Abstract
This work demonstrates that nonmetal boron is absent in the crystal structure thus it structures the melt and has a significant influence on the structure and physical characteristics of lithium niobate crystals . At this LiNbO3:B crystals possess a structure uniformity (and it is higher than that of a congruent crystals) , their NbLi defects amount is close to the amount in stoichiometric crystals though a photorefractive effect of LiNbO3:B crystals is much lower than in stoichiometric crystals and the structure and an optical uniformity is higher in LiNbO3:B crystals .
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Notes
- 1.
Non-photorefractive cations do not change the charge in the crystals under an optical radiation (they do not provide extra electrons to the system) despite the photorefractive cations.
- 2.
A band with frequency 630 cm−1 (А1(ТО)) is forbidden by the selection rules in the scattering geometry Y(ZX)Ȳ, it manifests in this geometry due to the photorefractive effect.
- 3.
For [27], a low-intensity band with frequency 120 cm−1 may also correspond to a mode of a pseudoscalar type А2, forbidden by the selection rules for a point group С3v. This vibration may appear in a Raman spectrum due to a lowering in a local point symmetry of lithium niobate crystals from С3v to С3 due to О3 triangles turning because of impurities in real crystals [27].
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Sidorov, N.V., Teplyakova, N.A., Titov, R.A., Palatnikov, M.N., Syuy, A.V., Prokopiv, N.N. (2019). Fine Particularities of Structure and Optical Properties of Lithium Niobate Crystals Grown from Boron Doped Charge with Different Genesis. In: Parinov, I., Chang, SH., Kim, YH. (eds) Advanced Materials. Springer Proceedings in Physics, vol 224. Springer, Cham. https://doi.org/10.1007/978-3-030-19894-7_21
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