Abstract
In recent years, the textile industry has been moving to novel concepts of products, which could deliver to the user, improved performances. Such smart textiles have been proven to have the potential to integrate within a commodity garment advanced feature and functional properties of different kinds. Among those functionalities, considerable interest has been played in functionalizing commodity garments in order to make them positively interact with the human body and therefore being beneficial to the user health. This kind of functionalization generally exploits biopolymers, a class of materials that possess peculiar properties such as biocompatibility and biodegradability that make them suitable for bio-functional textile production. In the context of biopolymer chitosan has been proved to be an excellent potential candidate for this kind of application given its abundant availability and its chemical properties that it positively interacts with biological tissue. Notwithstanding the high potential of chitosan-based technologies in the textile sectors, several issues limit the large-scale production of such innovative garments. In facts the morphologies of chitosan structures should be optimized in order to make them better exploit the biological activity; moreover a suitable process for the application of chitosan structures to the textile must be designed. The application process should indeed not only allow an effective and durable fixation of chitosan to textile but also comply with environmental rules concerning pollution emission and utilization of harmful substances.
This chapter reviews the use of microencapsulation technique as an approach to effectively apply chitosan to the textile material while overcoming the significant limitations of finishing processes. The assembly of chitosan macromolecules into microcapsules was proved to boost the biological properties of the polymer thanks to a considerable increase in the surface area available for interactions with the living tissues. Moreover, the incorporation of different active substances into chitosan shells allows the design of multifunctional materials that effectively combine core and shell properties. Based on the kind of substances to be incorporated, several encapsulation processes have been developed. The literature evidences how the proper choices concerning encapsulation technology, chemical formulations, and process parameter allow tuning the properties and the performances of the obtained microcapsules. Furthermore, the microcapsules based finishing process have been reviewed evidencing how the microcapsules morphology can positively interact with textile substrate allowing an improvement in the durability of the treatment. The application of the chitosan shelled microcapsules was proved to be capable of imparting different functionalities to textile substrates opening possibilities for a new generation of garments with improved performances and with the potential of protecting the user from multiple harms. Lastly, a continuous interest was observed in improving the process and formulation design in order to avoid the usage of toxic substances, therefore, complying with an environmentally friendly approach.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsReferences
AbdElhady MM (2012) Preparation and characterization of chitosan/zinc oxide nanoparticles for imparting antimicrobial and UV protection to cotton fabric. Int J Carbohydr Chem 2012:1–6. https://doi.org/10.1155/2012/840591
Abdel-Halim ES, Abdel-Mohdy FA, Al-Deyab SS, El-Newehy MH (2010) Chitosan and monochlorotriazinyl-β-cyclodextrin finishes improve antistatic properties of cotton/polyester blend and polyester fabrics. Carbohydr Polym 82:202–208. https://doi.org/10.1016/j.carbpol.2010.04.077
Abou-Okeil A, El-Shafie A, Hebeish A (2007) Chitosan phosphate induced better thermal characteristics to cotton fabric. J Appl Polym Sci 103:2021–2026. https://doi.org/10.1002/app.25322
