Abstract
We provide the rationale for possible significant improving efficiency of low-temperature thermoelectric generators (TEGs) based on bismuth-antimony telluride (Bi2Te3)x(Sb2Te3)1−x ternary alloys.
It has been shown by experiments that using in TEGs of p-type legs made of (Bi2Te3)x(Sb2Te3)1−x material with orientation alternative to traditional, i.e., when cleavage planes of legs are transverse to heat flux direction, results in increasing in thermoelectric efficiency by an average of 25% in the temperature range from 100 °C to 350 °C.
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References
K.H. Park, M. Mohamed, Z. Aksamija, U. Ravaioli, Phonon scattering due to van der Waals forces in the lattice thermal conductivity of Bi2Te3 thin films. J. Appl. Phys. 117, 015103 (2015). https://doi.org/10.1063/1.4905294
B.M. Goltsman, B.A. Kudinov, I.A. Smirnov, Thermoelectric semiconductor materials based on Bi2Te3 (Nauka, Moscow, 1972)
S.S. Sinani, G.N. Gordeeva, Bi2Te3—Bi2Se3 solid solutions as materials for thermoelements. Tech Phys (Sov.). 26, 2398–2399 (1956)
G.L. Shmelev, Materials for thermoelements based on three-component intermetallic alloys. Solid State Phys (Sov.). 1, 63–75 (1959)
L.D. Dudkin, N.K.H. Abrikosov, Physico-chemical investigations of cobalt antimony. J Inorg Chem (Sov.) 1, 2096–2101 (1956)
M.V. Kovalenko, B. Spokoyny, J.-S. Lee, M. Scheele, A. Weber, S. Perera, D. Landry, D.V. Talapin, Semiconductor nanocrystals functionalized with antimony telluride Zintl ions for nanostructured thermoelectrics. J. Am. Chem. Soc. 32, 6686–6695 (2010). https://doi.org/10.1021/ja909591x
M.V. Kovalenko, L. Manna, A. Cabot, Z. Hens, D.V. Talapin, C.R. Kagan, V.I. Klimov, A.I. Rogach, P. Reiss, D.J. Milliron, P. Guyot-Sionnnest, G. Konstantatos, W.J. Parak, T. Hyeon, B.A. Korgel, C.B. Murray, W. Heiss, Prospects of nanoscience with nanocrystals. ACS Nano 9, 1012–1057 (2015). https://doi.org/10.1021/nn506223h
S. Ortega, M. Ibáñez, Y. Liu, Y. Zhang, M.V. Kovalenko, D. Cadavid, A. Cabot, Bottom-up engineering of thermoelectric nanomaterials and devices from solution processed nanoparticle building blocks. Chem. Soc. Rev. 46, 3510–3528 (2017). https://doi.org/10.1039/c6cs00567e
M. Ibáñez, R. Hasler, Y. Liu, O. Dobrozhan, O. Nazarenko, D. Cadavid, A. Cabot, M.V. Kovalenko, Tuning p-type transport in bottom-up-engineered nanocrystalline Pb chalcogenides using alkali metal chalcogenides as capping ligands. ACS Chem Mater 29(17), 7093–7097 (2017). https://doi.org/10.1021/acs.chemmater.7b02967
L.D. Hicks, M.S. Dresselhaus, Effect of quantum-well structures on the thermoelectric figure of merit. Phys. Rev. B 47, 12727–12731 (1993)
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Dashevsky, Z., Skipidarov, S. (2019). Investigating the Performance of Bismuth-Antimony Telluride. In: Skipidarov, S., Nikitin, M. (eds) Novel Thermoelectric Materials and Device Design Concepts. Springer, Cham. https://doi.org/10.1007/978-3-030-12057-3_1
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