Abstract
The spatial arrangement of designed reaction centers with engineered porosity withdraws a special attention in exploring metal-organic frameworks (MOFs) for developing a wide range of photocatalyst in the last decade. This chapter targets to recapitulate the recent advancement of MOF-derived photocatalyst with their mechanism, types, structural engineering, and various practical uses.
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References
Abrahams BF, Hudson TA, McCormick LJ, Robson R (2011) Coordination polymers of 2,5-dihydroxybenzoquinone and chloranilic acid with the (10,3)-a topology. Cryst Growth Des 11:2717–2720. https://doi.org/10.1021/cg2005908@proofing
Abrahamsson M, Johansson PG, Ardo S, Kopecky A, Galoppini E, Meyer GJ (2010) Decreased interfacial charge recombination rate constants with N3-type sensitizers. J Phys Chem Lett 1:1725–1728. https://doi.org/10.1021/jz100546y
Adarsh NN, Dastidar P (2012) Coordination polymers: what has been achieved in going from innocent 4,4′-bipyridine to bis-pyridyl ligands having a non-innocent backbone? Chem Soc Rev 41:3039–3060. https://doi.org/10.1039/C2CS15251G
Adarsh NN, Sahoo P, Dastidar P (2010) Is a crystal engineering approach useful in designing metallogels? A case study. Cryst Growth Des 10:4976–4986. https://doi.org/10.1021/cg101078f
Akimov AV, Asahi R, Jinnouchi R, Prezhdo OV (2015) What makes the photocatalytic CO2 reduction on N-doped Ta2O5 efficient: insights from nonadiabatic molecular dynamics. J Am Chem Soc 137:11517–11525. https://doi.org/10.1021/jacs.5b07454
Allendorf MD, Stavila V (2015) Crystal engineering, structure–function relationships, and the future of metal–organic frameworks. CrystEngComm 17:229–246. https://doi.org/10.1039/C4CE01693A
Allendorf MD, Schwartzberg A, Stavila V, Talin AA (2011) A roadmap to implementing metal-organic frameworks in electronic devices: challenges and critical directions. Chem Eur J 17:11372–11388. https://doi.org/10.1002/chem.201101595
Alqadami AA, Naushad M, Alothman ZA, Ahamad T (2018) Adsorptive performance of MOF nanocomposite for methylene blue and malachite green dyes: kinetics, isotherm and mechanism. J Environ Manag 223:29–36. https://doi.org/10.1016/j.jenvman.2018.05.090
Alvaro M, Carbonell E, Ferrer B, Llabrés i Xamena FX, Garcia H (2007) Semiconductor behavior of a Metal-Organic Framework (MOF). Chem Eur J 13:5106–5112. https://doi.org/10.1002/chem.200601003
Ameloot R, Roeffaers MBJ, De Cremer G, Vermoortele F, Hofkens J, Sels BF, De Vos DE (2011) Metal–organic framework single crystals as photoactive matrices for the generation of metallic microstructures. Adv Mater 23:1788–1791. https://doi.org/10.1002/adma.201100063
Andrew Lin K-Y, Chang H-A, Hsu C-J (2015) Iron-based metal organic framework, MIL-88A, as a heterogeneous persulfate catalyst for decolorization of Rhodamine B in water. RSC Adv 5:32520–32530. https://doi.org/10.1039/C5RA01447F
Araya T, Jia MK, Yang J, Zhao P, Cai K, Ma WH, Huang YP (2017) Resin modified MIL-53 (Fe) MOF for improvement of photocatalytic performance. Appl Catal B Environ 203:768–777. https://doi.org/10.1016/j.apcatb.2016.10.072
Bag PP, Wang X-S, Cao R (2015) Microwave-assisted large scale synthesis of lanthanide metal–organic frameworks (Ln-MOFs), having a preferred conformation and photoluminescence properties. Dalton Trans 44:11954–11962. https://doi.org/10.1039/C5DT01598G
Bag PP, Wang D, Chen Z, Cao R (2016) Outstanding drug loading capacity by water stable microporous MOF: a potential drug carrier. Chem Commun 52:3669–3672. https://doi.org/10.1039/C5CC09925K
Bag PP, Wang X-S, Sahoo P, Xiong J, Cao R (2017) Efficient photocatalytic hydrogen evolution under visible light by ternary composite CdS@NU-1000/RGO. Catal Sci Technol 7:5113–5119. https://doi.org/10.1039/C7CY01254C
Bagheri M, Masoomi MY, Morsali A (2017) A MoO3–metal–organic framework composite as a simultaneous photocatalyst and catalyst in the PODS process of light oil. ACS Catal 7:6949–6956. https://doi.org/10.1021/acscatal.7b02581
Bai S, Jiang J, Zhang Q, Xiong Y (2015) Steering charge kinetics in photocatalysis: intersection of materials syntheses, characterization techniques and theoretical simulations. Chem Soc Rev 44:2893–2939. https://doi.org/10.1039/C5CS00064E
Bak T, Nowotny J, Rekas M, Sorrell CC (2002) Photo-electrochemical hydrogen generation from water using solar energy. Materials-related aspects. Int J Hydrog Energy 27:991–1022. https://doi.org/10.1016/S0360-3199(02)00022-8
Banerjee R, Sahoo SC, Kundu T (2016) Water soluble Metal-Organic Frameworks (MOFs). U.S. Patent US 9290518 B2, filed October 3, 2012, and issued March 22, 2016
Bellitto C, Dessy G, Fares V (1985) Synthesis, x-ray crystal structure, and chemical and physical properties of the new linear-chain mixed-valence complex (.mu.- iodo)tetrakis(dithioacetato)dinickel, Ni2(CH3CS2)4I, and x-ray crystal structure of the precursor tetrakis(dithioacetato)dinickel(II), Ni2(CH3CS2)4. Inorg Chem 24:2815–2820. https://doi.org/10.1021/ic00212a023