Agnihotri SA, Mallikarjuna NN, Aminabhavi TM (2004) Recent advances on chitosan-based micro- and nanoparticles in drug delivery. J Control Release 100:5–28. https://doi.org/10.1016/j.jconrel.2004.08.010
Alay Aksoy S, Alkan C, Tözüm MS, Demirbağ S, Altun Anayurt R, Ulcay Y (2016) Preparation and textile application of poly(methyl methacrylate-co-methacrylic acid)/n-octadecane and n-eicosane microcapsules. J Text I 108:30–41. https://doi.org/10.1080/00405000.2015.1133128
Ali SW, Rajendran S, Joshi M (2011) Synthesis and characterization of chitosan and silver loaded chitosan nanoparticles for bioactive polyester. Carbohydr Polym 83:438–446. https://doi.org/10.1016/j.carbpol.2010.08.004
Alonso D, Gimeno M, Olayo R, Vázquez-Torres H, Sepúlveda-Sánchez JD, Shirai K (2009) Cross-linking chitosan into UV-irradiated cellulose fibers for the preparation of antimicrobial-finished textiles. Carbohydr Polym 77:536–543. https://doi.org/10.1016/j.carbpol.2009.01.027
Alonso D, Gimeno M, Sepulveda-Sanchez JD, Shirai K (2010) Chitosan-based microcapsules containing grapefruit seed extract grafted onto cellulose fibers by a non-toxic procedure. Carbohydr Res 345:854–859. https://doi.org/10.1016/j.carres.2010.01.018
Antunes L, Faustino G, Mouro C, Vaz J, Gouveia IC (2014) Bioactive microsphere-based coating for biomedical-textiles with encapsulated antimicrobial peptides (AMPs). Ciência & Tecnologia dos Materiais 26:118–125. https://doi.org/10.1016/j.ctmat.2015.03.006
Argenziano M, Banche G, Luganini A, Finesso N, Allizond V, Gulino GR et al (2017) Vancomycin-loaded nanobubbles: a new platform for controlled antibiotic delivery against methicillin-resistant Staphylococcus aureus infections. Int J Pharm 523:176–188. https://doi.org/10.1016/j.ijpharm.2017.03.033
Ashraf M, Champagne P, Campagne C, Perwuelz A, Dumont F, Leriche A (2014) Study the multi self-cleaning characteristics of ZnO nanorods functionalized polyester fabric. J Ind Text 45:1440–1456. https://doi.org/10.1177/1528083714562086
Bahmani SA, East GC, Holme I (2000) The application of chitosan in pigment printing. Color Technol 116:94–99. https://doi.org/10.1111/j.1478-4408.2000.tb00027.x
Basal G, Sirin Deveci S, Yalcin D, Bayraktar O (2011) Properties of n-eicosane-loaded silk fibroin-chitosan microcapsules. J Appl Polym Sci 121:1885–1889. https://doi.org/10.1002/app.33651
Bashari A, Shakeri M, Shirvan AR, Najafabadi SA (2018) Chapter 1: functional finishing of textiles via nanomaterials. In: Ul-Islam S, Butola B (eds) Nanomaterials in the wet processing of textiles. Scrivener Publishing LLC, Beverly, pp 1–70. https://doi.org/10.1002/9781119459804.ch1
Bouwmeester H, van der Zande M, Jepson MA (2018) Effects of food-borne nanomaterials on gastrointestinal tissues and microbiota. Wiley Interdiscip Rev Nanomed Nanobiotechnol 10. https://doi.org/10.1002/wnan.1481
Bui V, Park D, Lee Y-C (2017) Chitosan combined with ZnO, TiO2 and Ag nanoparticles for antimicrobial wound healing applications: a mini review of the research trends. Polymers 9:21. https://doi.org/10.3390/polym9010021
Butstraen C, Salaün F (2014) Preparation of microcapsules by complex coacervation of gum Arabic and chitosan. Carbohydr Polym 99:608–616. https://doi.org/10.1016/j.carbpol.2013.09.006
Cauda V, Pugliese D, Garino N, Sacco A, Bianco S, Bella F et al (2014) Multi-functional energy conversion and storage electrodes using flower-like zinc oxide nanostructures. Energy 65:639–646. https://doi.org/10.1016/j.energy.2013.12.025
Chaiyasat A (2018) Innovative bifunctional microcapsule for heat storage and antibacterial properties. Int J Geomate 14. https://doi.org/10.21660/2018.45.7311
Chandrasekar S, Vijayakumar S, Rajendran R (2014) Application of chitosan and herbal nanocomposites to develop antibacterial medical textile. Biomed Aging Pathol 4:59–64. https://doi.org/10.1016/j.biomag.2013.10.007
