Abstract
Dyes are an important class of recalcitrant organic compounds, with a broad range of applications in the textiles and clothing industry. It is estimated that almost 2% of the dyes produced annually are discharged directly onto aqueous effluents through manufacturing and processing operations, and nearly 10% is subsequently lost during the coloration process. The presence of dyes in industrial wastewaters can create a host of environmental problems because of their potential cytotoxic, carcinogenic, and mutagenic effects on human health, as well as on general flora and fauna. Amongst the various physical, chemical, and biological techniques that are currently explored by the scientific community for the removal of dyes from aqueous medium, adsorption on activated carbon (AC) is widely considered as the most effective and promising option. However, commercially available ACs are fairly expensive and are often produced from non-renewable coal based resources, which make them economically undesirable and environmentally unsustainable. Consequently, there is a growing interest to synthesize ACs from renewable agricultural waste, which is conceived to be sufficiently abundant. Particularly, attributing to their high lignocellulosic composition and low ash content, date palm residues (such as fibers, seeds, rachis, fronds, etc.) as low cost precursors for manufacturing ACs are being intensively investigated in recent years. Compared to the commercial AC, the ACs derived from date palm byproducts exhibit superior textural characteristics, and, subsequently, greater adsorption capacity toward a plethora of dyes. Clearly, solicitations of date palm biomass, as a base feedstock for the mass production of AC, can not only solve the waste disposal crisis in date palm growing countries, with a beneficial and enhanced revenue potential, but may also contribute in regulation of the unsustainable management of the waste byproduct. This chapter targets this aspect amongst others, with an objective to provide a systematic overview of the recent progress in the development and application of date palm based ACs for decolorizing textile effluents. Furthermore, it attempts to segregate and identify the key gaps in the specific domain knowledge, and lays out novel strategic research guidelines, for making further advances in this promising approach, to a hitherto sustainable development.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Abdulkarim MA, Darwish NA, Magdy YM, Dwaidar A (2002) Adsorption of phenolic compounds and methylene blue onto activated carbon prepared from date fruit pits. Eng Life Sci 2:161–165. https://doi.org/10.1002/1618-2863(200206)2:6<161::AID-ELSC161>3.0.CO;2-2
Ahmad T, Danish M, Rafatullah M, Ghazali A, Sulaiman O, Hashim R, Ibrahim MNM (2012) The use of date palm as a potential adsorbent for wastewater treatment: a review. Environ Sci Pollut Res 19:1464–1484. https://doi.org/10.1007/s11356-011-0709-8
Ahmed MJ (2016) Preparation of activated carbons from date (Phoenix dactylifera L.) palm stones and application for wastewater treatments: review. Process Saf Environ Prot 102:168–182. https://doi.org/10.1016/j.psep.2016.03.010
Ahmed MJ, Dhedan SK (2012) Equilibrium isotherms and kinetics modeling of methylene blue adsorption on agricultural wastes-based activated carbons. Fluid Phase Equilib 317:9–14. https://doi.org/10.1016/j.fluid.2011.12.026
Ahmed MJ, Theydan SK (2012) Physical and chemical characteristics of activated carbon prepared by pyrolysis of chemically treated date stones and its ability to adsorb organics. Powder Technol 229:237–245. https://doi.org/10.1016/j.powtec.2012.06.043
Alhamed YA (2006) Activated carbon from dates’ stone by ZnCl2 activation. J King Abdulaziz Univ Eng Sci 17:75–100. https://doi.org/10.4197/Eng.17-2.4
Almi K, Lakel S, Benchabane A, Kriker A (2015) Characterization of date palm wood used as composites reinforcement. Acta Phys Pol A 127:1072–1074. https://doi.org/10.12693/APhysPolA.127.1072
