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Chromatographic Reactive Separations

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Applications of Ion Exchange Materials in Chemical and Food Industries

Abstract

Ion-exchange resins (IERs) possess the capability of catalyzing several classes of reactions, apart from their ability to make separations. In fact, it is possible to synthesize tailor-made IERs for the reactive processes at hand. Use of IERs can fetch a number of advantages compared to those of homogeneous catalysts and other solid catalysts. Reactive separation (RS) is a relatively new process technology that has the potential to offer several advantages over the conventional approach of reaction followed by separation. Various separation steps can be coupled with the reaction, including: distillation, extraction, chromatography, crystallization and separation by membranes. This chapter reviews the salient features and industrial applications of reactive separations using IERs.

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Abbreviations

A-15:

Amberlyst 15

AEM:

Anion-exchange membrane

CD:

Catalytic distillation

CEM:

Cation-exchange membrane

CSTR:

Continuous stirred tank reactor

FBCR:

Fixed bed chromatographic reactor

GCE:

Green chemistry and engineering

IER:

Ion-exchange resin

LAB sulphonate:

Linear alkyl-benzene sulfonate

LPG:

Liquefied petroleum gas

PI:

Process intensification

RA:

Reactive absorption

RC:

Reactive chromatography

RCond:

Reactive condensation

RCr:

Reactive crystallization

RD:

Reactive distillation

RM:

Reactive membrane

RPr:

Reactive precipitation

RS:

Reactive separation

RStr:

Reactive stripping

SCMCR:

Simulated counter current moving bed chromatographic reactor

SMBR:

Simulated moving-bed reactor

UO:

Unit operations

UP:

Unit processes

VLE:

Vapor–liquid equilibrium

VLLE:

Vapor–liquid–liquid equilibrium

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Authors and Affiliations

  1. Chemical Engineering Department, Dr. Babasaheb Ambedkar Technological University, Lonere, Mangaon, Raigad, 402103, Maharashtra, India

    Akash V. Shetty & Yogesh S. Mahajan

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  1. Akash V. Shetty
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  2. Yogesh S. Mahajan
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Correspondence to Yogesh S. Mahajan .

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  1. Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia

    Inamuddin

  2. Department of Chemistry, National Institute of Technology Srinagar, Srinagar, India

    Tauseef Ahmad Rangreez

  3. Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia

    Abdullah M. Asiri

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Shetty, A.V., Mahajan, Y.S. (2019). Chromatographic Reactive Separations. In: Inamuddin, Rangreez, T., M. Asiri, A. (eds) Applications of Ion Exchange Materials in Chemical and Food Industries. Springer, Cham. https://doi.org/10.1007/978-3-030-06085-5_7

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