Charuchinda S, Srikulkit K (2005) Co-application of sodium polyphosphate and chitosan to improve flame retardancy of cotton fabric. J Sci Res Chulalongkorn Univ 30:97–107
Chatterjee S, Salaün F, Campagne C, Vaupre S, Beirão A (2012) Preparation of microcapsules with multi-layers structure stabilized by chitosan and sodium dodecyl sulfate. Carbohydr Polym 90:967–975. https://doi.org/10.1016/j.carbpol.2012.06.028
Chatterjee S, Salaün F, Campagne C (2014a) Development of multilayer microcapsules by a phase coacervation method based on ionic interactions for textile applications. Pharmaceutics 6:281–297. https://doi.org/10.3390/pharmaceutics6020281
Chatterjee S, Salaün F, Campagne C (2014b) The influence of 1-butanol and trisodium citrate ion on morphology and chemical properties of chitosan-based microcapsules during rigidification by alkali treatment. Mar Drugs 12:5801–5816. https://doi.org/10.3390/md12125801
Chatterjee S, Salaün F, Campagne C, Vaupre S, Beirão A, El-Achari A (2014c) Synthesis and characterization of chitosan droplet particles by ionic gelation and phase coacervation. Polym Bull 71:1001–1013. https://doi.org/10.1007/s00289-014-1107-4
Chelaru C, Ignat M, Albu M, Meghea A (2015) Polymeric microcapsules for cosmetic applications, based on lemon essential oil. UPB Sci Bull Ser B Chem Mater Sci 77:101–112
Deveci SS, Basal G (2009) Preparation of PCM microcapsules by complex coacervation of silk fibroin and chitosan. Colloid Polym Sci 287:1455–1467. https://doi.org/10.1007/s00396-009-2115-z
Divya K, Vijayan S, George TK, Jisha MS (2017) Antimicrobial properties of chitosan nanoparticles: mode of action and factors affecting activity. Fiber Polym 18:221–230. https://doi.org/10.1007/s12221-017-6690-1
Donalisio M, Leone F, Civra A, Spagnolo R, Ozer O, Lembo D, Cavalli R (2018) Acyclovir-loaded chitosan nanospheres from nano-emulsion templating for the topical treatment of herpesviruses infections. Pharmaceutics 10. https://doi.org/10.3390/pharmaceutics10020046
Dotti F, Ferri A, Moncalero M, Colonna M (2016) Thermo-physiological comfort of soft-shell back protectors under controlled environmental conditions. Appl Ergon 56:144–152. https://doi.org/10.1016/j.apergo.2016.04.002
Doumbia AS, Vezin H, Ferreira M, Campagne C, Devaux E (2015) Studies of polylactide/zinc oxide nanocomposites: influence of surface treatment on zinc oxide antibacterial activities in textile nanocomposites. J Appl Polym Sci 132. https://doi.org/10.1002/app.41776
El-Tahlawy K (2008) Chitosan phosphate: a new way for production of eco-friendly flame-retardant cotton textiles. J Text I 99:185–191. https://doi.org/10.1080/00405000701584311
Erkan G, Sariiski M (2004) Microencapsulation in textile. Colourage 51:61–64
Fan F, Zhang W, Wang C (2015) Covalent bonding and photochromic properties of double-shell polyurethane-chitosan microcapsules crosslinked onto cotton fabric. Cellulose 22:1427–1438. https://doi.org/10.1007/s10570-015-0567-5
Fei B, Xin JH (2007) N, N-diethyl-m-toluamide–containing microcapsules for bio-cloth finishing. Am J Trop Med Hyg 77:52–57. https://doi.org/10.4269/ajtmh.2007.77.52
Fornasiero F (2017) Water vapor transport in carbon nanotube membranes and application in breathable and protective fabrics. Curr Opin Chem Eng 16:1–8. https://doi.org/10.1016/j.coche.2017.02.001
Garud A, Garud N (2010) Preparation and evaluation of chitosan microcapsules of metronidazole using tripolyphosphate cross-linking method. Dhaka Univ J Pharm Sci 9:125–130. https://doi.org/10.3329/dujps.v9i2.7897
Genç E, Alay Aksoy S (2016) Fabrication of microencapsulated PCMs with nanoclay doped chitosan shell and their application to cotton fabric. Teks Konfeksiyon 26:180–188
Gordon N (2001) Microencapsulation in textile finishing. Rev Prog Color Relat Top 31:57–64. https://doi.org/10.1111/j.1478-4408.2001.tb00138.x
