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The Influence of Microstructure and Emissivity of NiO-Doped Fe3O4 Spinel Structure on Near- and Middle-Infrared Radiation

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Characterization of Minerals, Metals, and Materials 2019

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

Abstract

The ferrites of spinel structure have high-infrared emissivity performance at high temperature, which make it possible to be used in metallurgical industry. Based on the preparation of the materials, microstructure and ions distribution of spinel structure Fe3O4 with Ni-ion doping was investigated. Further, the emissivity was measured as 0.97 in the 3–5 μm waveband at 500 °C, which presented excellent radiation performance. The first-principle calculation was conducted to explain the mechanism of emissivity variation with Ni-ion doping . The calculation results show that Ni doping makes the forbidden band increase, leading to a decrease of free carrier absorption in NiFe2O4 system, and this indicates that the Ni2+ doping would enhance the energy of electron transition from valence band to conduction band which is formed due to the hybridization of the 3d orbital electrons of the Ni ions and the 2p orbital electrons of the oxygen atoms.

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Authors and Affiliations

  1. School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, 30# Xueyuan Road, Beijing, 100083, China

    Jian Zhang, Bai Hao, Xu Zhang, Huanmei Yuan, Zefei Zhang & Liyun Yang

Authors
  1. Jian Zhang
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  2. Bai Hao
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  3. Xu Zhang
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  4. Huanmei Yuan
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  5. Zefei Zhang
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  6. Liyun Yang
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Corresponding author

Correspondence to Bai Hao .

Editor information

Editors and Affiliations

  1. Michigan Technological University, Houghton, MI, USA

    Bowen Li

  2. CanmetMATERIALS, Hamilton, ON, Canada

    Jian Li

  3. Al-Isra University, Amman, Jordan

    Shadia Ikhmayies

  4. ArcelorMittal Global R&D, East Chicago, IN, USA

    Mingming Zhang

  5. Middle East Technical University, Ankara, Turkey

    Yunus Eren Kalay

  6. Los Alamos National Laboratory, Los Alamos, NM, USA

    John S. Carpenter

  7. Michigan Technological University, Houghton, MI, USA

    Jiann-Yang Hwang

  8. Military Institute of Engineering, Rio de Janeiro, Brazil

    Sergio Neves Monteiro

  9. Chongqing University, Chongqing, China

    Chenguang Bai

  10. UNSW Canberra, Campbell, ACT, Australia

    Juan P. Escobedo-Diaz

  11. Free University of Bozen-Bolzano, Bolzano, Italy

    Pasquale Russo Spena

  12. Naval Research Laboratory, Washington, DC, USA

    Ramasis Goswami

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Zhang, J., Hao, B., Zhang, X., Yuan, H., Zhang, Z., Yang, L. (2019). The Influence of Microstructure and Emissivity of NiO-Doped Fe3O4 Spinel Structure on Near- and Middle-Infrared Radiation. In: Li, B., et al. Characterization of Minerals, Metals, and Materials 2019. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-05749-7_8

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