Effects of Electrolytic Parameters on the Preparation of Al–Sc Master Alloy in Na3AlF6-K3AlF6-AlF3 Melt

  • Kai Yang
  • Zhongliang TianEmail author
  • Xun Hu
  • Yanqing Lai
  • Jie Li
Conference paper
Part of the The Minerals, Metals & Materials Series book series (MMMS)


The effects of electrolytic parameters on the content of Sc in Al–Sc master alloy prepared by electrolysis in Na3AlF6-K3AlF6-AlF3 melt were studied. It is observed that the content of Sc in Al–Sc master alloy increases and then decreases with increasing the electrolysis temperature and the cathodic current density. Under the electrolysis condition (temperature 950 °C, cathodic current density 1.50 A cm−2 and concentration of Al2O3 1.0 wt%), the content of Sc in the production is increased from 0.81 to 3.87 wt% as the value of the concentration ratio of Sc2O3 to Al2O3 ([Sc2O3]/[Al2O3]) increased from 2 to 6. The analysis of SEM indicates that the production of Al–Sc master alloy is composed of the aluminum and the Al3Sc. The distribution of Sc in Al–Sc master alloy is uniform.


Al–Sc master alloy Electrolytic parameters Na3AlF6-K3AlF6-AlF3 melt Electrolysis 



The authors gratefully acknowledge the financial support from the State Natural Science Fund (No. 51674301).


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© The Minerals, Metals & Materials Society 2019

Authors and Affiliations

  • Kai Yang
    • 1
  • Zhongliang Tian
    • 1
    Email author
  • Xun Hu
    • 1
  • Yanqing Lai
    • 1
  • Jie Li
    • 1
  1. 1.School of Metallurgy and EnvironmentCentral South UniversityChangshaChina

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