Selective Hydrogenation of Carbon Dioxide into Methanol

Pham Minh, Doan; Roger, Anne-Cécile; Parkhomenko, Ksenia; L’Hospital, Valentin; Rego de Vasconcelos, Bruna; Ro, Kyoung; Mahajan, Devinder; Chen, Lyufei; Singh, Sharanjit; Vo, Dai-Viet N.

doi:10.1007/978-3-030-28638-5_5

Doan Pham Minh⁷,
Anne-Cécile Roger⁸,
Ksenia Parkhomenko⁸,
Valentin L’Hospital⁸,
Bruna Rego de Vasconcelos⁹,
Kyoung Ro¹⁰,
Devinder Mahajan¹¹,
Lyufei Chen¹²,
Sharanjit Singh¹³ &
…
Dai-Viet N. Vo ORCID: orcid.org/0000-0001-9064-7016^14,15

Part of the book series: Environmental Chemistry for a Sustainable World ((ECSW,volume 41))

1171 Accesses
3 Citations

Abstract

This chapter is dedicated to methanol synthesis from carbon dioxide and hydrogen. Methanol, chemical formula CH₃OH, is an important platform molecule which can be transformed into a large number of other chemicals, i.e., formaldehyde, acetic acid, dimethyl ether, methyl tert-butyl ether, and methyl methacrylate, as well as complex hydrocarbon mixtures, e.g., gasoline and diesel. Up to date, methanol is produced at industrial scale by steam reforming of natural gas, leading to high environmental impacts. The selective hydrogenation of carbon dioxide into methanol can be a good alternative since it is possible to capture carbon dioxide from industrial processes and to produce hydrogen from renewable energies, e.g., solar energy and wind energy.

From a thermodynamic point of view, carbon dioxide hydrogenation is strongly influenced by the total pressure, temperature, and feeding composition. The use of a catalyst is also mandatory to control the kinetic and the selectivity into methanol. Among solid catalysts studied, copper-based catalysts have been found to be the best catalytic systems. Promoters like zinc oxide were usually used. Nickel-, palladium-, and silver-based catalysts also showed good catalytic performance compared to copper-based catalysts. Soluble catalysts have been intensively studied for this hydrogenation. Ru complexes appeared as the best homogeneous catalyst. Other metal-free homogeneous catalysts, e.g., N-heterocyclic carbenes, have been found to be active and selective in this reaction. Efforts have been made on the mechanistic study of the reaction in both the gas and liquid phases. Large industrial production has started in several countries showing the interest and the feasibility of the process.

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Abbreviations

Me:: methyl group or CH₃−
MEFCO2:: methanol fuel from CO₂
mV:: millivolts
phen:: phenanthroline
PNN ligands:: phosphorus–nitrogen–nitrogen pincer ligands
ptpbα:: pyrido[2,3:5,6]pyrazino[2,3-f][1,10]phenanthroline
ptpbβ:: pyrido[3,4,5,6]pyrazino[2,3-f][1,10]phenanthroline
Ru(acac)₃:: ruthenium(III) acetylacetonate
SPIRE:: Sustainable Process Industry through Resource and Energy Efficiency
TMM:: trimethylenemethane
Triphos:: 1,1,1-tris(diphenylphosphinomethyl)ethane
μM:: micromole per litre or 10⁻⁶ mole per litre

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Université de Toulouse, IMT Mines Albi, UMR CNRS 5302, Centre RAPSODEE, Albi cedex 09, France
Doan Pham Minh
Université de Strasbourg, ICPEES groupe Energie et Carburants pour un Environnement Durable, UMR 7515, Strasbourg Cedex 2, France
Anne-Cécile Roger, Ksenia Parkhomenko & Valentin L’Hospital
Biomass Technology Laboratory, Department of Chemical Engineering, Université de Sherbrooke, Sherbrooke, QC, Canada
Bruna Rego de Vasconcelos
USDA-ARS, Coastal Plains Soil, Water & Plant Research Center, Florence, SC, USA
Kyoung Ro
Institute of Gas Innovation and Technology, Advanced Energy Research and Technology and Materials Science and Chemical Engineering Department, Stony Brook University, Stony Brook, NY, USA
Devinder Mahajan
Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY, USA
Lyufei Chen
Faculty of Chemical and Natural Resources Engineering, Universiti Malaysia Pahang, Gambang, Kuantan, Pahang, Malaysia
Sharanjit Singh
Center of Excellence for Green Energy and Environmental Nanomaterials (CE@GrEEN), Nguyen Tat Thanh University, Ho Chi Minh City, Vietnam
Dai-Viet N. Vo
Faculty of Chemical and Natural Resources Engineering, Universiti Malaysia Pahang, Gambang, Kuantan, Pahang, Malaysia
Dai-Viet N. Vo

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Inamuddin
Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia
Abdullah M. Asiri
Lab. Multiphase Flow in Pow. Eng., Xi’an Jiaotong University, Xi’an, China
Eric Lichtfouse

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Pham Minh, D. et al. (2020). Selective Hydrogenation of Carbon Dioxide into Methanol. In: Inamuddin, Asiri, A., Lichtfouse, E. (eds) Conversion of Carbon Dioxide into Hydrocarbons Vol. 2 Technology. Environmental Chemistry for a Sustainable World, vol 41. Springer, Cham. https://doi.org/10.1007/978-3-030-28638-5_5

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