Abstract
The hydroxyaurones were synthesized by condensation of benzofuran-3-one with hydroxybenzaldehydes, and then new methacrylic monomers were obtained. The kinetics of radical thermo-initiated homopolymerization of new monomers by dilatometric method in 10% solutions of DMF was investigated. The intra-chain stabilizing effect of aurone derivatives, on the destruction of polystyrene, has been investigated. It has been established that the applications of the studied additives with covalent introduction significantly inhibit the process of its degradation in comparison with industrial polystyrene produced by Styron (Switzerland).
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Nestorak I et al (2011) Investigation of inhibiting action mechanism of succinimidophenylmethacrylate derivatives prepared by the Diels-Alder reaction on polystyrene decomposition. Mol Cryst Liq Cryst 536:208–214. https://doi.org/10.1080/15421406.2011.538609
Schwetlick K et al (2002) Antioxidant action mechanisms of hindered amine stabilizers. Polym Degrad Stab 78(1):35–40
Smoliak LY et al (2003) Estimation of parameters that correlate molecular structure of hindered amines with their stabilizing efficiency. Polym Degrad Stab 82(2):169–172
Boersma A (2006) Predicting the efficiency of antioxidants in polymers. Polym Degrad Stab 91(3):472–478
Ebdon JR et al (2000) Thermal degradation and flame retardance in copolymers of methyl methacrylate with diethyl(methacryloyloxymethyl)phosphonate. Polym Degrad Stab 70(3):425–436
Kolendo AYu et al (2009) Ukr. P. 41029. Promyslova Vlastnist’, 8. (in Ukrainian)
Karabets Y et al (2014) Brominating of oxyphenylimides for enhancement of stabilizing processes Mol. Cryst Liq Cryst 590:90–96. https://doi.org/10.1080/15421406.2013.873852
Karabets Y et al (2017) Synthesis and investigation of bromine containing oxy- and Propionoxyphenylimides for polymers thermostabilization Mol. Cryst Liq Cryst 640:54–57. https://doi.org/10.1080/15421406.2016.1255512
Nestorak I et al (2008) Thermal stabilizing properties of maleimidophenylmethacrylates derivatives with substitutes of various molecular arhitectures in imide cycle. Mol Cryst Liq Cryst 497:299–306. https://doi.org/10.1080/15421400801921991
Kharchenko O et al (2016) Design, synthesis, and photochemistry of styrylquinoline-containing polymers. Mol Cryst Liq Cryst 640:71–77. https://doi.org/10.1080/15421406.2016.1255516
Smokal V et al (2018) Synthesis and photophysical properties of new styrylquinoline-containing polymers. Mol Cryst Liq Cryst 661(1):38–44. https://doi.org/10.1080/15421406.2018.1460236
Kharchenko O et al (2018) Reactivity and polymerisation ability of styrilquinaline containing metacrylic monomers. Chem Chem Technol 12(1):47–52. https://doi.org/10.23939/chcht12.01.047
Derkowska-Zielinska B et al (2018) Functionalized polymers with strong push-pull azo chromophores in side chain for optical application. Opt Mater 85:391–398. https://doi.org/10.1016/j.optmat.2018.09.008
Guichaoua D et al (2018) Functionalized methacrylic thiazolidinone polymer for optical applications. ICTON 8473860. https://doi.org/10.1109/ICTON.2018.8473860
Bourbigot S et al (2004) Kinetic analysis of the thermal degradation of polystyrene–montmorillonite nanocomposite. Polym Degrad Stab 84(3):483–492
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2019 Springer Nature Switzerland AG
About this paper
Cite this paper
Iukhymenko, N., Martynes-Harsiia, A., Kharchenko, O., Smokal, V., Krupka, O., Kolendo, A. (2019). Synthesis and Study of Methacrylic Monomers and Polymers on the Basis of Aurones. In: Fesenko, O., Yatsenko, L. (eds) Nanophotonics, Nanooptics, Nanobiotechnology, and Their Applications. NANO 2018. Springer Proceedings in Physics, vol 222. Springer, Cham. https://doi.org/10.1007/978-3-030-17755-3_31
Download citation
DOI: https://doi.org/10.1007/978-3-030-17755-3_31
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-17754-6
Online ISBN: 978-3-030-17755-3
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)