Abstract
The natural nanoparticles of CaCO3, from eggshell and CaCO3/Ag, were investigated as candidates for biocide nanoparticles in a blend of thermoplastic elastomer, styrene–ethylene/butadiene–styrene (SEBS), and polyolefin, high-melt-strength polypropylene (HMSPP). The nanoparticles with silver (Ag) were synthesized by metal precursor method, and before the application in the polymer matrix, the nanoparticles were analyzed on dynamic lighting scattering (DLS) and Raman spectroscopy. After DLS and Raman analyses, the nanoparticles were evaluated in biocide tests against P. aeruginosa and S. auerus. The aim of this investigation was the blending and the injection molding in dumbbell samples with the nanoparticles. The characterizations were carried out by differential scanning calorimetry (DSC), thermogravimetry analysis, mechanical tests, X-ray diffraction, Raman spectroscopy, scanning electron microscopy, and energy-dispersive scanning and biocide tests. Correlation between size and particle distribution on the polymer was founded. However, samples at higher concentrations (>1 wt%) do not show biocide activity.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Narayanan KB, Suresh AK, Sakthivel N (2015) Metallic nanocomposites: bacterial-based ecologically benign biofabrication and optimization studies. In: Eco-friendly polymer nanocomposites. Advanced Structure Materials. Springer, India, pp 215–231
Tiimob BJ, Jeelani S, Rangari VK (2016) Eggshell reinforced biocomposite—an advanced “green” alternative structural material. J Appl Polym Sci. https://doi.org/10.1002/app.43124
Nomiya K, Kasuga NC, Takayama A (2014) Synthesis, structure and antimicrobial activities of polymeric and nonpolymeric silver and other metel complexes. In: Polymeric materials with antimicrobial activity: form synthesis to applications. RSC Polymer Chemistry Series, pp 156–207
Guzmán MG, Dille J, Godet S (2009) Synthesis of silver nanoparticles by chemical reduction method and their antibacterial activity. Int J Chem Bio Eng, 104–111
Le AT, Tam LT, Tam PD, Huy PT, Huy TQ, Hieu NV, Cotolan N, Rak M, Bele M, Cör A, Muresan LM, Milosev I (2016) Sol-gel synthesis, characterization and properties of TiO2 and Ag-TiO2 coatings on titanium substrate. Surf Coat Technol, 790–799
Kudrinskiy AA, Krutyakov YA (2010) Synthesis of oleic acid-stabilized silver nanoparticles and analysis of their antibacterial activity. Mater Sci Eng C, 910–916
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2019 The Minerals, Metals & Materials Society
About this paper
Cite this paper
Komatsu, L.G.H., Zafalon, A.T., Santos, V.J., Lincopan, N., Rangari, V.K., Parra, D.F. (2019). Application of Natural Nanoparticles in Polymeric Blend of HMSPP/SEBS for Biocide Activity. In: Ikhmayies, S., Li, J., Vieira, C., Margem (Deceased), J., de Oliveira Braga, F. (eds) Green Materials Engineering. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-10383-5_9
Download citation
DOI: https://doi.org/10.1007/978-3-030-10383-5_9
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-10382-8
Online ISBN: 978-3-030-10383-5
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)