Abstract
Regarding the increasing rate of greenhouse gases emission such as CO2, and subsequently the global warming issue, recovery of CO2 exhausted from industry, and also its utilization is of paramount importance. There are several practical methods to capture CO2 involving physical and chemical absorption, adsorption, membrane and cryogenic technologies, among which the chemical absorption through solvent commonly amines; e.g., primary, secondary and tertiary amines is considered to be most efficient method due to high CO2 capacity arising from the reaction taking place between the solvent and CO2. However, two major obstacles encounter this method including high energy requirement for solvent regeneration and developing novel solvent to enhance CO2 absorption capacity, when conventional absorption/desorption process is applied.
To address the mentioned obstacles, one can either employ membrane technology or develop more suitable chemical solvents. Many investigators have dealt with developing novel solvents including blending of amin-based solvents, potassium carbonate, metal hydroxide solutions e.g., Sodium hydroxide, ammonia aqueous solution. In addition, membrane technology can either be applied for both absorption and desorption process simultaneously, or it can be joined to the conventional process. If it is aimed to join membrane technology with the conventional process, some novel processes including membrane flash, electrodialysis membrane and electrolysis membrane are substituted with the desorption section of the conventional processes.
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Abbreviations
- AEM:
-
Anion exchange membrane
- AHPD:
-
2-amino-2-hydroxymethyl-1,3-propanediol
- AMP:
-
2-amino-2-methyl-1-propanol
- BPM:
-
Bipolar membrane
- C2H4O:
-
Ethylene oxide
- C8H23N5:
-
Tetraethylenepentamine
- CEM:
-
Cation exchange membrane
- CFC:
-
Chlorofluorocarbons
- CH3:
-
Methyl
- CH4:
-
Methane
- CO2:
-
Carbon dioxide
- DEPG:
-
Dimethyl ether of polyethylene glycol
- ETA:
-
Ethanolamine
- H3AsO3:
-
Arsenious acid
- H3BO3:
-
Boric acid
- IPCC:
-
Intergovernmental Panel on Climate Change
- K2CO3:
-
potassium carbonate
- MDEA:
-
Methyldiethanolamine
- MEA:
-
Monoethanolamine
- MeOH:
-
Methanol
- NaHCO3:
-
Sodium bicarbonate
- NaOH:
-
Sodium hydroxide
- NH3:
-
Ammonia
- NMP:
-
Normal methyl pyrrolidone
- NO:
-
Nitrogen Oxide
- O2:
-
Oxygen
- PC:
-
Propylene carbonate
- PE:
-
polyethylene
- PFA:
-
Poly(tetrafluoroethylen-co-perfluorovinylether)
- PM:
-
2-Piperadine methanol
- PP:
-
Polypropylene
- PTFE:
-
Polytetrafluoroethylene
- PVDF:
-
Polyvinylidene fluoride
- PZ:
-
Piperazine
- PZEA:
-
2-(1-piperazinyl)-ethylamine
- SF6:
-
Sulfur hexafluoride
- SO2:
-
Sulfur dioxide
- SOx:
-
Sulfur Oxides
- TBP:
-
Tributyl phosphate
- T-S1:
-
Titanium silicate
- UOP LLC:
-
Universal Oil Products
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Ebrahimzadeh Sarvestani, M., Raeisi, M., Rahimpour, M.R. (2019). Methods for the Recovery of CO2 from Chemical Solvents. In: Inamuddin, Asiri, A., Lichtfouse, E. (eds) Sustainable Agriculture Reviews 38. Sustainable Agriculture Reviews, vol 38. Springer, Cham. https://doi.org/10.1007/978-3-030-29337-6_9
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