Abstract
Natural rubber (NR) is the most commonly used elastomer in the automotive industry thanks to its outstanding fatigue resistance. Strain-induced crystallization (SIC) is found to play a role of paramount importance in the great crack growth resistance of NR (Lindley, Int J Fracture 9:449–462, 1973). Typically, NR exhibits a lifetime reinforcement for non-relaxing loadings (Cadwell et al., 1940; Ruellan et al., 2019). At the microscopic scale, fatigue striations were observed on the fracture surface of Diabolo samples tested in fatigue. They are the signature of SIC (Cadwell et al., 1940; Le Cam et al., 2013; Le Cam et al., 2004). In order to provide additional information on the role of SIC in the fatigue crack growth resistance of NR, striations are investigated through post-mortem analysis after fatigue experiments using loading ranging from −0.25 to 0.25. No striation was observed in the case of tests performed at 90 °C. This confirms that the formation of striation requires a certain crystallinity level in the material. At 23 °C, two striation regimes were identified: small striation patches with different orientations (Regime 1) and zones with large and well-formed striations (Regime 2). Since fatigue striations are observed for all the loading ratios applied, they are therefore not the signature of the reinforcement. Nevertheless, increasing the minimum value of the strain amplified the striation phenomenon and the occurrence of Regime 2.
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References
S.M. Cadwell, R.A. Merril, C.M. Sloman, F.L. Yost, Dynamic fatigue life of rubber. Ind. Eng. Chem. Anal. Ed. 12, 19–23 (1940). (reprinted in Rubber Chem. and Tech. 1940;13:304-315)
J.H. Fielding, Flex life and crystallisation of synthetic rubber. Ind. Eng. Chem. 35, 1259–1261 (1943)
J.R. Beatty, Fatigue of rubber. Rubber Chem. Technol. 37, 1341–1364 (1964)
P.B. Lindley, Relation between hysteresis and the dynamic crack growth resistance of natural rubber. Int. J. Fract. 9, 449–462 (1973)
J.-B. Le Cam, B. Huneau, E. Verron, Fatigue damage in carbon black filled natural rubber under uni- and multiaxial loading conditions. Int. J. Fatigue 52, 82–94 (2013)
J.-B. Le Cam, B. Huneau, E. Verron, L. Gornet, Mechanism of fatigue crack growth in carbon black filled natural rubber. Macromolecules 37, 5011–5017 (2004)
J.-B. Le Cam, E. Toussaint, The mechanism of fatigue crack growth in rubbers under severe loading: the effect of stress-induced crystallization. Macromolecules 43, 4708–4714 (2010)
M. Flamm, J. Spreckels, T. Steinweger, U. Weltin, Effects of very high loads on fatigue life of NR elastomer materials. Int. J. Fatigue 33, 1189–1198 (2011)
L. Munoz, Etude exprimentale des mécanismes d’endommagement par fatigue dans les élastomères renforcés, PhD thesis. Université Claude Bernard Lyon 1, (2011)
B. Ruellan, J.-B.L. Cam, E. Robin, I. Jeanneau, F. Canévet, G. Mauvoisin, D. Loison, Fatigue crack growth in natural rubber: The role of SIC investigated through post-mortem analysis of fatigue striations. Eng. Fract. Mech. 201, 353–365 (2018)
N. André, Critère local d’amorcage de fissures en fatigue dans un élastomère de type NR, PhD thesis. Ecole Nationale Supérieure des Mines de Paris, (1999)
N. Saintier, Prévisions de la durée de vie en fatigue du NR, sous chargement multiaxial, PhD thesis. Ecole Nationale Supérieure des Mines de Paris, (2000)
B. Ruellan, J.-B. Le Cam, E. Robin, I. Jeanneau, F. Canévet, Fatigue of natural rubber under different temperatures. Int. J. Fatigue 124, 544–557 (2019). https://doi.org/10.1016/j.ijfatigue.2018.10.009
S. Beurrot-Borgarino, B. Huneau, E. Verron, P. Rublon, Strain-induced crystallization of carbon black-filled natural rubber during fatigue measured by in situ synchrotron X-ray diffraction. Int. J. Fatigue 47, 1–7 (2013)
S. Trabelsi, Etude statique et dynamique de la cristallisation des élastomères sous tension, PhD thesis. Université Paris XI Orsay, (2002)
W.V. Mars, A. Fatemi, Factors that affect the fatigue life of rubber: a literature survey. Rubber Chem. Technol. 77, 391–412 (2004)
J.-B. Le Cam, Endommagement en fatigue des élastomères, PhD Thesis. Ecole Centrale de Nantes, (2005)
Acknowledgements
The authors thank the Cooper Standard France company for supporting this work and for fruitful discussions. The authors thank also the National Center for Scientific Research (MRCT-CNRS and MI-CNRS) and Rennes Metropole for supporting this work financially. SEM images were performed at CMEBA facility (ScanMAT, University of Rennes 1), which received a financial support from the European Union (CPER-FEDER 2007-2014).
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Ruellan, B. et al. (2020). A Post Mortem Analysis of the Strain-Induced Crystallization Effects on Fatigue of Elastomers. In: Silberstein, M., Amirkhizi, A., Shuman, X., Beese, A., Berke, R., Pataky, G. (eds) Challenges in Mechanics of Time Dependent Materials, Fracture, Fatigue, Failure and Damage Evolution, Volume 2. Conference Proceedings of the Society for Experimental Mechanics Series. Springer, Cham. https://doi.org/10.1007/978-3-030-29986-6_16
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