Bhattacharjee S, Khan MI, Li X, Zhu Q-L, Wu X-T (2018) Recent progress in asymmetric catalysis and chromatographic separation by chiral metal–organic frameworks. Catalysts 8:120. https://doi.org/10.3390/catal8030120
Biradha K, Ramanan A, Vittal JJ (2009) Coordination polymers versus metal−organic frameworks. Cryst Growth Des 9:2969–2970. https://doi.org/10.1021/cg801381p
Biswal BP, Shinde DB, Pillai VK, Banerjee R (2013) Stabilization of graphene quantum dots (GQDs) by encapsulation inside zeolitic imidazolate framework nanocrystals for photoluminescence tuning. Nanoscale 5:10556–10561. https://doi.org/10.1039/C3NR03511E
Bolton JR, Mataga N, McLendon G (eds) (1991) Electron transfer in inorganic, organic and biological systems, Advances in chemistry series. American Chemical Society, Washington, DC
Butler KT, Hendon CH, Walsh A (2014a) Electronic structure modulation of metal–organic frameworks for hybrid devices. ACS Appl Mater Interfaces 6:22044–22050. https://doi.org/10.1021/am507016r
Butler KT, Hendon CH, Walsh A (2014b) Electronic chemical potentials of porous metal–organic frameworks. J Am Chem Soc 136:2703–2706. https://doi.org/10.1021/ja4110073
Cavka JH, Jakobsen S, Olsbye U, Guillou N, Lamberti C, Bordiga S, Lillerud KP (2008) A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability. J Am Chem Soc 130:13850–13851. https://doi.org/10.1021/ja8057953
Chambers MB, Wang X, Elgrishi N, Hendon CH, Walsh A, Bonnefoy J, Canivet J, Quadrelli EA, Farrusseng D, Mellot-Draznieks C, Fontecave M (2015) Photocatalytic carbon dioxide reduction with rhodium-based catalysts in solution and heterogenized within metal–organic frameworks. ChemSusChem 8:603–608. https://doi.org/10.1002/cssc.201403345
Chambers MB, Wang X, Ellezam L, Ersen O, Fontecave M, Sanchez C, Rozes L, Mellot-Draznieks C (2017) Maximizing the photocatalytic activity of metal–organic frameworks with aminated-functionalized linkers: substoichiometric effects in MIL-125-NH2. J Am Chem Soc 139: 8222–8228 and the reference there in. https://doi.org/10.1021/jacs.7b02186
Chen X, Burda C (2008) The electronic origin of the visible-light absorption properties of C-, N- and S-doped TiO2 nanomaterials. J Am Chem Soc 130:5018–5019. https://doi.org/10.1021/ja711023z
Chen X, Shen S, Guo L, Mao SS (2010) Semiconductor-based photocatalytic hydrogen generation. Chem Rev 110:6503–6570. https://doi.org/10.1021/cr1001645
Chen Y, Wang D, Deng X, Li Z (2017a) Metal–organic frameworks (MOFs) for photocatalytic CO2 reduction. Cat Sci Technol 7:4893–4490. https://doi.org/10.1039/C7CY01653K
Chen Y-F, Tan L-L, Liu J-M, Qin S, Xie Z-Q, Huang J-F, Xu Y-W, Xiao L-M, Su C-Y (2017b) Calix[4]arene based dye-sensitized Pt@UiO-66-NH2 metal-organic framework for efficient visible-light photocatalytic hydrogen production. Appl Catal B 206:426–433. https://doi.org/10.1016/j.apcatb.2017.01.040
Chi L, Xu Q, Liang XY, Wang JD, Su XT (2016) Iron-based metal–organic frameworks as catalysts for visible light-driven water oxidation. Small 12:1351–1135. https://doi.org/10.1002/smll.201503526
Choi KM, Kim D, Rungtaweevoranit B, Trickett CA, Barmanbek JTD, Alshammari AS, Yang P, Yaghi OM (2017) Plasmon-enhanced photocatalytic CO2 conversion within metal–organic frameworks under visible light. J Am Chem Soc 139:356–362. https://doi.org/10.1021/jacs.6b11027
Corey EJ (1967) General methods for the construction of complex molecules. Pure Appl Chem 14:19–38. https://doi.org/10.1351/pac196714010019
Coropceanu V, Cornil J, da Silva FDA, Olivier Y, Silbey R, Brédas J-L (2007) Charge transport in organic semiconductors. Chem Rev 107:926–952. https://doi.org/10.1021/cr050140x
Dan-Hardi M, Serre C, Frot T, Rozes L, Maurin G, Sanchez C, Férey G (2009) A new photoactive crystalline highly porous titanium (IV) dicarboxylate. J Am Chem Soc 131:10857–10859. https://doi.org/10.1021/ja903726m
Darago LE, Aubrey ML, Yu CJ, Gonzalez MI, Long JR (2015) Electronic conductivity, ferrimagnetic ordering, and reductive insertion mediated by organic mixed-valence in a ferric semiquinoid metal–organic framework. J Am Chem Soc 137:15703–15711. https://doi.org/10.1021/jacs.5b10385
de Koning MC, van Grol M, Breijaert T (2017) Degradation of paraoxon and the chemical warfare agents VX, tabun, and soman by the metal–organic frameworks UiO-66-NH2, MOF-808, NU-1000, and PCN-777. Inorg Chem 56:11804–11809. https://doi.org/10.1021/acs.inorgchem.7b01809
deKrafft KE, Wang C, Lin W (2012) Metal-organic framework templated synthesis of Fe2O3/TiO2 nanocomposite for hydrogen production. Adv Mater 24:2014–2018. https://doi.org/10.1002/adma.201200330
Desiraju GR (ed) (1989) Crystal engineering: the design of organic solids. Elsevier Scientific Publishers, Amsterdam/New York
Desiraju GR (1995) Supramolecular synthons in crystal engineering—a new organic synthesis. Angew Chem Int Ed 34:2311–2327. https://doi.org/10.1002/anie.199523111
Desiraju GR (2007) Crystal engineering: a holistic view. Angew Chem Int Ed 46:8342–8356. https://doi.org/10.1002/anie.200700534
