Abstract
The anchoring effect of the mesogens on different substrates is particularly interesting because of fundamental reasons as well as because of wide practical applications. In this work, we use molecular dynamics computer simulations to study the effect of embedding n-cyanobiphenyl molecules between two arrays of carbon nanotubes. We examine the effect of distance between the nanotube planes on the ordering and mobility of the mesogenic phase formed in such confinement. We assess the temperature stability and uniaxial ordering imposed by the nanotube array.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Roscioni OM, Muccioli L, Zannoni C (2017) Predicting the conditions for homeotropic anchoring of liquid crystals at a soft surface. 4-n-Pentyl-4′-cyanobiphenyl on alkylsilane self-assembled monolayers. ACS Appl Mater Interfaces 9:11993–12002. https://doi.org/10.1021/acsami.6b16438
Raczyńska V, Górny K, Raczyński P, Dendzik Z (2018) Percolation threshold of 5-Cyanobiphenyl mesogene phases between graphene planes: computer simulation study. In: Fesenko O, Yatsenko L (eds) Nanochemistry, biotechnology, nanomaterials, and their applications. NANO 2017. Springer proceedings in physics, vol 214. Springer. https://doi.org/10.1007/978-3-319-92567-7_17
Skrzypek M, Dendzik Z, Brol P, Gburski Z (2004) Cluster and layers of fullerene molecules between graphite planes. J Mol Struct 704:287–290. https://doi.org/10.1016/j.molstruc.2004.02.045
Rahman M, Lee W (2009) J Phys D Appl Phys 42:063001–063013. https://doi.org/10.1088/0022-3727/42/6/0630013
Górny K, Raczyński P, Dendzik Z, Gburski Z (2015) Odd−even effects in the dynamics of liquid crystalline thin films on the surface of single walled carbon and silicon carbide nanotubes: computer simulation study. J Phys Chem C 119:19266–19271. https://doi.org/10.1021/acs.jpcc.5b05961
Phillips JC, Braun R, Wang W, Gumbart J, Tajkhorshid E, Villa E, Chipot C, Skeel RD, Kalé L, Schulten K (2005) Scalable molecular dynamics with NAMD. J Comput Chem 26:1781–1802. https://doi.org/10.1002/jcc.20289
Humphrey W, Dalke A, Schulten K (1996) VMD - visual molecular dynamics. J Mol Graph 14:33–38. https://doi.org/10.1016/0263-7855(96)00018-5
Tiberio G, Muccioli L, Berardi R, Zannoni C (2009) Towards in silico liquid crystals. Realistic transition temperatures and physical properties for n-Cyanobiphenyls via molecular dynamics simulations. Chemphyschem 10:125–136. https://doi.org/10.1002/cphc.200800231
Giorgino T (2014) Computing 1-D atomic densities in macromolecular simulations: the density profile tool for VMD. Comput Phys Commun 185:317–322. https://doi.org/10.1016/j.cpc.2013.08.022
Allen MP, Tildesley DJ (1989) Computer simulation of liquids. Clarendon Press/Oxford University Press, Oxford, UK/New York
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2019 Springer Nature Switzerland AG
About this paper
Cite this paper
Raczyńska, V., Górny, K., Raczynski, P., Dendzik, Z. (2019). Properties of n-Cyanobiphenyl Nematogene Phases Formed Between Carbon Nanotube Arrays: Computer Simulation Study. In: Fesenko, O., Yatsenko, L. (eds) Nanophotonics, Nanooptics, Nanobiotechnology, and Their Applications. NANO 2018. Springer Proceedings in Physics, vol 222. Springer, Cham. https://doi.org/10.1007/978-3-030-17755-3_27
Download citation
DOI: https://doi.org/10.1007/978-3-030-17755-3_27
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-17754-6
Online ISBN: 978-3-030-17755-3
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)