Abstract
Ferroelectric ceramics of the (1 − x)PbZrO3–xPbTiO3 (PZT) system solid solutions (SSs) were obtained and comprehensively investigated in the full range of components’ solubility. The processes occurring in the nano-, meso-, and microstructure of ceramics with changes in the ratio of the components were considered in detail. It is shown that the appearance of clusters of a new phase and their evolution when solid solutions approach the morphotropic regions of the system cause consistent changes in the structural ordering in the entire range of scales studied. X-ray studies of the crystal structure and multifractal parametrization of the grain landscape were carried out. Comprehensive studies have shown that changes in the crystal structure begin already far from morphotropic phase transitions areas. The role of crystallographic shear planes as a concentrator of mechanical stresses in the system was revealed. In a number of compositions, the appearance of phases with symmetry of the matrix and close but different cell parameters and the rate of their change is established. They were called phase states. It was shown that the multifractal parameters of a microstructure are a sensitive indicator of all mesostructural changes occurring in a ceramic object. The possibilities of the influence of the state of different structural levels on the formation of piezoelectric properties of the material are considered.
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Acknowledgements
The work was supported by the Ministry of Education and Science of the Russian Federation: projects Nos. 3.6371.2017/8.9 (the basic part of the state task), Grant of Russian Foundation for Basic Research No. 18-32-00552. The equipment of the Center of Research Institute of Physics SFedU was used.
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Titov, S., Andryushina, I., Shilkina, L., Titov, V., Andryushin, K., Reznichenko, L. (2019). The Changes in the Structure of PZT-Ceramics at Nano-, Mezo- and Microscopic Levels Under Morphotropic Phase Transitions. In: Parinov, I., Chang, SH., Kim, YH. (eds) Advanced Materials. Springer Proceedings in Physics, vol 224. Springer, Cham. https://doi.org/10.1007/978-3-030-19894-7_19
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