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Preparing Alumina by an Electrolytic Method from Sulfuric Acid Leachate of Coal Fly Ash

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Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

Abstract

Coal fly ash (CFA) is a solid waste from burning coal in power plants and has caused serious environmental problems. From this study, a three-staged process: sulphating-roasting, leaching and electrolysis, to produce alumina from coal fly ash in an environmentally-friendly manner is proposed. In this work, the key process of electrolysis was investigated in detail, batch experiments were performed to evaluate the potential effects of important parameters such as electrode distance. The electrolytic products were analyzed by XRD , XRF , SEM and Particle size distribution (PSD). The results showed that the electrolysis products were Al (OH)3 which can be used for aluminum reduction . Moreover, the electrolysis mechanisms in sulfuric acid leachate are also discussed.

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References

  1. Wang BD, Zhou YX, Li L, Wang Y (2018) Preparation of amidoxime-functionalized mesoporous silica nanospheres (ami-MSN) from coal fly ash for the removal of U(VI). Sci. Total Environ. 626: 219–227.

    Google Scholar 

  2. Liu J, Dong Y, Dong X, Hampshire S, Zhu L, Zhu Z, Li L (2016) Feasible recycling of industrial waste coal fly ash for preparation of anorthite-cordierite based porous ceramic membrane supports with addition of dolomite. J. Eur. Ceram. Soc. 36: 1059–1071.

    Google Scholar 

  3. Li C, Li Y, Sun H, Li L (2011) The Composition of fly ash glass phase and its dissolution properties applying to geopolymeric materials. J. Am. Ceram. Soc. 94: 1773–1778.

    Google Scholar 

  4. Lv JF, Yang HY, Jin ZN, Zhao ML (2018) Lead extraction and glass-ceramics synthesis from waste cathode ray tube funnel glass through cooperative smelting process with coal fly ash. Waste Manage. Res. 76: 687–696.

    Google Scholar 

  5. Asl SMH, Arezou G, Mazyar SB, Hamedreza J, Mehdi M, Hossein K (2018) Porous catalysts fabricated from coal fly ash as cost-effective alternatives for industrial applications: A review. Fuel. 217: 320–342.

    Google Scholar 

  6. Liu T, Tang Y, Han L, Song J, Luo Z, Lu A (2017) Recycling of harmful waste leadzinc mine tailing and fly ash for preparation of inorganic porous ceramics. Ceram. Int. 43: 4910–4918.

    Google Scholar 

  7. Hirajima T, Petrus HTB., Oosako Y., Nonaka M, Sasaki K, Ando T (2010) Recovery of cenospheres from coal fly ash using a dry separation process: separation estimation and potential application. Int. J. Miner. Process. 95: 18–24.

    Google Scholar 

  8. Wang J, Li X, Bai Z, Huang L (2017) The effects of coal gangue and fly ash on the hydraulic properties and water content distribution in reconstructed soil profiles of coal‐mined land with a high groundwater table. Hydrol. Process. 31: 687–697.

    Google Scholar 

  9. Dai S, Li D, Chou CL, Zhao L, Zhang Y, Ren D, Ma Y, Sun Y (2008) Mineralogy and geochemistry of boehmite-rich coals: new insights from the Haerwusu Surface Mine, Jungar Coalfield, Inner Mongolia, China. Int. J. Coal Geol. 74: 185–202.

    Google Scholar 

  10. Dai S, Zou J, Jiang Y, Ward CR., Wang X, Li T, Xue W, Liu S, Tian H, Sun X, Zhou D (2012) Mineralogical and geochemical compositions of the Pennsylvanian coal in the Adaohai mine, Daqingshan coalfield, Inner Mongolia, China: modes of occurrence and origin of diaspore, gorceixite, and ammonian illite. Int. J. Coal Geol. 94: 250–270.

    Google Scholar 

  11. Han GH, Yang SZ, Peng WJ, Huang YF, Wu HY, Chai WC, Liu JT (2018) Enhanced recycling and utilization of mullite from coal fly ash with a flotation and metallurgy process. J. Clean. Prod. 178: 804–813.

    Google Scholar 

  12. Bojinova D, Teodosieva R (2016) Leaching of valuable elements from thermal power plant bottom ash using a thermo-hydrometallurgical process. Waste Manag. Res. 34: 511–517.

    Google Scholar 

  13. Immanuel V, Shukla A (2012) Effect of operating variables on performance of membrane electrolysis cell for carrying out Bunsen reaction of I-S cycle. Int J Hydrogen Energy. 37.

    Google Scholar 

  14. Kumar M, Shetti NP (2018) Magnetron sputter deposited NiCu alloy catalysts for production of hydrogen through electrolysis in alkaline water Materials. Science for Energy Technologies.

    Google Scholar 

  15. Li QF, Chen YJ, Harris VG (2018) Particle-size distribution modified effective medium theory and validation by magneto-dielectric Co-Ti substituted BaM ferrite composites. J. Magn. Magn. Mater. 453: 44–47.

    Google Scholar 

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Correspondence to Ting-an Zhang .

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Shi, Y., Jiang, Kx., Zhang, Ta., Lv, Gz. (2019). Preparing Alumina by an Electrolytic Method from Sulfuric Acid Leachate of Coal Fly Ash. In: Chesonis, C. (eds) Light Metals 2019. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-05864-7_7

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