Skip to main content

Some Simple Systems

  • Chapter
  • First Online:
  • 2635 Accesses

Part of the book series: Undergraduate Texts in Physics ((UNTEPH))

Abstract

The time-independent Schroedinger equation is solved for a number of simple one-dimensional systems. In particular, the Infinite Square Well, the Potential Step, the Square Barrier (tunneling phenomena), the Square Well (bound states) and the Delta Function potential.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   54.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   69.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Notes

  1. 1.

    Continuity of any measurable physical quantity—e.g., the probability density—is always a requirement. Therefore, the wave function must always be continuous. The same is true for the first spatial derivative of the wave function provided the potential is non-singular. For the above case, at the points where the potential is infinite, it is obvious that the second spatial derivative of the wave function does not exist and, therefore, its first derivative is neither differentiable nor continuous. Thus, here there is no continuity condition for the first derivative.

  2. 2.

    Note that \(e^{\pm 2ik_nL}\,=\,e^{\pm in\pi }\,=\,(-1)^n\).

  3. 3.

    For an analysis of the general properties of the solutions of the one-dimensional Schroedinger equation see [1].

  4. 4.

    Mathematically, the general solution could also be written in terms of \(\sin (kx)\) and \(\cos (kx)\). Nevertheless, in situations with propagating particles it is always preferable to use plane wave exponentials, since they are associated with a sense of direction. In bound state problems however, in cases where the potential has definite parity, it will be more profitable to write the solution in terms of cosines and sines which are even and odd.

  5. 5.

    For an analysis of the issue of bound states in general one-dimensional potentials see [2].

  6. 6.

    See the section on Generalized Functions in the Mathematical Appendix.

  7. 7.

    Such a situation can occur if a particle occupies the ground state of an infinite square well of width \([-L,L]\) and suddenly (in a time interval \(\tau \) much smaller than the characteristic time of the system, i.e., \(\tau<<8mL^2/\hbar \pi ^2\)) the walls of the well move so that the width gets doubled.

  8. 8.

    You may assume the regularization \(\lim _{x\rightarrow \infty }e^{i\,k\,x }\,=\,\lim _{\epsilon \rightarrow 0}\lim _{x\rightarrow \infty }e^{i(x+i\epsilon )k}\,=\,0\).

References

  1. A. Messiah, Quantum Mechanics (Dover publications, Mineola, 1958). Single-volume reprint of the John Wiley & Sons, New York, two-volume 1958 edition

    Google Scholar 

  2. F. Levin, An Introduction to Quantum Theory (Cambridge University Press, Cambridge, 2002)

    MATH  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Kyriakos Tamvakis .

Problems and Exercises

Problems and Exercises

3.1

Particles of mass m and energy E are incident from the left on the potential step \(V(x)=-\Theta (x)V_0\) with \(V_0>0\). Calculate the reflection coefficient.

3.2

Consider a particle of mass m and energy \(E>V_0>0\) incident on the potential step \(V(x)=\Theta (x)V_0\). Calculate the reflection coefficient for incidence from the right and for incidence from the left and compare the results.

3.3

Consider the asymmetric square well

$$V(x)=\left\{ \begin{array}{cc} V_1\,&{}\,(x<0)\\ \,&{}\,\\ -V_0\,&{}\,(0<x<L)\\ \,&{}\,\\ 0\,&{}\,(x>L) \end{array}\right. $$

with \(V_1\) and \(V_0\) positive. Investigate the existence of bound states.

3.4

A particle trapped in an infinite square well of width \([-2L,\,2L]\) has initially (\(t=0\)) a wave functionFootnote 7

$$\psi (x,0)\,=\,\left\{ \begin{array}{cc} \frac{1}{\sqrt{L}}\cos (\pi x/2L)\,&{}\,(|x|\le L)\\ \,&{}\,\\ 0\,&{}\,(L\le |x|\le 2L). \end{array}\right. $$

Calculate the probability to find the system in its ground state.

3.5

Verify explicitly the orthogonality of the energy eigenfunctionsFootnote 8 of the potential step \(V(x)=\Theta (x)V_0\)

$$\int _{-\infty }^{+\infty }dx\,\psi _E^*(x)\psi _{E'}(x)\,=\,0\,\,\,\,\,\,\,\,\,\,\,\,(E\ne E')\,.$$

3.6

A particle of mass m is trapped in an infinite square well of width \([-L,\,L]\). The particle is initially (\(t=0\)) in a state with wave function

$$\psi (x,0)\,=\,\frac{1}{\sqrt{2}}\left( \,\psi _N(x)\,+\,i\,\psi _{N+1}(x)\,\right) \,,$$

where \(\psi _n(x)\) is the energy eigenfunction corresponding to energy \(E_n\). Find the wave function of the particle at times \(t>0\). Calculate the probability to find the particle in the initial state at time \(t>0\). What is the minimum time that this probability becomes one? Calculate the probability to find the particle at time \(t>0\) in the orthogonal state

$$\psi ^{(\bot )}(x)\,=\,\frac{1}{\sqrt{2}}\left( \,\psi _N(x)\,-i\psi _{N+1}(x)\,\right) \,.$$

3.7

A particle of mass m and energy \(E>0\) is incident from the right on a potential step \(V(x)=-V_0\Theta (-x)\) with \(V_0>0\). What is the value of the ratio \(E/V_0\) if the reflection coefficient is 1 / 4?

3.8

A particle of mass m is bound in a potential

$$V(x)\,=\,\left\{ \begin{array}{cc} +\infty \,&{}\,(x\le 0)\\ \,&{}\,\\ -\frac{\hbar ^2g^2}{2m}\delta (x-a)\,&{}\,(x>0). \end{array}\right. $$

Calculate the probability to find the particle in the region \(a\le x<\infty \).

3.9

A particle moves in the potential \(V(x)=g^2\,|x|\). If the particle is in a state with wave function

$$\psi (x)\,=\,N\,x\,e^{-\alpha \,x^2}\,,$$

where \(N,\,\alpha >0\) are known parameters, calculate the probability to find the particle in the ground state \(\psi _0(x)\) of the energy. The exact form of \(\psi _0(x)\) is not necessary.

3.10

Consider a particle moving in the potential of two attractive delta functions

$$V(x)\,=\,-\frac{\hbar ^2 g^2}{2m}\left( \,\delta (x+a)\,+\,\delta (x-a)\,\right) \,.$$

Investigate the existence of bound states (\(E<0\)).

Rights and permissions

Reprints and permissions

Copyright information

© 2019 Springer Nature Switzerland AG

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Tamvakis, K. (2019). Some Simple Systems. In: Basic Quantum Mechanics. Undergraduate Texts in Physics. Springer, Cham. https://doi.org/10.1007/978-3-030-22777-7_3

Download citation

Publish with us

Policies and ethics