Alrumman SA (2016) Enzymatic saccharification and fermentation of cellulosic date palm wastes to glucose and lactic acid. Braz J Microbiol 47:110–119. https://doi.org/10.1016/j.bjm.2015.11.015
Arevalo-Gallegos A, Ahmad Z, Asgher M, Parra-Saldivar R, Iqbal HMN (2017) Lignocellulose: a sustainable material to produce value-added products with a zero waste approach – a review. Int J Biol Macromol 99:308–318. https://doi.org/10.1016/j.ijbiomac.2017.02.097
Ashour SS (2010) Kinetic and equilibrium adsorption of methylene blue and remazol dyes onto steam-activated carbons developed from date pits. J Saudi Chem Soc 14:47–53. https://doi.org/10.1016/j.jscs.2009.12.008
Banat F, Al-Asheh S, Al-Makhadmeh L (2003a) Evaluation of the use of raw and activated date pits as potential adsorbents for dye containing waters. Process Chem 39:193–202. https://doi.org/10.1016/S0032-9592(03)00065-7
Banat F, Al-Asheh S, Al-Makhadmeh L (2003b) Preparation and examination of activated carbons from date pits impregnated with potassium hydroxide for the removal of methylene blue from aqueous solutions. Adsorp Sci Technol 21:597–606. https://doi.org/10.1260/026361703771953613
Bekheet SA, El-Sharabasy SF (2015) Date palm status and perspective in Egypt. In: Al-Khayri J, Jain S, Johnson D (eds) Date palm genetic resources and utilization. Springer, Dordrecht, pp 75–123. https://doi.org/10.1007/978-94-017-9694-1_3
Belhachemi M, Rios RVRA, Addoun F, Silvestre-Albero J, Sepúlveda-Escribano A, RodrÃguez-Reinoso F (2009) Preparation of activated carbon from date pits: effect of the activation agent and liquid phase oxidation. J Anal Appl Pyrolysis 86:168–172. https://doi.org/10.1016/j.jaap.2009.05.004
Chandrasekaran M, Bahkali AH (2013) Valorization of date palm (Phoenix dactylifera) fruit processing by-products and wastes using bioprocess technology – review. Saudi J Biol Sci 20:105–120. https://doi.org/10.1016/j.sjbs.2012.12.004
Chowdhury S, Saha P (2010) Sea shell powder as a new adsorbent to remove basic green 4 (malachite green) from aqueous solutions: equilibrium, kinetic and thermodynamic studies. Chem Eng J 164:168–177. https://doi.org/10.1016/j.cej.2010.08.050
Chowdhury S, Mishra R, Saha P, Kushwaha P (2011) Adsorption thermodynamics, kinetics and isosteric heat of adsorption of malachite green onto chemically modified rice husk. Desalination 265:159–168. https://doi.org/10.1016/j.desal.2010.07.047
Crini G (2006) Non-conventional low-cost adsorbents for dye removal: a review. Bioresour Technol 97:1061–1085. https://doi.org/10.1016/j.biortech.2005.05.001
Daoud M, Benturki O, Kecira Z, Girods P, Donnot A (2017) Removal of reactive dye (BEZAKTIV red S-MAX) from aqueous solution by adsorption onto activated carbons prepared from date palm rachis and jujube stones. J Mol Liq 243:799–809. https://doi.org/10.1016/j.molliq.2017.08.093
El May Y, Jeguirim M, Dorge S, Trouvé G, Said R (2012) Study on the thermal behavior of different date palm residues: characterization and devolatization kinetics under inert and oxidative atmospheres. Energy 44:702–709. https://doi.org/10.1016/j.energy.2012.05.022
Elmay Y, Trouvé G, Jeguirim M, Said R (2013) Energy recovery of date palm residues in a domestic pellet boiler. Fuel Process Technol 112:12–18. https://doi.org/10.1016/j.fuproc.2013.02.015
Elmay Y, Jeguirim M, Dorge S, Trouvé G, Said R (2014) Evaluation of date palm residues combustion in fixed bed laboratory reactor: a comparison with sawdust behaviour. Renew Energ 62:209–215. https://doi.org/10.1016/j.renene.2013.07.007
El-Shafey EI, Ali SNF, Al-Busafi S, Al-Lawati HAJ (2016) Preparation and characterization of surface functionalized activated carbons from date palm leaflets and application for methylene blue removal. J Environ Chem Eng 4:2713–2724. https://doi.org/10.1016/j.jece.2016.05.015
El-Sharkawy EA, Soliman AY, Al-Amer KM (2007) Comparative study for the removal of methylene blue via adsorption and photocatalytic degradation. J Colloid Interface Sci 310:498–508. https://doi.org/10.1016/j.jcis.2007.02.013
