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Influence of Amine Additives on the Electrodeposition of Aluminum from AlCl3-Dimethyl Sulfone Electrolytes

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Light Metals 2019

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

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Abstract

Coating of Al on various materials contributes to increase the widespread use of Al and Al coated materials in various industrial applications. There are several methods applied for Al coating such as hot dipping, thermal spray, chemical vapor deposition, physical vapor deposition and electroplating. Low-temperature electroplating process is the most economical method. In this research, AlCl3/dimethyl sulfone has been proposed for electroplating at low temperature. Furthermore, the effect of amine additives on the thickness, stability and the purity of the deposited film were investigated. These amine group additives bring the change in the surface morphology and crystal orientation of the Al film. Preferential adsorption of amine groups on the surface of the aluminum film lead to reduction of Cl and S and consequently decrease the cracks from aluminum film surface.

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Author information

Authors and Affiliations

  1. Department of Mining, Metallurgy and Petroleum Engineering, School of Engineering, Al-Azhar University, Nasr City, Cairo, 11371, Egypt

    S. A. Salman

  2. Department of Materials Science and Engineering, Graduate School of Engineering, Nagoya University, Nagoya, 464-8603, Japan

    S. A. Salman & Sangjae Kim

  3. Institute of Materials and Systems for Sustainability, IMaSS, Nagoya University, Nagoya, 464-8603, Japan

    Kensuke Kuroda & Masazumi Okido

Authors
  1. S. A. Salman
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  2. Sangjae Kim
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  3. Kensuke Kuroda
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  4. Masazumi Okido
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Corresponding author

Correspondence to S. A. Salman .

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Editors and Affiliations

  1. Metal Quality Solutions, LLC, Avonmore, PA, USA

    Corleen Chesonis

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© 2019 The Minerals, Metals & Materials Society

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Salman, S.A., Kim, S., Kuroda, K., Okido, M. (2019). Influence of Amine Additives on the Electrodeposition of Aluminum from AlCl3-Dimethyl Sulfone Electrolytes. In: Chesonis, C. (eds) Light Metals 2019. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-05864-7_16

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