Diercks CS, Liu Y, Cordova KE, Yaghi OM (2018) The role of reticular chemistry in the design of CO2 reduction catalysts. Nat Mater 17:301–307. https://doi.org/10.1038/s41563-018-0033-5
Ding W, Negre CFA, Palma JL, Durrell AC, Allen LJ, Young KJ, Milot RL, Schmuttenmaer CA, Brudvig GW, Crabtree RH, Batista VS (2014) Linker rectifiers for covalent attachment of transition-metal catalysts to metal-oxide surfaces. ChemPhysChem 15:1138–1147. https://doi.org/10.1002/cphc.201400063
Esken D, Turner S, Wiktor C, Kalidindi SB, Van Tendeloo G, Fischer RA (2011) GaN@ZIF-8: selective formation of gallium nitride quantum dots inside a zinc methylimidazolate framework. J Am Chem Soc 133:16370–16373. https://doi.org/10.1021/ja207077u
Evans A, Luebke R, Petit C (2018) The use of metal–organic frameworks for CO purification. J Mater Chem A 6:10570–10594. https://doi.org/10.1039/C8TA02059K
Fang Y, Ma Y, Zheng M, Yang P, Asiri AM, Wang X (2017) Metal–organic frameworks for solar energy conversion by photoredox catalysis. Coord Chem Rev 373:83–115. https://doi.org/10.1016/j.ccr.2017.09.013
Fei H, Sampson MD, Lee Y, Kubiak CP, Cohen SM (2015) Photocatalytic CO2 reduction to formate using a Mn(I) molecular catalyst in a robust metal–organic framework. Inorg Chem 54:6821–6828. https://doi.org/10.1021/acs.inorgchem.5b00752
Feng PL, Perry JJ IV, Nikodemski S, Jacobs BW, Meek ST, Allendorf MD (2010) Assessing the purity of metal−organic frameworks using photoluminescence: MOF-5, ZnO quantum dots, and framework decomposition. J Am Chem Soc 132:15487–15489. https://doi.org/10.1021/ja1065625
Férey G, Mellot-Draznieks C, Serre C, Millange F, Dutour J, Surble S, Margiolaki I (2005) A chromium terephthalate-based solid with unusually large pore volumes and surface area. Science 309:2040–2042. https://doi.org/10.1126/science.1116275
Foster ME, Azoulay JD, Wong BM, Allendorf MD (2014) Novel metal–organic framework linkers for light harvesting applications. Chem Sci 5:2081–2090. https://doi.org/10.1039/C4SC00333K
Fu Y, Sun D, Chen Y, Huang R, Ding Z, Fu X, Li Z (2012) An amine-functionalized titanium metal-organic framework photocatalyst with visible-light-induced activity for CO2 reduction. Angew Chem Int Ed 51:3364–3367. https://doi.org/10.1002/anie.201108357
Fujishima A, Honda K (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature 238:37–38
Furukawa H, Ko N, Go YB, Aratani N, Choi SB, Choi E, Yazaydin AÖ, Snurr RQ, O’Keeffe M, Kim J, Yaghi OM (2010) Ultrahigh porosity in metal-organic frameworks. Science 329:424–428. https://doi.org/10.1126/science.1192160
Gao C, Wang J, Xu H, Xiong Y (2017) Coordination chemistry in the design of heterogeneous photocatalysts. Chem Soc Rev 46:2799–2823. https://doi.org/10.1039/C6CS00727A
Gascon J, Hernández-Alonso MD, Almeida AR, van Klink GPM, Kapteijn F, Mul G (2008) Isoreticular MOFs as efficient photocatalysts with tunable band gap: an operando FTIR study of the photoinduced oxidation of propylene. ChemSusChem 1:981–983. https://doi.org/10.1002/cssc.200800203
Givaja G, Amo-Ochoa P, Gómez-Garcíab CJ, Zamora F (2012) Electrical conductive coordination polymers. Chem Soc Rev 41:115–147. https://doi.org/10.1039/C1CS15092H
Habisreutinger SN, Schmidt-Mende L, Stolarczyk JK (2013) Photocatalytic reduction of CO2 on TiO2 and other semiconductors. Angew Chem Int Ed 52:7372–7408. https://doi.org/10.1002/anie.201207199
Han Y, Bai C, Zhang L, Wu J, Meng H, Xu J, Xu Y, Liang Z, Zhang X (2018) A facile strategy for fabricating AgI–MIL-53(Fe) composites: superior interfacial contact and enhanced visible light photocatalytic performance. New J Chem 42:3799–3807. https://doi.org/10.1039/C8NJ00417J
Harrison WA (1983) Theory of the two-center bond. Phys Rev B 27:3592. https://doi.org/10.1103/PhysRevB.27.3592
Hausdorf S, Wagler J, Mossig R, Mertens FORL (2008) Proton and water activity-controlled structure formation in zinc carboxylate-based metal organic frameworks. J Phys Chem A 112:7567–7576. https://doi.org/10.1021/jp7110633
Hendon CH, Tiana D, Walsh A (2012) Conductive metal–organic frameworks and networks: fact or fantasy? Phys Chem Chem Phys 14:13120–13132. https://doi.org/10.1039/C2CP41099K
Hendon CH, Tiana D, Fontecave M, Sanchez C, D’arras L, Sassoye C, Rozes L, Mellot-Draznieks C, Walsh A (2013) Engineering the optical response of the titanium-MIL-125 metal–organic framework through ligand functionalization. J Am Chem Soc 135:10942–10945. https://doi.org/10.1021/ja405350u
Hoffmann R (1963) An extended Hückel theory. I Hydrocarbons. J Chem Phys 39:1397. https://doi.org/10.1063/1.1734456
Holladay JD, Hu J, King DL, Wang Y (2009) An overview of hydrogen production technologies. Catal Today 139:244–260. https://doi.org/10.1016/j.cattod.2008.08.039
Horike S, Umeyama D, Kitagawa S (2013) Ion conductivity and transport by porous coordination polymers and metal–organic frameworks. Acc Chem Res 46:2376–2384. https://doi.org/10.1021/ar300291s