Hassan MM, Sunderland M (2015) Antimicrobial and insect-resist wool fabrics by coating with microencapsulated antimicrobial and insect-resist agents. Prog Org Coat 85:221–229. https://doi.org/10.1016/j.porgcoat.2015.04.016
Helander IM, Nurmiaho-Lassila EL, Ahvenainen R, Rhoades J, Roller S (2001) Chitosan disrupts the barrier properties of the outer membrane of gram-negative bacteria. Int J Food Microbiol 71:235–244. https://doi.org/10.1016/s0168-1605(01)00609-2
Hoseinzadeh E, Makhdoumi P, Taha P, Hossini H, Stelling J, Kamal MA, Ashraf GM (2017) A review on nano-antimicrobials: metal nanoparticles, methods and mechanisms. Curr Drug Metab 18:120–128. https://doi.org/10.2174/1389200217666161201111146
Hsieh F-M, Huang C, Lin T-F, Chen Y-M, Lin J-C (2008) Study of sodium tripolyphosphate-crosslinked chitosan beads entrapped with Pseudomonas putida for phenol degradation. Process Biochem 43:83–92. https://doi.org/10.1016/j.procbio.2007.10.016
Hu J, Xiao Z-B, Zhou R-J, Ma S-S, Li Z, Wang M-X (2011) Comparison of compounded fragrance and chitosan nanoparticles loaded with fragrance applied in cotton fabrics. Text Res J 81:2056–2064. https://doi.org/10.1177/0040517511416274
Hu S, Song L, Pan H, Hu Y (2012) Thermal properties and combustion behaviors of chitosan based flame retardant combining phosphorus and nickel. Ind Eng Chem Res 51:3663–3669. https://doi.org/10.1021/ie2022527
Huang K-S, Wu W-J, Chen J-B, Lian H-S (2008) Application of low-molecular-weight chitosan in durable press finishing. Carbohydr Polym 73:254–260. https://doi.org/10.1016/j.carbpol.2007.11.023
Hui PC, Wang WY, Kan CW, Ng FS, Wat E, Zhang VX et al (2013) Microencapsulation of traditional chinese herbs-pentaherbs extracts and potential application in healthcare textiles. Colloids Surf B: Biointerfaces 111:156–161. https://doi.org/10.1016/j.colsurfb.2013.05.036
Ivanova NA, Rutberg GI, Philipchenko AB (2013) Enhancing the superhydrophobic state stability of chitosan-based coatings for textiles. Macromol Chem Phys 214:1515–1521. https://doi.org/10.1002/macp.201300273
Javid A, Raza ZA, Hussain T, Rehman A (2014) Chitosan microencapsulation of various essential oils to enhance the functional properties of cotton fabric. J Microencapsul 31:461–468. https://doi.org/10.3109/02652048.2013.879927
Kandola BK, Horrocks AR, Price D, Coleman GV (1996) Flame-retardant treatments of cellulose and their influence on the mechanism of cellulose pyrolysis. J Macromol Sci Polym Rev 36:721–794. https://doi.org/10.1080/15321799608014859
Kasaai MR (2010) Determination of the degree of N-acetylation for chitin and chitosan by various NMR spectroscopy techniques: a review. Carbohydr Polym 79:801–810. https://doi.org/10.1016/j.carbpol.2009.10.051
Khadjavi A, Magnetto C, Panariti A, Argenziano M, Gulino GR, Rivolta I et al (2015) Chitosan-shelled oxygen-loaded nanodroplets abrogate hypoxia dysregulation of human keratinocyte gelatinases and inhibitors: new insights for chronic wound healing. Toxicol Appl Pharmacol 286:198–206. https://doi.org/10.1016/j.taap.2015.04.015
Kondo A (1979) Microcapsule processing and technology. Marcel Dekker, New York
Konuklu Y, Paksoy HO (2015) The preparation and characterization of chitosan-gelatin microcapsules and microcomposites with fatty acids as thermal energy storage materials. Energy Technol 3:503–508. https://doi.org/10.1002/ente.201402178
Kovach I, Won J, Friberg SE, Koetz J (2016) Completely engulfed olive/silicone oil Janus emulsions with gelatin and chitosan. Colloid Polym Sci 294:705–713. https://doi.org/10.1007/s0039601638284
Kulkarni A, Tourrette A, Warmoeskerken MMCG, Jocic D (2010) Microgel-based surface modifying system for stimuli-responsive functional finishing of cotton. Carbohydr Polym 82:1306–1314. https://doi.org/10.1016/j.carbpol.2010.07.011
