Ionic Liquids for Carbon Dioxide Capture

Raeisi, Maryam; Keshavarz, Amineh; Rahimpour, Mohammad Reza

doi:10.1007/978-3-030-29337-6_8

Maryam Raeisi⁷,
Amineh Keshavarz⁸ &
Mohammad Reza Rahimpour ORCID: orcid.org/0000-0002-1643-3105⁸

Part of the book series: Sustainable Agriculture Reviews ((SARV,volume 38))

664 Accesses

Abstract

The emissions of anthropogenic carbon dioxide have been considered as the noticeable contributor to the global warming. Many technologies are developed to mitigate the global warming issue through controling the emission of greenhous gasses into the environment. Among the existing methods, post-combustion process is a very promising approach for capturing carbon dioxide. In this regard, various solvents such as amine-based solvents have been employed. The ionic liquid has also shown a great potential as a solvent for capturing carbon dioxide, recently.

In this chapter, various properties of ionic liquids such as selectivity and solubility of carbon dioxide will be discussed. Besides, previous researches in this regards will be reviewed. Furthermore, various strategies for improving the performance of ionic liquid will be introduced. Finally, the economic aspects of carbon dioxide capture process through ionic liquids, which is of paramount importance in the industrial scale, will be evaluated.

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Abbreviations

([hmim] [hFAP]):: 1-hexyl-3- methylimidazolium tris(heptafluoropropyl)trifluorophosphate
([P14666][Cl]):: trihexyl(tetradecyl)phosphonium chloride
[aP₄₄₄₃][AA]:: dual aminofunctionalized phosphonium ionic liquids
[BF₄]:: tetrafluoroborate
[bmim] [Br]:: 1-butyl-3-methylimidazolium bromide
[bmim] [DCA]:: 1-butyl-3-methylimidazolium dicyanamid
[bmim][BF₄]:: 1-butyl-3-methylimidazolium tetrafluoroborate
[bmim][PF₆]:: 1-butyl-3-methyl-imidazolium hexafluorophosphate
[bmim][TFO]:: 1-butyl-3-methylimidazolium trifluoromethanesulfonate
[C₂mim][CH₃CO₂]:: 1-ethyl-3-methyl-1H-imidazolium acetate
[C₂mim][NFO]:: 1-ethyl-3-methyl-1H-imidazolium nonafluorobutanesulfonate
[C₂mim][NO₂]:: 1-ethyl-3-methyl-1H-imidazolium nitrite
[C₂mim][NO₃]:: 1-ethyl-3-methyl-1H-imidazolium nitrate
[C₂mim][TFO]:: 1-ethyl-3-methyl-1H-imidazolium trifluoromethane sulfonate
[C₂mim][BF₄]:: 1-ethyl-3-methylimidazolium tetrafluoroborate
[C₂mim][CF₃SO₃]:: 1-ethyl-3-methylimidazolium trifluoromethanesulfonate
[C₂mim][CH3COO]:: 1-ethyl-3-methylimidazolium trifluoroacetate
[C₂mim][Cl]:: 1-ethyl-3-methylimidazolium chloride
[C₂mim][I]:: 1-ethyl-3-methylimidazolium iodide
[C₂mim][OTF]:: 1-ethyl-3-methylimidazolium triflate
[C₂mim][PF₆]:: 1-ethyl-3-methyl-1H-imidazolium hexafluorophosphate
[C₂mim][TF₂N]:: 1-ethyl-3-methyl-1H-imidazolium bis((trifluoromethyl)sulfonyl)imide
[C₃mim][Cl]:: 1-propyl-3-methylimidazolium chloride
[C₃mim][PF₆]:: 1- propyl −3-propylimidazolium hexafluorophosphate
[C₃mim][TF₂N]:: 1-propyl-3-methylimidazolium bis(trifluoromethyl)sulfonyl)imide
[C₄mim][BF₄]:: 1-butyl-3-methylimidazolium tetrafluoroborate
[C₄mim][NFO]:: 1-butyl-3-methylimidazolium nonafluorobutanesulfonate
[C₄mim][TFO]:: 1-butyl-3-methylimidazolium trifluoromethane sulfonate
[C₄mim][CF₃COO]:: 1-butyl-3-methylimidazolium trifluoroacetate
[C₄mim][Cl]:: 1-butyl-3-methylimidazolium chloride
[C₄mim][I]:: 1-butyl-3-methylimidazolium iodide
[C₄mim][PF₆]:: 1-butyl-3-methylimidazolium hexafluorophosphate
[C₄mim][TF₂N]:: 1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide
[C₆mim][BF₄]:: 1-hexyl-3-methylimidazolium tetrafluoroborate
[C₆mim][Cl]:: 1-hexyl-3-methylimidazolium chloride
[C₆mim][PF₆]:: 1-hexyl-3-methylimidazolium hexafluorophosphate
[C₈mim][BF₄]:: 1-octyl-3-methylimidazolium tetrafluoroborate
[C₈mim][Cl]:: 1-octyl-3-methylimidazolium chloride
[C₈mim][PF₆]:: 1-octyl-3-methylimidazolium hexafluorophosphate
[CH₃SO₄]:: methyl sulfate
[emim][ESO₄]:: 1-ethyl-3-methylimidazolium ethyl sulfate
[emim][TFO]:: 1-ethyl-3-methylimidazolium trifluoromethanesulfonate
[hmim] [TFO]:: 1-hexyl-3-methylimidazolium trifluoromethanesulfonate
[hmim][BF₄]:: 1-hexyl-3-methylimidazolium tetrafluoroborat
[hmim][PF₆]:: 1-hexyl-3-methylimidazolium hexafluorophosphate
[N1888][Tf₂N]:: methyltrioctylammonium bis(trifluoromethylsulfonyl)imide
[N-bupy][BF₄]:: N-butylpyridinium tetrafluoroborate
[NO3]:: nitrate
[omim][Cl]:: 1-octyl-3-methylimidazolium chloride
[P(C4)4][AA]:: tetrabutylphosphonium amino acid
[P(C4)4][OH]:: tetrabutylphosphonium hydroxide
[P14666][Tf₂N]:: trihexyl(tetradecyl)phosphonium bis(trifluoromethylsulfonyl) imide
[P5mim][nFAP]:: 1-pentyl-3 methylimidazolium tris(nonafluorobutyl)trifluorophosphate
APILs:: aprotic ionic liquids
CCS:: carbon capture and storage
ILs:: ionic liquids
PILs:: protic ionic liquids
PMG:: pentamethylguanidinium
TGA:: thermo gravimetric analysis
TMG:: tetramethylguanidinium
TSIL:: task specific ionic liquids

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Department of Chemical Engineering, Shiraz University of Technology, Shiraz, Iran
Maryam Raeisi
Department of Chemical Engineering, Shiraz University, Shiraz, Iran
Amineh Keshavarz & Mohammad Reza Rahimpour

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Amineh Keshavarz
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Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia
Inamuddin
Department of Applied Chemistry, Faculty of Engineering and Technology, Aligarh Muslim University, Aligarh, India
Abdullah M. Asiri
Aix-Marseille Université, CNRS, IRD, INRA, Coll France, CEREGE, Aix-en-Provence, France
Eric Lichtfouse

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Raeisi, M., Keshavarz, A., Rahimpour, M.R. (2019). Ionic Liquids for Carbon Dioxide Capture. In: Inamuddin, Asiri, A., Lichtfouse, E. (eds) Sustainable Agriculture Reviews 38. Sustainable Agriculture Reviews, vol 38. Springer, Cham. https://doi.org/10.1007/978-3-030-29337-6_8

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Published: 02 January 2020
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