Horiuchi Y, Toyao T, Saito M, Mochizuki K, Iwata M, Higashimura H, Anpo M, Matsuoka M (2012) Visible-light-promoted photocatalytic hydrogen production by using an amino-functionalized Ti(IV) metal–organic framework. J Phys Chem C 116:20848–20853. https://doi.org/10.1021/jp3046005
Hu K, Blair AD, Piechota EJ, Schauer PA, Sampaio RN, Parlane FGL, Meyer GJ, Berlinguette CP (2016) Kinetic pathway for interfacial electron transfer from a semiconductor to a molecule. Nat Chem 8:853–859. https://doi.org/10.1038/NCHEM.2549
Hua C, Doheny P, Ding B, Chan B, Yu M, Kepert CJ, D’Alessandro DM (2018) Through-space intervalence charge transfer as a mechanism for charge delocalization in metal–organic frameworks. J Am Chem Soc 140:6622–6630. https://doi.org/10.1021/jacs.8b02638
Hückel E (1931) Perspective on “Quantentheoretische Beiträge zum Benzolproblem. I. Die Elektronenkonfiguration des Benzols und verwandter Beziehungen”. Z Phys 70:204–286
Hurd JA, Vaidhyanathan R, Thangadurai V, Ratcliffe CI, Moudrakovski IL, Shimizu GKH (2009) Anhydrous proton conduction at 150°C in a crystalline metal-organic framework. Nat Chem 1:705–710. https://doi.org/10.1038/NCHEM.402
Imaz I, Hernando J, Ruiz-Molina D, Maspoch D (2009) Metal-organic spheres as functional systems for guest encapsulation. Angew Chem Int Ed 48:2325–2329. https://doi.org/10.1002/anie.200804255
Jiao L, Wang Y, Jiang HL, Xu Q (2017) Metal–organic frameworks as platforms for catalytic applications. Adv Mater 30:e1703663. https://doi.org/10.1002/adma.201703663
Johansson PG, Kopecky A, Galoppini E, Meyer GJ (2013) Distance dependent electron transfer at TiO2 interfaces sensitized with phenylene ethynylene bridged RuII–isothiocyanate compounds. J Am Chem Soc 135:8331–8341. https://doi.org/10.1021/ja402193f
Kaake L, Barbara PF, Zhu X-Y (2010) Intrinsic charge trapping in organic and polymeric semiconductors: a physical chemistry perspective. J Phys Chem Lett 1:628–635. https://doi.org/10.1021/jz9002857
Kajiwara T, Fujii M, Tsujimoto M, Kobayashi K, Higuchi M, Tanaka K, Kitagawa S (2016) Photochemical reduction of low concentrations of CO2 in a porous coordination polymer with a ruthenium(II)-CO complex. Angew Chem Int Ed 55:2697–2700. https://doi.org/10.1002/anie.201508941
Kang Z, Fana L, Sun D (2017) Recent advances and challenges of metal–organic framework membranes for gas separation. J Mater Chem A 5:10073–10091. https://doi.org/10.1039/C7TA01142C
Karnahl M, Kuhnt C, Ma F, Yartsev A, Schmitt M, Dietzek B, Rau S, Popp J (2011) Tuning of photocatalytic hydrogen production and photoinduced intramolecular electron transfer rates by regioselective bridging ligand substitution. ChemPhysChem 12:2101–2109. https://doi.org/10.1002/cphc.201100245
Kobayashi Y, Jacobs B, Allendorf MD, Long JR (2010) Conductivity, doping, and redox chemistry of a microporous dithiolene-based metal−organic framework. Chem Mater 22:4120–4122. https://doi.org/10.1021/cm101238m
Kreno LE, Leong K, Farha OK, Allendorf M, Van Duyne RP, Hupp JT (2012) Metal–organic framework materials as chemical sensors. Chem Rev 112:1105–1125. https://doi.org/10.1021/cr200324t
Kubacka A, Fernández-García M, Colón G (2012) Advanced nanoarchitectures for solar photocatalytic applications. Chem Rev 112:1555–1614. https://doi.org/10.1021/cr100454n
Kumar A, Guo C, Sharma G et al (2016) Magnetically recoverable ZrO2/Fe3O4/chitosan nanomaterials for enhanced sunlight driven photoreduction of carcinogenic Cr(VI) and dechlorination & mineralization of 4-chlorophenol from simulated waste water. RSC Adv 6:13251–13263. https://doi.org/10.1039/C5RA23372K
Kumar A, Rana A, Sharma G et al (2018) Aerogels and metal–organic frameworks for environmental remediation and energy production. Environ Chem Lett 16:797–820. https://doi.org/10.1007/s10311-018-0723-x
Larsen RW, Wojtas L (2013) Photoinduced inter-cavity electron transfer between Ru(II)tris(2,2′-bipyridne) and Co(II)tris(2,2′-bipyridine) Co-encapsulated within a Zn(II)-trimesic acid metal organic framework. J Mater Chem A 1:14133–14139. https://doi.org/10.1039/C3TA13422A
Larsen RW, Wojtas L (2015) Fixed distance photoinduced electron transfer between Fe and Zn porphyrins encapsulated within the Zn HKUST-1 metal organic framework. Dalton Trans 44:2959–2963. https://doi.org/10.1039/c4dt02685c
Lau VW-H, Moudrakovski I, Botari T, Weinberger S, Mesch MB, Duppel V, Senker J, Blum V, Lotsch BV (2016) Rational design of carbon nitride photocatalysts by identification of cyanamide defects as catalytically relevant sites. Nat Commun 7:12165. https://doi.org/10.1038/ncomms12165
Lee Y, Kim S, Fei H, Kang JK, Cohen SM (2015) Photocatalytic CO2 reduction using visible light by metal-monocatecholato species in a metal–organic framework. Chem Commun 51:16549–16552. https://doi.org/10.1039/C5CC04506A
Li H, Eddaoudi M, O’Keeffe M, Yaghi OM (1999) Design and synthesis of an exceptionally stable and highly porous metal-organic framework. Nature 402:276–279. https://doi.org/10.1038/46248
