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International Conference Physics of Liquid Matter: Modern Problems

PLMMP 2018: Modern Problems of the Physics of Liquid Systems pp 137–164Cite as

Organization of Nano-disks of Laponite® in Soft Colloidal Systems

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Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 223))

Abstract

The structure and properties of soft colloidal systems filled by nano-disks of Laponite® (Lap) are critically reviewed. The known Lap grades, chemical structure and physical properties are described. Various phases formed by exfoliated surface-charged Lap discs in aqueous media are analyzed, accounting for the kinetics of phase transformations and aging processes. The emerging interfacial structures are considered, as well as interactions of Lap discs with surfactants. Special attention is paid to formation of organically modified Lap (LapO). The latter can form homogeneous dispersions in non-aqueous media (organic solvents, soft non-ionic polymers, nematic and liquid crystals (LC)). LapO platelets exhibit various behavior patterns in ordered LC media, with specific effects emerging from interactions of disc-like LapO and rod-like LC molecules and carbon nanotubes. Promising practical applications of Lap based suspensions and nanomaterials based thereon are also outlined.

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Abbreviations

BET:

Brunauer–Emmett–Teller adsorption theory

CEC:

cation exchange capacity

CNTs:

carbon nanotubes

DLS:

dynamic light scattering

DSC:

differential scanning calorimetry

Lap:

Laponite®

LapO:

organo-modified Lap

LC:

liquid crystal

LLC:

lyotropic liquid crystal

NMR:

nuclear magnetic resonance

SANS:

small-angle neutron scattering

SAXS:

small-angle X-ray scattering

SEM:

scanning electron microscopy

TEB:

transient electrically-induced birefringence

TEM:

transmission electron microscopy

XRD:

X-ray diffraction

5CB:

4-pentyl-4′-cyanobiphenyl, CH3(CH2)4C6H4C6H4CN

M5:

A mixture of cholesterol esters consisting of 30% cholesteryl formate (C28H46O2), 5% cholesteryl butyrate (C31H52O2) and 65% cholesteryl nonanoate C36H62O2

SDS:

sodium dodecyl sulfate, NaC12H25SO4

PSS-Na:

sodium polystyrene sulfonate, (CH2CHC6H4SO3Na)n

CTAB:

hexadecyltrimethylammonium bromide, C19H42N+Br−

CTAC:

hexadecyltrimethylammonium chloride, C19H42N+Cl−

DODAB:

dimethydioctodecylammonium bromide, C38H80N+Br−

DODAC:

dimethydioctodecylammonium chloride, C38H80N+Cl−

Brij 30:

polyoxyethylene(4)lauryl ether, C12H25(OCH2CH2)4OH

Brij 35:

polyethylene glycol dodecyl ether, C12H25(OCH2CH2)nOH, n ~ 23

PEG/PEO:

polyethylene glycol/oxide, H(OCH2CH2)nOH, PEG: Mw < 20 × 103 g/mol, PEO: Mw >  20 × 103 g/mol

SAP:

oly(isobutylene) based stabilizer SAP 230TP (Infineum, UK)

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Acknowledgements

This work was partially supported by the funding from the National Academy of Sciences of Ukraine, Projects No. 0117U004046 and 43/19-H (NIL).

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Authors and Affiliations

  1. Department of Physical Chemistry of Disperse Minerals, Biocolloidal Chemistry Institute, 42, Vernadsky av, Kyiv, 03142, Ukraine

    Nikolai Lebovka

  2. Institute for Scintillation Materials of STC “Institute for Single Crystals”, NAS of Ukraine, 60, Nauky Ave, Kharkiv, 61001, Ukraine

    Longin Lisetski

  3. Department of Molecular Physics, Taras Shevchenko National University of Kyiv, 2, Prosp. Academician Glushkov, Kyiv, 03022, Ukraine

    Leonid A. Bulavin

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  1. Nikolai Lebovka
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Correspondence to Nikolai Lebovka .

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  1. National Academy of Sciences of Ukraine, Kyiv, Ukraine

    Leonid A. Bulavin

  2. International Center for Quantum Materials and School of Physics, Peking University, Beijing, China

    Limei Xu

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Lebovka, N., Lisetski, L., Bulavin, L.A. (2019). Organization of Nano-disks of Laponite® in Soft Colloidal Systems. In: Bulavin, L., Xu, L. (eds) Modern Problems of the Physics of Liquid Systems. PLMMP 2018. Springer Proceedings in Physics, vol 223. Springer, Cham. https://doi.org/10.1007/978-3-030-21755-6_6

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