F.D.F., La Porta, F.d.A. (2020). Revised Fundamental Properties and Crystal Engineering of Spinel Ferrite Nanoparticles. In: La Porta, F., Taft, C. (eds) Emerging Research in Science and Engineering Based on Advanced Experimental and Computational Strategies. Engineering Materials. Springer, Cham. https://doi.org/10.1007/978-3-030-31403-3_20
Download citation
DOI: https://doi.org/10.1007/978-3-030-31403-3_20
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-31402-6
Online ISBN: 978-3-030-31403-3
eBook Packages: EngineeringEngineering (R0)