Li R, Hu J, Deng M, Wang H, Wang X, Hu Y, Jiang H-L, Jiang J, Zhang Q, Xie Y, Xiong Y (2014) Integration of an inorganic semiconductor with a metal–organic framework: a platform for enhanced gaseous photocatalytic reactions. Adv Mater 26:4783–4788. https://doi.org/10.1002/adma.201400428
Li J-S, Tang Y-J, Li S-L, Zhang S-R, Dai Z-H, Si L, Lan Y-Q (2015) Carbon nanodots functional MOFs composites by a stepwise synthetic approach: enhanced H2 storage and fluorescent sensing. CrystEngComm 17:1080–1085. https://doi.org/10.1039/C4CE02020K
Li Y, Xu H, Ouyangab S, Ye J (2016) Metal-organic frameworks for photocatalysis. Phys Chem Chem Phys 18:7563–7572. https://doi.org/10.1039/C5CP05885F
Li M, Zheng Z, Zheng Y, Cui C, Li C, Li Z (2017) Controlled growth of metal–organic framework on upconversion nanocrystals for NIR-enhanced photocatalysis. ACS Appl Mater Interfaces 9:2899–2905. https://doi.org/10.1021/acsami.6b15792
Li Y, Fu Y, Ni B, Ding K, Chen W, Wu K, Huang X, Zhang Y (2018) Effects of ligand functionalization on the photocatalytic properties of titanium-based MOF: a density functional theory study. AIP Adv 8:035012. https://doi.org/10.1063/1.5021098
Liang R, Jing F, Shen L, Qin N, Wu L (2015) MIL-53(Fe) as a highly efficient bifunctional photocatalyst for the simultaneous reduction of Cr (VI) and oxidation of dyes. J Hazard Mater 287:364–372. https://doi.org/10.1016/j.jhazmat.2015.01.048
Lingampalli SR, Ayyub MM, Rao CNR (2017) Recent progress in the photocatalytic reduction of carbon dioxide. ACS Omega 2:2740–2748. https://doi.org/10.1021/acsomega.7b00721
Linsebigler AL, Lu G, Yates JT (1995) Photocatalysis on TiO2 surfaces: principles, mechanisms, and selected results. Chem Rev 95:735–758. https://doi.org/10.1021/cr00035a013
Liu H, Xu C, Li D, Jiang H-L (2018) Photocatalytic hydrogen production coupled with selective benzylamine oxidation over MOF composites. Angew Chem Int Ed 57:5379–5383. https://doi.org/10.1002/anie.201800320
Llabres i Xamena FX, Abad A, Corma A, Garcia H (2007) MOFs as catalysts: activity, reusability and shape-selectivity of a Pd-containing MOF. J Catal 250:294–298. https://doi.org/10.1016/j.jcat.2007.06.004
Llabrés i Xamena FX, Corma A, Garcia H (2007) Applications for Metal−Organic Frameworks (MOFs) as quantum dot semiconductors. J Phys Chem C 111:80–85. https://doi.org/10.1021/jp063600e
Lopez HA, Dhakshinamoorthy A, Ferrer B, Atienzar P, Alvaro M, Garcia H (2011) Photochemical response of commercial MOFs: Al2(BDC)3 and its use as active material in photovoltaic devices. J Phys Chem C 115:22200–22206. https://doi.org/10.1021/jp206919m
Lu G, Li S, Guo Z, Farha OK, Hauser BG, Qi X, Wang Y, Wang X, Han S, Liu X, DuChene JS, Zhang H, Zhang Q, Chen X, Ma J, Loo SCJ, Wei WD, Yang Y, Hupp JT, Huo F (2012) Imparting functionality to a metal–organic framework material by controlled nanoparticle encapsulation. Nat Chem 4:310–316. https://doi.org/10.1038/nchem.1272
Maeda K, Domen K (2007) New non-oxide photocatalysts designed for overall water splitting under visible light. J Phys Chem C 111:7851–7861. https://doi.org/10.1021/jp070911w
Maity K, Kundu T, Banerjee R, Biradha K (2015) One-dimensional water cages with repeat units of (H2O)24 resembling pagodane trapped in a 3D coordination polymer: proton conduction and tunable luminescence emission by adsorption of anionic dyes. CrystEngComm 17:4439–4443. https://doi.org/10.1039/C5CE00969C
Marcus RA (1956) On the theory of oxidation-reduction reactions involving electron transfer. I. J Chem Phys 24:966. https://doi.org/10.1063/1.1742723
Marcus RA, Sutin N (1985) Electron transfers in chemistry and biology. Biochim Biophys Acta 811:265–322. https://doi.org/10.1016/0304-4173(85)90014-X
Meng X, Yu Q, Liu G, Li S, Zhao G, Liu H, Li P, Chang K, Kako T, Ye J (2017) Efficient photocatalytic CO2 reduction in all-inorganic aqueous environment: cooperation between reaction medium and Cd (II) modified colloidal ZnS. Nano Energy 34:524–532. https://doi.org/10.1016/j.nanoen.2017.03.021
Meyer K, Bashir S, Llorca J, Idriss H, Ranocchiari M, van Bokhoven JA (2016) Photocatalyzed hydrogen evolution from water by a composite catalyst of NH2-MIL-125(Ti) and surface nickel(II) species. Chem Eur J 22:13894–13899. https://doi.org/10.1002/chem.201601988
Mo K, Yang Y, Cui Y (2014) A homochiral metal–organic framework as an effective asymmetric catalyst for cyanohydrin synthesis. J Am Chem Soc 136:1746–1749. https://doi.org/10.1021/ja411887c
Mondloch JE, Bury W, FairenJimenez D, Kwon S, DeMarco EJ, Weston MH, Sarjeant AA, Nguyen ST, Stair PC, Snurr RQ, Farha OK, Hupp JT (2013) Vapor-phase metalation by atomic layer deposition in a metal–organic framework. J Am Chem Soc 135:10294–10297. https://doi.org/10.1021/ja4050828
Nasalevich MA, Goesten MG, Savenije TJ, Kapteijn F, Gascon J (2013) Enhancing optical absorption of metal–organic frameworks for improved visible light photocatalysis. Chem Commun 49:10575–10577. https://doi.org/10.1039/C3CC46398B