Lam PL, Li L, Yuen CWM, Gambari R, Wong RSM, Chui CH, Lam KH (2013) Effects of multiple washing on cotton fabrics containing berberine microcapsules with anti-Staphylococcus aureus activity. J Microencapsul 30:143–150. https://doi.org/10.3109/02652048.2012.704953
Laufer G, Kirkland C, Morgan AB, Grunlan JC (2012) Intumescent multilayer nanocoating, made with renewable polyelectrolytes, for flame-retardant cotton. Biomacromolecules 13:2843–2848. https://doi.org/10.1021/bm300873b
Laurenti M, Cauda V (2017) ZnO nanostructures for tissue engineering applications. Nanomaterials (Basel) 7. https://doi.org/10.3390/nano7110374
Leistner M, Abu-Odeh AA, Rohmer SC, Grunlan JC (2015) Water-based chitosan/melamine polyphosphate multilayer nanocoating that extinguishes fire on polyester-cotton fabric. Carbohydr Polym 130:227–232. https://doi.org/10.1016/j.carbpol.2015.05.005
Li Y, Ai L, Yokoyama W, Shoemaker CF, Wei D, Ma J, Zhong F (2013) Properties of chitosan-microencapsulated orange oil prepared by spray-drying and its stability to detergents. J Agric Food Chem 61:3311–3319. https://doi.org/10.1021/jf305074q
Li G, Li Y, Chen G, He J, Han Y, Wang X, Kaplan DL (2015) Silk-based biomaterials in biomedical textiles and fiber-based implants. Adv Healthc Mater 4:1134–1151. https://doi.org/10.1002/adhm.201500002
Li J, Wu Y, Zhao L (2016) Antibacterial activity and mechanism of chitosan with ultra high molecular weight. Carbohydr Polym 148:200–205. https://doi.org/10.1016/j.carbpol.2016.04.025
Liu L, Yang JP, Ju XJ, Xie R, Liu YM, Wang W (2011) Monodisperse core-shell chitosan microcapsules for pH-responsive burst release of hydrophobic drugs. Soft Matter 7:4821. https://doi.org/10.1039/c0sm01393e
Liu J, Liu C, Liu Y, Chen M, Hu Y, Yang Z (2013) Study on the grafting of chitosan-gelatin microcapsules onto cotton fabrics and its antibacterial effect. Colloids Surf B: Biointerfaces 109:103–108. https://doi.org/10.1016/j.colsurfb.2013.03.040
Ma Z, Garrido-Maestu A, Jeong KC (2017) Application, mode of action, and in vivo activity of chitosan and its micro- and nanoparticles as antimicrobial agents: a review. Carbohydr Polym 176:257–265. https://doi.org/10.1016/j.carbpol.2017.08.082
Maji TK, Hussain MR (2008) Microencapsulation of zanthoxylum limonellaoil (ZLO) in genipin crosslinked chitosan-gelatin complex for mosquito repellent application. J Appl Polym Sci 111:779–785. https://doi.org/10.1002/app.29001
Mantegazza V, Contini M, Botti M, Ferri A, Dotti F, Berardi P, Agostoni P (2018) Improvement in exercise capacity and delayed anaerobic metabolism induced by far-infrared-emitting garments in active healthy subjects: a pilot study. Eur J Prev Cardiol:2047487318768598. https://doi.org/10.1177/2047487318768598
Martí M, Rodríguez R, Carreras N, Lis M, Valldeperas J, Coderch L, Parra JL (2012) Monitoring of the microcapsule/liposome application on textile fabrics. J Text I 103:19–27. https://doi.org/10.1080/00405000.2010.542011
Massella D, Leone F, Peila R, Barresi AA, Ferri A (2017) Functionalization of cotton fabrics with polycaprolactone nanoparticles for transdermal release of melatonin. J Funct Biomater 9:1. https://doi.org/10.3390/jfb9010001
Mathis R, Mehling A (2011) Chapter 6: textiles with cosmetic effects. In: Bartels VT (ed) Handbook of medical textiles. Woodhead Publishing, Oxford, pp 153–172. https://doi.org/10.1533/9780857093691.1.153
Mihailiasa M, Caldera F, Li J, Peila R, Ferri A, Trotta F (2016) Preparation of functionalized cotton fabrics by means of melatonin loaded beta-cyclodextrin nanosponges. Carbohydr Polym 142:24–30. https://doi.org/10.1016/j.carbpol.2016.01.024
Monllor P, Bonet MA, Cases F (2007) Characterization of the behaviour of flavour microcapsules in cotton fabrics. Eur Polym J 43:2481–2490. https://doi.org/10.1016/j.eurpolymj.2007.04.004
Morais DS, Guedes RM, Lopes MA (2016) Antimicrobial approaches for textiles: from research to market. Materials (Basel) 9:498. https://doi.org/10.3390/ma9060498