Foo KY, Hameed BH (2011) Preparation of activated carbon from date stones by microwave induced chemical activation: application for methylene blue adsorption. Chem Eng J 170:338–341. https://doi.org/10.1016/j.cej.2011.02.068
Gao Z, Zhang Y, Song N, Li X (2017) Biomass-derived renewable carbon materials for electrochemical energy storage. Mater Res Lett 5:69–88. https://doi.org/10.1080/21663831.2016.1250834
Gaspard S, Passé-Coutrin N, Durimel A, Cesaire T, Jeanne-Rose V (2014) Activated carbon from biomass for water treatment. In: Gaspard S, Ncibi MC (eds) Biomass for sustainable applications: pollution remediation and energy. RSC Publishing, London, pp 46–105. https://doi.org/10.1039/9781849737142-00046
Gonźalez JF, Román S, Gonźalez-GarcÃa CM, Valente Nabais JM, Ortiz AL (2009) Porosity development in activated carbons prepared from walnut shells by carbon dioxide or steam activation. Ind Eng Chem Res 48:7474–7481. https://doi.org/10.1021/ie801848x
Gupta VK, Carrott PJM, Ribeiro Carrott MML, Suhas (2009) Low-cost adsorbents: growing approach to wastewater treatment – a review. Crit Rev Environ Sci Technol 39:783–842. https://doi.org/10.1080/10643380801977610
Suhas, Gupta VK, Carrott PJM, Singh R, Chaudhary M, Kushwaha S (2016) Cellulose: a review as natural, modified and activated carbon adsorbent. Bioresour Technol 216:1066–1076. https://doi.org/10.1016/j.biortech.2016.05.106
Hsi H-C, Horng RS, Pan T-A, Lee S-K (2011) Preparation of activated carbons from raw and biotreated agricultural residues for removal of volatile organic compounds. J Air Waste Manag Assoc 61:543–551. https://doi.org/10.3155/1047-3289.61.5.543
Hussein FH, Halbus AF, Lafta AJ, Athab ZH (2015) Preparation and characterization of activated carbon from Iraqi Khestawy date palm. J Chem. https://doi.org/10.1155/2015/295748
Ioannidou O, Zabaniotou A (2007) Agricultural residues as precursors for activated carbon production – a review. Renew Sust Energ Rev 11:1966–2005. https://doi.org/10.1016/j.rser.2006.03.013
Islam M, Tan IAW, Benhouria A, Asif M, Hameed BH (2015) Mesoporous and adsorptive properties of palm date seed activated carbon prepared via sequential hydrothermal carbonization and sodium hydroxide activation. Chem Eng J 270:187–195. https://doi.org/10.1016/j.cej.2015.01.058
Jeppu GP, Clement TP (2012) A modified langmuir-freundlich isotherm model for simulating pH-dependent adsorption effects. J Contam Hydrol 129–130:46–53. https://doi.org/10.1016/j.jconhyd.2011.12.001
Kausar A, Iqbal M, Javed A, Aftab K, Nazli Z-i-H, Bhatti HN, Nouren S (2018) Dyes adsorption using clay and modified clay: a review. J Mol Liq 256:395–407. https://doi.org/10.1016/j.molliq.2018.02.034
Kodam KM, Kolekar YM (2015) Bacterial degradation of textile dyes. In: Singh SN (ed) Microbial degradation of synthetic dyes in wastewaters. Springer, Cham, pp 243–266. https://doi.org/10.1007/978-3-319-10942-8_11
Lattieff FA (2016) A study of biogas production from date palm fruit wastes. J Clean Prod 139:1191–1195. https://doi.org/10.1016/j.jclepro.2016.08.139
Mahmoudi K, Hosni K, Hamdi N, Srasra E (2015) Kinetics and equilibrium studies on removal of methylene blue and methyl orange by adsorption onto activated carbon prepared from date pits – a comparative study. Korean J Chem Eng 32:274–283. https://doi.org/10.1007/s11814-014-0216-y
Menya E, Olupot PW, Storz H, Lubwama M, Kiros Y (2018) Production and performance of activated carbon from rice husks for removal of natural organic matter from water: a review. Chem Eng Res Des 129:271–296. https://doi.org/10.1016/j.cherd.2017.11.008
Merdan N, Eyupoglu S, Duman MN (2017) Ecological and sustainable natural dyes. In: Muthu SS (ed) Textiles and clothing sustainability. Springer, Singapore, pp 1–42. https://doi.org/10.1007/978-981-10-2185-5_1
Shahid-ul-Islam, Mohammad F (2017) Anthraquinone-based natural colourants from insects. In: Muthu SS (ed) Textiles and clothing sustainability. Springer, Singapore, pp 81–98. https://doi.org/10.1007/978-981-10-2185-5_3