Nasalevich MA, van der Veen M, Kapteijn F, Gascon J (2014) Metal–organic frameworks as heterogeneous photocatalysts: advantages and challenges. CrystEngComm 16:4919–4926. https://doi.org/10.1039/C4CE00032C
Okawa H, Shigematsu A, Sadakiyo M, Miyagawa T, Yoneda K, Ohba M, Kitagawa H (2009) Oxalate-bridged bimetallic complexes {NH(prol)3}[MCr(ox)3] (M = MnII, FeII, CoII; NH(prol)3+ = Tri(3-hydroxypropyl)ammonium) exhibiting coexistent ferromagnetism and proton conduction. J Am Chem Soc 131:13516–13522. https://doi.org/10.1021/ja905368d
Okawa H, Sadakiyo M, Yamada T, Maesato M, Ohba M, Kitagawa H (2013) Proton-conductive magnetic metal–organic frameworks, {NR3(CH2COOH)}[MaIIMbIII(ox)3]: effect of carboxyl residue upon proton conduction. J Am Chem Soc 135:2256–2262. https://doi.org/10.1021/ja309968u
Ola O, Maroto-Valer MM (2015) Review of material design and reactor engineering on TiO2 photocatalysis for CO2 reduction. J Photochem Photobiol C Photochem Rev 24:16–42. https://doi.org/10.1016/j.jphotochemrev.2015.06.001
Paille G, Gomez-Mingot M, Roch-Marchal C, Lassalle-Kaiser B, Mialane P, Fontecave M, Mellot-Draznieks C, Dolbecq A (2018) A fully noble metal-free photosystem based on cobalt-polyoxometalates immobilized in a porphyrinic metal–organic framework for water oxidation. J Am Chem Soc 140:3613–3618. https://doi.org/10.1021/jacs.7b11788
Pasveer W, Cottaar J, Tanase C, Coehoorn R, Bobbert P, Blom P, De Leeuw D, Michels M (2005) Unified description of charge-carrier mobilities in disordered semiconducting polymers. Phys Rev Lett 94:206601. https://doi.org/10.1103/PhysRevLett.94.206601
Pi Y, Li X, Xia Q, Wu J, Li Z, Li Y, Xiao J (2017) Formation of willow leaf-like structures composed of NH2-MIL68(In) on a multifunctional multiwalled carbon nanotube backbone for enhanced photocatalytic reduction of Cr (VI). Nano Res 10:3543–3556. https://doi.org/10.1007/s12274-017-1565-8
Portillo AS, Baldoví HG, Fernandez MTG, Navalón S, Atienzar P, Ferrer B, Alvaro M, Garcia H, Li Z (2017) Ti as mediator in the photoinduced electron transfer of mixed-metal NH2–UiO-66(Zr/Ti): transient absorption spectroscopy study and application in photovoltaic cell. J Phys Chem C 121:7015–7024. https://doi.org/10.1021/acs.jpcc.6b13068
Puchberger M, Kogler FR, Jupa M, Gross S, Fric H, Kickelbick G, Schubert U (2006) Can the clusters Zr6O4(OH)4(OOCR)12 and [Zr6O4(OH)4(OOCR)12]2 be converted into each other? Eur J Inorg Chem 6:3283–3293. https://doi.org/10.1002/ejic.200600348
Ren J, Guo H, Yang J, Qin Z, Lin J, Li Z (2015) Insights into the mechanisms of CO2 methanation on Ni(111) surfaces by density functional theory. Appl Surf Sci 351:504–516. https://doi.org/10.1016/j.apsusc.2015.05.173
Rodríguez NA, Savateev A, Grela MA, Dontsova D (2017) Facile synthesis of potassium poly(heptazine imide) (PHIK)/Ti-based metal–organic framework (MIL-125-NH2) composites for photocatalytic applications. ACS Appl Mater Interfaces 9:22941–22294. https://doi.org/10.1021/acsami.7b04745
Rosseinsky DR, Tonge JS, Berthelot J, Cassidy JF (1987) Site-transfer conductivity in solid iron hexacyanoferrates by dielectric relaxometry, voltammetry and spectroscopy. Prussian Blue, congeners and mixtures. J Chem Soc Faraday Trans 83:231–243. https://doi.org/10.1039/F19878300231
Sahoo P, Tan JB, Zhang Z-M, Singh SK, Lu TB (2018) Engineering the surface structure of binary/ternary ferrite nanoparticles as high-performance electrocatalysts for the oxygen evolution reaction. ChemCatChem 10:1075–1083. https://doi.org/10.1002/cctc.201701790
Savenije TJ, Ferguson AJ, Kopidakis N, Rumbles G (2013) Revealing the dynamics of charge carriers in polymer: fullerene blends using photoinduced time-resolved microwave conductivity. J Phys Chem C 117:24085–24103. https://doi.org/10.1021/jp406706u
Schneider J, Matsuoka M, Takeuchi M, Zhang J, Horiuchi Y, Anpo M, Bahnemann DW (2014) Understanding TiO2 photocatalysis: mechanisms and materials. Chem Rev 114:9919–9986. https://doi.org/10.1021/cr5001892
Sen S, Yamada T, Kitagawa H, Bharadwaj PK (2014) 3D coordination polymer of Cd(II) with an imidazolium-based linker showing parallel polycatenation forming channels with aligned imidazolium groups. Cryst Growth Des 14:1240–1244. https://doi.org/10.1021/cg401760m
Serpone N, Emeline A (2012) Semiconductor photocatalysis — past, present, and future outlook. J Phys Chem Lett 3:673–677. https://doi.org/10.1021/jz300071j
Sha Z, Sun J, Chan HSO, Jaenicke S, Wu J (2015) Enhanced photocatalytic activity of the AgI/UiO-66(Zr) composite for rhodamine B degradation under visible-light irradiation. ChemPlusChem 80:1321–1328. https://doi.org/10.1002/cplu.201402430
Sharma S, Ghosh SK (2018) Metal−organic framework-based selective sensing of biothiols via chemidosimetric approach in water. ACS Omega 3:254–258. https://doi.org/10.1021/acsomega.7b01891
Shen L, Luo M, Liu Y, Liang R, Jing F, Wu L (2015) Noble-metal-free MoS2 co-catalyst decorated UiO-66/CdS hybrids for efficient photocatalytic H2 production. Appl Catal B 166–167:445–452. https://doi.org/10.1016/j.apcatb.2014.11.056