Mostafalu P, Kiaee G, Giatsidis G, Khalilpour A, Nabavinia M, Dokmeci MR et al (2017) A textile dressing for temporal and dosage controlled drug delivery. Adv Funct Mater 27:1702399. https://doi.org/10.1002/adfm.201702399
Muzzarelli RAA (2009) Genipin-crosslinked chitosan hydrogels as biomedical and pharmaceutical aids. Carbohydr Polym 77:1–9. https://doi.org/10.1016/j.carbpol.2009.01.016
Nada A, Al-Moghazy M, Soliman AAF, Rashwan GMT, Eldawy THA, Hassan AAE, Sayed GH (2018) Pyrazole-based compounds in chitosan liposomal emulsion for antimicrobial cotton fabrics. Int J Biol Macromol 107:585–594. https://doi.org/10.1016/j.ijbiomac.2017.09.031
Ocak B (2012) Complex coacervation of collagen hydrolysate extracted from leather solid wastes and chitosan for controlled release of lavender oil. J Environ Manag 100:22–28. https://doi.org/10.1016/j.jenvman.2012.01.026
Oliveira N, Cunha J (2019) Integrating technologies into fashion products: future challenges. In: Machado J, Soares F, Veiga G (eds) Innovation, engineering and entrepreneurship. HELIX 2018. Lecture notes in electrical engineering. Springer, Cham, pp 595–601. https://doi.org/10.1007/978-3-319-91334-6_81
Parisi OI, Scrivano L, Sinicropi MS, Puoci F (2017) Polymeric nanoparticle constructs as devices for antibacterial therapy. Curr Opin Pharmacol 36:72–77. https://doi.org/10.1016/j.coph.2017.08.004
Paulo BB, Andreola K, Taranto O, Ferreira AD, Prata AS (2018) Coating approach for a phase change material (PCM). Powder Technol. https://doi.org/10.1016/j.powtec.2018.03.003
Pedro AS, Cabral-Albuquerque E, Ferreira D, Sarmento B (2009) Chitosan: an option for development of essential oil delivery systems for oral cavity care? Carbohydr Polym 76:501–508. https://doi.org/10.1016/j.carbpol.2008.12.016
Peila R, Scordino P, Shanko DB, Caldera F, Trotta F, Ferri A (2017) Synthesis and characterization of β-cyclodextrin nanosponges for N,N-diethyl-meta-toluamide complexation and their application on polyester fabrics. React Funct Polym 119:87–94. https://doi.org/10.1016/j.reactfunctpolym.2017.08.008
Peng H, Xiong H, Li J, Chen L, Zhao Q (2010) Methoxy poly(ethylene glycol)-grafted-chitosan based microcapsules: synthesis, characterization and properties as a potential hydrophilic wall material for stabilization and controlled release of algal oil. J Food Eng 101:113–119. https://doi.org/10.1016/j.jfoodeng.2010.06.019
Perelshtein I, Ruderman E, Perkas N, Tzanov T, Beddow J, Joyce E et al (2013) Chitosan and chitosan–ZnO-based complex nanoparticles: formation, characterization, and antibacterial activity. J Mater Chem B 1:1968. https://doi.org/10.1039/c3tb00555k
Poncelet D, Dreffier C, Subra-Paternault P, Vandamme TF (2007) Introduction aux techniques de microencapsulation. In: Vandamme TF, Poncelet D, Subra-Paternault P (eds) Microencapsulation Des Sciences aux technologies. Éd. Tec & Doc, Paris, pp 1–7
Pothakamury UR, Barbosa-Cánovas GV (1995) Fundamental aspects of controlled release in foods. Trends Food Sci Technol 6:397–406. https://doi.org/10.1016/S0924-2244(00)89218-3
Prata AS, Grosso CRF (2015) Production of microparticles with gelatin and chitosan. Carbohydr Polym 116:292–299. https://doi.org/10.1016/j.carbpol.2014.03.056
Rajendran R, Radhai R, Balakumar C, Hasabo AMA, Vigneswaran C, Vaideki K (2012) Synthesis and characterization of neem chitosan nanocomposites for development of antimicrobial cotton textiles. J Eng Fiber Fabr 7:136–141
Ramadan MA, Samy S, Hebeish AA (2011) Chapter 1: eco-friendly pretreatment of cellulosic fabrics with chitosan and its influence on dyeing efficiency. In: Kumbasar EPA (ed) Natural dyes. IntechOpen, Rijeka, pp 3–12. https://doi.org/10.5772/20097
Rana V, Babita K, Goyal D, Tiwary A (2004) Sodium citrate cross-linked chitosan films: optimization as substitute for human/rat/rabbit epidermal sheets. J Pharm Pharm Sci 8:10–17
Ristić T, Zabret A, Zemljič LF, Peršin Z (2016) Chitosan nanoparticles as a potential drug delivery system attached to viscose cellulose fibers. Cellulose 24:739–753. https://doi.org/10.1007/s10570-016-1125-5
