Skip to main content

The Separation of Refined Silicon by Gas Pressure Filtration in Solvent Refining Process

  • Conference paper
  • First Online:
Energy Technology 2019

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

  • 1432 Accesses

Abstract

The separation of refined silicon by gas pressure filtration combined with solvent refining was studied. The purified silicon grains were separated by gas pressure filtration under a pressure differential of 0.2 MPa. In all of the systems, Al–40%Si, Sn–40%Si, Cu–40%Si, and Fe–80%Si, the effect of separation temperature (T) on separation efficiency was evaluated. In Al–40%Si alloy, the silicon content in separated silicon was 91.3 wt% and the recovery rate of silicon was 97.6%, at T = 600 °C. In Sn–40%Si alloy, almost all of the silicon was retained, and the silicon content in separated silicon was 79.4 wt% at T = 600 °C. For Cu–40%Si alloy and Fe–80%Si alloy, the silicon content in separated silicon was over 75 wt% under high superheat. With efficient removal of impurities, the combination of gas pressure filtration and solvent refining is a promising method.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Pizzini S (2010) Towards solar grade silicon: challenges and benefits for low cost photovoltaics. Sol Energy Mater Sol Cells 94(9):1528–1533

    Article  CAS  Google Scholar 

  2. Mitrašinović AM, Utigard TA (2009) Refining silicon for solar cell application by copper alloying. Silicon 1:239–488

    Article  Google Scholar 

  3. Hu L, Wang Z, Gong XZ, Guo ZC, Zhang H (2013) Impurities removal from metallurgical-grade silicon by combined Sn-Si and Al-Si refining processes. Metall Mater Trans B 44:828–836

    Article  CAS  Google Scholar 

  4. Li JW, Guo ZC, Tang HQ, Wang Z, Sun ST (2012) Si purification by solidification of Al-Si melt with super gravity. Trans Nonferrous Met Soc China 22:958–963

    Article  CAS  Google Scholar 

  5. Ma X, Zheng L, Zhang H, Zhao B, Wang C, Xu F (2011) Thermal system design and optimization of an industrial silicon directional solidification system. J Cryst Growth 318(1):288–292

    Article  CAS  Google Scholar 

  6. Martorano MA, Ferreira Neto JB, Oliveira TS, Tsubaki TO (2011) Refining of metallurgical silicon by directional solidification. Mater Sci Eng, B 176(3):217–226

    Article  CAS  Google Scholar 

  7. Krystad E, Tang K, Tranell G (2012) The kinetics of boron transfer in slag refining of silicon. JOM 64(8):968–972

    Article  CAS  Google Scholar 

  8. Wu J, Li Y, Wei K, Bin Y, Dai Y (2014) Boron removal in purifying metallurgical grade silicon by CaO-SiO2 slag refining. Trans Nonferrous Met Soc China 24(4):1231–1236

    Article  CAS  Google Scholar 

  9. Nakamura N, Baba H, Sakaguchi Y, Kato Y (2004) Born removal in molten silicon by a steam-added plasma melting method. Mater Trans 45:858–864

    Article  CAS  Google Scholar 

  10. Zheng SS, Chen WH, Cai J, Li JT, Chen C, Luo XT (2010) Mass Transfer of phosphorus in silicon melts under vacuum induction refining. Metall Mater Trans B 41:1268–1273

    Article  CAS  Google Scholar 

  11. Lee W, Kim J, Jang B, Ahn Y, Lee H, Yoon W (2011) Metal impurities behaviors of silicon in the fractional melting process. Sol Energy Mater Sol Cells 95:59–62

    Article  CAS  Google Scholar 

  12. Gu X, Yu X, Yang DR (2011) Low-cost solar grade silicon purification process with Al–Si system using a powder metallurgy technique. Sep Purif Technol 77:33–39

    Article  CAS  Google Scholar 

  13. Li JW, Guo ZC, Tang HQ, Li JC (2013) Removal of impurities from metallurgical grade silicon by liquation refining method. High Temp Mater Processes 32:503–510

    CAS  Google Scholar 

  14. Zhao LX, Wang Z, Guo ZC, Li CY (2011) Low-temperature purification process of metallurgical silicon. Trans Nonferrous Met Soc China 21:1185–1192

    Article  CAS  Google Scholar 

  15. Esfahani S, Barati M (2011) Purification of metallurgical silicon using iron as an impurity getter, part I: growth and separation of Si. Met Mater Int 17(5):823–829

    Article  CAS  Google Scholar 

  16. Esfahani S, Barati M (2011) Purification of metallurgical silicon using iron as impurity getter, part II: extent of silicon purification. Met Mater Int 17(6):1009–1015

    Article  CAS  Google Scholar 

  17. Juneja JM, Mukherjee TK (1986) A study of the purification of metallurgical grade silicon. Hydrometallurgy 16(1):69–75

    Article  CAS  Google Scholar 

  18. Gumaste JL, Mohanty BC, Galgali RK, Syamaprasad U, Nayak BB, Singh SK, Jena PK (1987) Solvent refining of metallurgical grade silicon. Sol Energy Mater 16(4):289–296

    Article  CAS  Google Scholar 

  19. Yoshikawa T, Morita K (2005) Cutting edge of electromagnetic processing for materials: refining of Si by the solidification of Si–Al melt with electromagnetic force. ISIJ Int 45(7):967–971

    Article  CAS  Google Scholar 

  20. Ma X, Yoshikawa T, Morita K (2013) Si growth by directional solidification of Si–Sn alloys to produce solar-grade Si. J Cryst Growth 377:192–196

    Article  CAS  Google Scholar 

  21. Li JW, Guo ZC, Li JC, Yu LZ (2015) Super gravity separation of purified Si from solvent refining with the Al-Si alloy system for solar grade silicon. Silicon 7:239–246

    Article  CAS  Google Scholar 

  22. Li J, Liu Y, Tan Y, Li Y, Zhang L, Wu S, Jia P (2013) Effect of tin addition on primary silicon recovery in Si–Al melt during solidification refining of silicon. J Cryst Growth 371:1–6

    Article  CAS  Google Scholar 

  23. Okamoto H (2012) Cu-Si (Copper-Silicon). J Phase Equilib Diff 33:415–416

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundations of China (Grant No.51804030) and the Key Projects of the State Key Research and Development Plan of China (2016YFB0601304).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Zhancheng Guo .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2019 The Minerals, Metals & Materials Society

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Li, T., Guo, L., Wang, Z., Guo, Z. (2019). The Separation of Refined Silicon by Gas Pressure Filtration in Solvent Refining Process. In: Wang, T., et al. Energy Technology 2019. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-06209-5_25

Download citation

Publish with us

Policies and ethics