Shi L, Wang T, Zhang H, Chang K, Meng X, Liu H, Ye J (2015) An amine-functionalized iron (III) metal–organic framework as efficient visible-light photocatalyst for Cr (VI) reduction. Adv Sci 2:1500006. https://doi.org/10.1002/advs.201500006
Shimizu GKH, Taylor JM, Kim S (2013) Proton conduction with metal-organic frameworks. Science 341:354–355. https://doi.org/10.1126/science.1239872
Silva CG, Luz I, LlabrésiXamena FX, Corma A, García H (2010a) Water stable Zr–benzenedicarboxylate metal–organic frameworks as photocatalysts for hydrogen generation. Chem Eur J 16:11133–11138. https://doi.org/10.1002/chem.200903526
Silva CG, Corma A, Garcia H (2010b) Metal–organic frameworks as semiconductors. J Mater Chem 20:3141–3156. https://doi.org/10.1039/B924937K
Sivula K, van de Krol R (2016) Semiconducting materials for photoelectrochemical energy conversion. Nat Rev Mater 1:15010. https://doi.org/10.1038/natrevmats.2015.10
Song F, Wang C, Lin W (2011) A chiral metal–organic framework for sequential asymmetric catalysis. Chem Commun 47:8256–8258. https://doi.org/10.1039/C1CC12701B
Stavila V, Talin AA, Allendorf MD (2014) MOF-based electronic and opto-electronic devices. Chem Soc Rev 43:5994–6010. https://doi.org/10.1039/C4CS00096J
Sun F, Yin Z, Wang Q-Q, Sun D, Zeng M-H, Kurmoo M (2013) Tandem postsynthetic modification of a metal–organic framework by thermal elimination and subsequent bromination: effects on absorption properties and photoluminescence. Angew Chem Int Ed 52:1–6. https://doi.org/10.1002/ange.201300821
Sun D, Gao Y, Fu J, Zeng X, Chenb Z, Li Z (2015a) Construction of a supported Ru complex on bifunctional MOF-253 for photocatalytic CO2 reduction under visible light. Chem Commun 51:2645–2648. https://doi.org/10.1039/C4CC09797A
Sun D, Ye L, Li Z (2015b) Visible-light-assisted aerobic photocatalytic oxidation of amines to imines over NH2-MIL-125(Ti). Appl Catal B Environ 164:428–432. https://doi.org/10.1016/j.apcatb.2014.09.054
Tachikawa T, Choi JR, Fujitsuka M, Majima T (2008) Photoinduced charge-transfer processes on MOF-5 nanoparticles: elucidating differences between metal-organic frameworks and semiconductor metal oxides. J Phys Chem C 112:14090–14101. https://doi.org/10.1021/jp803620v
Takanabe K (2017) Photocatalytic water splitting: quantitative approaches toward photocatalyst by design. ACS Catal 7:8006–8022. https://doi.org/10.1021/acscatal.7b02662
Tian J, Xu Z-Y, Zhang D-W, Wang H, Xie S-H, Xu D-W, Ren Y-H, Wang H, Liu Y, Li Z-T (2016) Supramolecular metal-organic frameworks that display high homogeneous and heterogeneous photocatalytic activity for H2 production. Nat Commun 7:11580. https://doi.org/10.1038/ncomms11580
Toyao T, Saito M, Horiuchi Y, Mochizuki K, Iwata M, Higashimura H, Matsuoka M (2013) Efficient hydrogen production and photocatalytic reduction of nitrobenzene over a visiblelight- responsive metal–organic framework photocatalyst. Cat Sci Technol 3:2092–2097
Tranchemontagne DJ, Hunt JR, Yaghi OM (2008) Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0. Tetrahedron 64:8553–8557
Van Wyk A, Smith T, Park J, Deria P (2018) Charge-transfer within Zr-based metal–organic framework: the role of polar node. J Am Chem Soc 140:2756–2760. https://doi.org/10.1021/jacs.7b13211
Vlasova EA, Yakimov SA, Naidenko EV, Kudrik EV, Makarov SV (2016) Application of metal–organic frameworks for purification of vegetable oils. Food Chem 190:103–109. https://doi.org/10.1016/j.foodchem.2015.05.078
Vu TA, Le GH, Vu HT, Nguyen KT, Quan TTT, Nguyen QK, Tran HTK, Dang PT, Vu LD, Lee GD (2017) Highly photocatalytic activity of novel Fe-MIL-88B/GO nanocomposite in the degradation of reactive dye from aqueous solution. Mater Res Express 4:035038. https://doi.org/10.1088/2053-1591/aa6079
Wakaoka T, Hirai K, Murayama K, Takano Y, Takagi H, Furukawa S, Kitagawa S (2014) Confined synthesis of CdSe quantum dots in the pores of metal–organic frameworks. J Mater Chem C 2:7173–7175. https://doi.org/10.1039/C4TC01136H
Wang S, Wang X (2015) Multifunctional metal-organic frameworks for photocatalysis. Small 11:30973112. https://doi.org/10.1002/smll.201500084
Wang C, Xie Z, deKrafft KE, Lin W (2011) Doping metal–organic frameworks for water oxidation, carbon dioxide reduction, and organic photocatalysis. J Am Chem Soc 133:13445–13454. https://doi.org/10.1021/ja203564w
Wang C, Wang J-L, Lin W (2012) Elucidating molecular iridium water oxidation catalysts using metal–organic frameworks: a comprehensive structural, catalytic, spectroscopic, and kinetic study. J Am Chem Soc 134:19895–11990. https://doi.org/10.1021/ja310074j
Wang D, Huang R, Liu W, Sun D, Li Z (2014) Fe-based MOFs for photocatalytic CO2 reduction: role of coordination unsaturated sites and dual excitation pathways. ACS Catal 4:4254–4260. https://doi.org/10.1021/cs501169t
Wang D, Wang M, Li Z (2015) Fe-based metal–organic frameworks for highly selective photocatalytic benzene hydroxylation to phenol. ACS Catal 5:6852–6857. https://doi.org/10.1021/acscatal.5b01949