Rokhade AP, Shelke NB, Patil SA, Aminabhavi TM (2007) Novel interpenetrating polymer network microspheres of chitosan and methylcellulose for controlled release of theophylline. Carbohydr Polym 69:678–687. https://doi.org/10.1016/j.carbpol.2007.02.008
Roy JC, Salaün F, Giraud S, Ferri A, Guan J (2017) Chitosan-based sustainable textile technology: process, mechanism, innovation, and safety. In: Shalaby EA (ed) Biological activities and application of marine polysaccharides. InTech, London
Roy JC, Ferri A, Giraud S, Jinping G, Salaun F (2018a) Chitosan-carboxymethylcellulose-based polyelectrolyte complexation and microcapsule shell formulation. Int J Mol Sci 19. https://doi.org/10.3390/ijms19092521
Roy JC, Giraud S, Ferri A, Mossotti R, Guan J, Salaün F (2018b) Influence of process parameters on microcapsule formation from chitosan—type B gelatin complex coacervates. Carbohydr Polym 198:281–293. https://doi.org/10.1016/j.carbpol.2018.06.087
Rubio L, Alonso C, Coderch L, Parra JL, Martí M, Cebrián J et al (2010) Skin delivery of caffeine contained in biofunctional textiles. Text Res J 80:1214–1221. https://doi.org/10.1177/0040517509358798
Ruocco N, Costantini S, Guariniello S, Costantini M (2016) Polysaccharides from the marine environment with pharmacological, cosmeceutical and nutraceutical potential. Molecules 21. https://doi.org/10.3390/molecules21050551
Salaün F (2016) Chapter 6: microencapsulation technology for smart textile coatings. In: Hu J (ed) Active coatings for smart textiles. Woodhead Publishing, Doxford, pp 179–220. https://doi.org/10.1016/B978-0-08-100263-6.00009-5
Samimi Gharaie S, Habibi S, Nazockdast H (2018) Fabrication and characterization of chitosan/gelatin/thermoplastic polyurethane blend nanofibers. J Text Fibrous Mater 1:251522111876932. https://doi.org/10.1177/2515221118769324
Scacchetti FAP, Pinto E, Soares GMB (2018) Thermal and antimicrobial evaluation of cotton functionalized with a chitosan-zeolite composite and microcapsules of phase-change materials. J Appl Polym Sci 135:46135. https://doi.org/10.1002/app.46135
Shah T, Halacheva S (2016) Chapter 6: drug-releasing textiles. In: van Langenhove L (ed) Advances in smart medical textiles. Woodhead Publishing, Oxford, pp 119–154. https://doi.org/10.1016/B978-1-78242-379-9.00006-2
Sharkawy A, Fernandes IP, Barreiro MF, Rodrigues AE, Shoeib T (2017) Aroma-loaded microcapsules with antibacterial activity for eco-friendly textile application: synthesis, characterization, release, and green grafting. Ind Eng Chem Res 56:5516–5526. https://doi.org/10.1021/acs.iecr.7b00741
Souza JM, Caldas AL, Tohidi SD, Molina J, Souto AP, Fangueiro R, Zille A (2014a) Properties and controlled release of chitosan microencapsulated limonene oil. Braz J Pharmacog 24:691–698. https://doi.org/10.1016/j.bjp.2014.11.007
Souza JM, Caldas AL, Tohidi SD, Molina J, Souto AP, Fangueiro R, Zille A (2014b) Properties and controlled release of chitosan microencapsulated limonene oil. Rev Bras Farm 24:691–698. https://doi.org/10.1016/j.bjp.2014.11.007
Specos MMM, García JJ, Tornesello J, Marino P, Vecchia MD, Tesoriero MVD, Hermida LG (2010) Microencapsulated citronella oil for mosquito repellent finishing of cotton textiles. Trans R Soc Trop Med Hyg 104:653–658. https://doi.org/10.1016/j.trstmh.2010.06.004
Stegmaier T, Wunderlich W, Hager T, Siddique AB, Sarsour J, Planck H (2008) Chitosan – a sizing agent in fabric production – development and ecological evaluation. Clean 36:279–286. https://doi.org/10.1002/clen.200700013
Tian M, Tang X, Qu L, Zhu S, Guo X, Han G (2015) Robust ultraviolet blocking cotton fabric modified with chitosan/graphene nanocomposites. Mater Lett 145:340–343. https://doi.org/10.1016/j.matlet.2015.01.147