Nasser RA, Salem MZM, Hiziroglu S, Al-Mefarrej HA, Mohareb AS, Alam M, Aref IM (2016) Chemical analysis of different parts of date palm (Phoenix dactylifera L.) using ultimate, proximate and thermo-gravimetric techniques for energy production. Energies 9:374. https://doi.org/10.3390/en9050374
Pathania D, Gupta D, Al-Muhtaseb AH et al (2016a) Photocatalytic degradation of highly toxic dyes using chitosan-g-poly(acrylamide)/ZnS in presence of solar irradiation. J Photochem Photobiol A Chem 329:61–68. https://doi.org/10.1016/j.jphotochem.2016.06.019
Pathania D, Katwal R, Sharma G, Naushad M (2016b) Novel guar gum / Al2O3 nanocomposite as an effective photocatalyst for the degradation of malachite green dye. Int J Biol Macromol 87:366–374. https://doi.org/10.1016/j.ijbiomac.2016.02.073
Pereira L, Alves M (2012) Dyes – environmental impact and remediation. In: Malik A, Grohmann E (eds) Environmental protection strategies for sustainable development. Springer, Dordrecht, pp 111–162. https://doi.org/10.1007/978-94-007-1591-2_4
Rafatullah M, Ahmad T, Ghazali A, Sulaiman O, Danish M, Hashim R (2013) Oil palm biomass as a precursor of activated carbons: a review. Crit Rev Environ Sci Technol 43:1117–1161. https://doi.org/10.1080/10934529.2011.627039
Rashidi NA, Yusup S (2017) A review on recent technological advancement in the activated carbon production from oil palm wastes. Chem Eng J 314:277–290. https://doi.org/10.1016/j.cej.2016.11.059
Reddy KSK, Al Shoaibi A, Srinivasakannan C (2012) A comparison of microstructure and adsorption characteristics of activated carbons by CO2 and H3PO4 activation from date palm pits. New Carbon Mater 27:344–351. https://doi.org/10.1016/S1872-5805(12)60020-1
Sevilla M, Mokaya R (2014) Energy storage applications of activated carbons: supercapacitors and hydrogen storage. Energy Environ Sci 7:1250–1280. https://doi.org/10.1039/C3EE43525C
Sharma G, Naushad M, Pathania D et al (2015) Modification of Hibiscus cannabinus fiber by graft copolymerization: application for dye removal. Desalin Water Treat 54:3114–3121. https://doi.org/10.1080/19443994.2014.904822
Singh K, Arora S (2011) Removal of synthetic textile dyes from wastewaters: a critical review on present treatment technologies. Crit Rev Environ Sci Technol 41:807–878. https://doi.org/10.1080/10643380903218376
Singh SN, Mishra S, Jauhari N (2015) Degradation of anthraquinone dyes stimulated by fungi. In: Singh SN (ed) Microbial degradation of synthetic dyes in wastewaters. Springer, Cham, pp 333–356. https://doi.org/10.1007/978-3-319-10942-8_15
Theydan SK, Ahmed MJ (2012) Adsorption of methylene blue onto biomass-based activated carbon by FeCl3 activation: equilibrium, kinetics, and thermodynamic studies. J Anal Appl Pyrolysis 97:116–122. https://doi.org/10.1016/j.jaap.2012.05.008
Usman ARA, Abduljabbar A, Vithanage M, Ok YS, Ahmad M, Ahmad M, Elfaki J, Abdulazeem SS, Al-Wabel MI (2015) Biochar production from date palm waste: charring temperature induced changes in composition and surface chemistry. J Anal Appl Pyrolysis 115:392–400. https://doi.org/10.1016/j.jaap.2015.08.016
Yaqub MT, Sen TK, Afroze S, Ang HM (2014) Dye and its removal from aqueous solution by adsorption: a review. Adv Colloid Interf Sci 209:172–184. https://doi.org/10.1016/j.cis.2014.04.002
Yuen FK, Hameed BH (2009) Recent developments in the preparation and regeneration of activated carbons by microwaves. Adv Colloid Interf Sci 149:19–27. https://doi.org/10.1016/j.cis.2008.12.005
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2019 Springer Nature Switzerland AG
About this chapter
Cite this chapter
Chowdhury, S., Pan, S., Balasubramanian, R., Das, P. (2019). Date Palm Based Activated Carbon for the Efficient Removal of Organic Dyes from Aqueous Environment. In: Naushad, M., Lichtfouse, E. (eds) Sustainable Agriculture Reviews 34. Sustainable Agriculture Reviews, vol 34. Springer, Cham. https://doi.org/10.1007/978-3-030-11345-2_12
Download citation
DOI: https://doi.org/10.1007/978-3-030-11345-2_12
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-11344-5
Online ISBN: 978-3-030-11345-2
eBook Packages: Biomedical and Life SciencesBiomedical and Life Sciences (R0)