Wang J-W, Sahoo P, Lu T-B (2016) Reinvestigation of water oxidation catalyzed by a dinuclear cobalt polypyridine complex: identification of CoOx as a real heterogeneous catalyst. ACS Catal 6:5062–5068. https://doi.org/10.1021/acscatal.6b00798
Wang W, Xu X, Zhou W, Shao Z (2017) Recent progress in metal-organic frameworks for applications in electrocatalytic and photocatalytic water splitting. Adv Sci 4:1600371. https://doi.org/10.1002/advs.201600371
Wang M, Liu J, Guo C, Gao X, Gong C, Wang Y, Liu B, Li X, Gurzadyana GG, Sun L (2018a) Metal–organic frameworks (ZIF-67) as efficient cocatalysts for photocatalytic reduction of CO2: the role of the morphology effect. J Mater Chem A 6:4768–4775. https://doi.org/10.1039/C8TA00154E
Wang M, Yang L, Guo C, Liu X, He L, Song Y, Zhang Q, Qu X, Zhang H, Zhang Z, Fang S (2018b) Bimetallic Fe/Ti-based metal–organic framework for persulfate-assisted visible light photocatalytic degradation of orange II. Chem Sel 3:3664–3674. https://doi.org/10.1002/slct.201703134
Wasielewski MR (1992) Photoinduced electron transfer in supramolecular systems for artificial photosynthesis. Chem Rev 92:435–461. https://doi.org/10.1021/cr00011a005
Wee LH, Janssens N, Sree SP, Wiktor C, Gobechiya E, Fischer RA, Kirschhock CEA, Martens JA (2014) Local transformation of ZIF-8 powders and coatings into ZnO nanorods for photocatalytic application. Nanoscale 6:2056–2060. https://doi.org/10.1039/C3NR05289C
Weinberg DR, Gagliard CJ, Hull JF, Murphy CF, Kent CA, Westlake BC, Paul A, Ess DH, McCafferty DG, Meyer TJ (2012) Proton-coupled electron transfer. Chem Rev 112:4016–4093. https://doi.org/10.1021/cr200177j
Wu MX, Yang YW (2017) Metal–Organic Framework (MOF)-based drug/cargo delivery and cancer therapy. Adv Mater 29:1606134. https://doi.org/10.1002/adma.201606134
Wu P, He C, Wang J, Peng X, Li X, An Y, Duan C (2012) Photoactive chiral metal–organic frameworks for light-driven asymmetric α-alkylation of aldehydes. J Am Chem Soc 134:14991–14999. https://doi.org/10.1021/ja305367j
Xu H-Q, Hu J, Wang D, Li Z, Zhang Q, Luo Y, Yu S-H, Jiang H-L (2015) Visible-light photoreduction of CO2 in a metal–organic framework: boosting electron–hole separation via electron trap states. J Am Chem Soc 137:13440–13443. https://doi.org/10.1021/jacs.5b08773
Yang L-M, Fang G-Y, Ma J, Ganz E, Han SS (2014) Band gap engineering of paradigm MOF-5. Cryst Growth Des 14:2532–2541. https://doi.org/10.1021/cg500243s
Yu X, Wang L, Cohen SM (2017) Photocatalytic metal–organic frameworks for organic transformations. CrystEngComm 19:4126–4136. https://doi.org/10.1039/C7CE00398F
Yuan X, Wang H, Wu Y, Zeng G, Chen X, Leng L, Wu Z, Li H (2016) One-pot self-assembly and photoreduction synthesis of silver nanoparticle-decorated reduced graphene oxide/MIL-125(Ti) photocatalyst with improved visible light photocatalytic activity. Appl Organomet Chem 30:289–296. https://doi.org/10.1002/aoc.3430
Zeng L, Guo X, He C, Duan C (2016) Metal–organic frameworks: versatile materials for heterogeneous photocatalysis. ACS Catal 6:7935–7945. https://doi.org/10.1021/acscatal.6b02228
Zhang T, Lin W (2014) Struct Bond 157: 89. https://doi.org/10.1007/430_2013_131 # Springer, Berlin/Heidelberg 2013, Published online: 7 September (2013)
Zhang S, Li L, Zhao S, Sun Z, Hongab M, Luo J (2015a) Hierarchical metal–organic framework nanoflowers for effective CO2 transformation driven by visible light. J Mater Chem A 3:15764–15768. https://doi.org/10.1039/C5TA03322E
Zhang Z-M, Zhang T, Wang C, Lin Z, Long L-S, Lin W (2015b) Photosensitizing metal–organic framework enabling visible-light-driven proton reduction by a Wells–Dawson-type polyoxometalate. J Am Chem Soc 137:3197–3200. https://doi.org/10.1021/jacs.5b00075
Zhang Q, Zhang C, Cao L, Wang Z, An B, Lin Z, Huang R, Zhang Z, Wang C, Lin W (2016) Förster energy transport in metal–organic frameworks is beyond step-by-step hopping. J Am Chem Soc 138:5308–5315. https://doi.org/10.1021/jacs.6b01345
Zhang Y, Guo J, Shi L, Zhu Y, Hou K, Zheng Y, Tang Z (2017) Tunable chiral metal organic frameworks toward visible light–driven asymmetric catalysis. Sci Adv 3:e1701162. https://doi.org/10.1126/sciadv.1701162
Zhou H-C, Long JR, Yaghi OM (2012) Introduction to metal–organic frameworks. Chem Rev 112:673–674. https://doi.org/10.1021/cr300014x
Zhu C, Xia Q, Chen X, Liu Y, Du X, Cui Y (2016) Chiral metal–organic framework as a platform for cooperative catalysis in asymmetric cyanosilylation of aldehydes. ACS Catal 6:7590–7596. https://doi.org/10.1021/acscatal.6b02359
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Bag, P.P., Sahoo, P. (2020). Designing Metal-Organic Frameworks Based Photocatalyst for Specific Photocatalytic Reactions: A Crystal Engineering Approach. In: Rajendran, S., Naushad, M., Ponce, L., Lichtfouse, E. (eds) Green Photocatalysts for Energy and Environmental Process. Environmental Chemistry for a Sustainable World, vol 36. Springer, Cham. https://doi.org/10.1007/978-3-030-17638-9_6
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