Tokatlı K, Demirdöven A (2018) Optimization of chitin and chitosan production from shrimp wastes and characterization. J Food Process Preserv 42:e13494. https://doi.org/10.1111/jfpp.13494
Varan NY (2017) The effects of chitosan antimicrobial treatments on the physical and mechanical properties and wear performances of highly elastic fabrics used for burn scar management. J Text I:1–7. https://doi.org/10.1080/00405000.2017.1322477
Verlee A, Mincke S, Stevens CV (2017) Recent developments in antibacterial and antifungal chitosan and its derivatives. Carbohydr Polym 164:268–283. https://doi.org/10.1016/j.carbpol.2017.02.001
Wang Z, Zheng L, Li C, Wu S, Xiao Y (2017) Preparation and antimicrobial activity of sulfopropyl chitosan in an ionic liquid aqueous solution. J Appl Polym Sci 134. https://doi.org/10.1002/app.44989
Wijesirigunawardana PB, Perera BG K (2018) Development of a cotton smart textile with medicinal properties using lime oil microcapsules. Acta Chim Slov 65:150–159. https://doi.org/10.17344/acsi.2017.3727
Yadav SK, Suresh AK, Khilar KC (1990) Microencapsulation in polyurea shell by interfacial polycondensation. AICHE J 36:431–438. https://doi.org/10.1002/aic.690360312
Yang Z, Song B, Li Q, Fan H, Ouyang F (2004) Effects of surfactant and acid type on preparation of chitosan microcapsules. China Particuol 2:70–75. https://doi.org/10.1016/S1672-2515(07)60026-8
Yang Z, Zeng Z, Xiao Z, Ji H (2014) Preparation and controllable release of chitosan/vanillin microcapsules and their application to cotton fabric. Flavour Fragr J 29:114–120. https://doi.org/10.1002/ffj.3186
Yang K, Jiao M, Wang S, Yu Y, Diao Q, Cao J (2018) Thermoregulation properties of composite phase change materials in high temperature environmental conditions. Int J Cloth Sci Tech 30:507–516. https://doi.org/10.1108/ijcst-11-2017-0173
Yao S, Swetha P, Zhu Y (2018) Nanomaterial-enabled wearable sensors for healthcare. Adv Healthc Mater 7:1700889. https://doi.org/10.1002/adhm.201700889
Yip J, Luk MYA (2016) Microencapsulation technologies for antimicrobial textiles. In: Sun G (ed) Antimicrobial textiles. Woodhead Publishing, Duxford, pp 19–46. https://doi.org/10.1016/b978-0-08-100576-7.00003-1
Yuan G, Cranston R (2008) Recent advances in antimicrobial treatments of textiles. Text Res J 78:60–72. https://doi.org/10.1177/0040517507082332
Yuen CW, Kan CW, Cheuk KL, Cheung HC, Cheng SY, Yip J, Lam PL (2012) Development of miconazole nitrate containing chitosan microcapsules and their anti-Aspergillus niger activity. J Microencapsul 29:505–510. https://doi.org/10.3109/02652048.2011.642017
Zemljič LF, Peršin Z, Šauperl O, Rudolf A, Kostić M (2017) Medical textiles based on viscose rayon fabrics coated with chitosan-encapsulated iodine: antibacterial and antioxidant properties. Text Res J 88:2519–2531. https://doi.org/10.1177/0040517517725117
Zhang Y, Wang X, Xu C, Yan W, Tian Q, Sun Z (2018) Fabrication of chitosan gel droplets via crosslinking of inverse Pickering emulsifications. Carbohydr Polym 186:1–8. https://doi.org/10.1016/j.carbpol.2017.12.062
Acknowledgments
The research work is supported by the European Union under the framework of Erasmus Mundus joint doctoral program entitled Sustainable Development and Design for Textile (Project SMDTex. 2015-41).
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2019 Springer Nature Switzerland AG
About this chapter
Cite this chapter
Massella, D., Giraud, S., Guan, J., Ferri, A., Salaün, F. (2019). Manufacture Techniques of Chitosan-Based Microcapsules to Enhance Functional Properties of Textiles. In: Crini, G., Lichtfouse, E. (eds) Sustainable Agriculture Reviews 35. Sustainable Agriculture Reviews, vol 35. Springer, Cham. https://doi.org/10.1007/978-3-030-16538-3_8
Download citation
DOI: https://doi.org/10.1007/978-3-030-16538-3_8
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-16537-6
Online ISBN: 978-3-030-16538-3
eBook Packages: Biomedical and Life SciencesBiomedical and Life Sciences (R0)