Characterization of Modified Nickel Silicate Anode Material for LithiumIon Batteries

  • Yunyun Wei
  • Guihong Han
  • Yanfang HuangEmail author
  • Duo Zhang
Conference paper
Part of the The Minerals, Metals & Materials Series book series (MMMS)


Ni2SiO4, as a new anode material for lithium–ion batteries, was prepared by the high-temperature calcination method in this work. The MgO-coated NSO was prepared by melt injection method. Electrochemical properties, including voltammogram (CV), electrochemical impedance spectroscopy (EIS), charge/discharge curves and cycle performance were tested. The structure and morphology of materials were further characterized by XRD and SEM. The results demonstrated that the MgO-coated Ni2SiO4 materials exhibited higher cycle charge capacity and coulombic efficiency than that of Ni2SiO4. When the MgO coating amount is 1%, the first cycle charge capacity and coulombic efficiency were 584.2 mAh/g and 66.25%, respectively. After 50 cycles, the charge capacity was still maintained at 359.7 mAh/g when the current density was 100 mAh/g, which was 162.7 mAh/g higher than the NSO. The crystal structure of the materials belongs to an orthorhombic system, and the morphological structure presented cubic particles. Therefore, the NSO anode material has a better cycle stability and high capacity when the MgO coating amount is 1%.


MgO-coated Ni2SiO4 Electrochemical properties Anode material Lithium–ion batteries 



The authors acknowledge the financial support provided by the National Science Fund of China (No. 51674225, No. 51774252), the Innovative Talents Foundation in Universities in Henan Province (No. 18HASTIT011), the Educational Commission of Henan Province of China (No. 17A450001, 18A450001), and the China Postdoctoral Science Foundation (No. 2017M622375).


  1. 1.
    Zhang WM, Hu JS, Guo YG, Zheng SF, Zhong LS, Song WG, Wan LJ (2010) Tin-nanoparticles encapsulated in elastic hollow carbon spheres for high-performance anode material in lithium-ion batteries. Adv Mater 20:1160–1165CrossRefGoogle Scholar
  2. 2.
    Jung HG, Jang MW, Hassoun J, Sun YK, Scrosati B (2011) A high-rate long-life Li4Ti5O12/Li[Ni0.45Co0.1Mn1.45]O4 lithium-ion battery. Nat Commun 2:516CrossRefGoogle Scholar
  3. 3.
    Etacheri V, Marom R, Ran E, Salitra G, Aurbach D (2011) Challenges in the development of advanced Li-ion batteries: a review. Energy Environ Sci 4:3243–3262CrossRefGoogle Scholar
  4. 4.
    Tarascon JM, Armand M (2001) Issues and challenges facing rechargeable lithium batteries. Nature 414:359–367CrossRefGoogle Scholar
  5. 5.
    Sun Y, Zhao L, Pan H, Lu X, Gu L, Hu YS, Li H, Armand M, Ikuhara Y, Chen L (2013) Direct atomic-scale confirmation of three-phase storage mechanism in Li4Ti5O12 anodes for room-temperature sodium-ion batteries. Nat Commun 4:1870CrossRefGoogle Scholar
  6. 6.
    Aricò AS, Bruce P, Scrosati B, Tarascon JM, Schalkwijk WV (2005) Nanostructured materials for advanced energy conversion and storage devices. Nat Mater 4:366–377CrossRefGoogle Scholar
  7. 7.
    Zhang F, An Y, Zhai W, Gao X, Feng J, Ci L, Xiong S (2015) Nanotubes within transition metal silicate hollow spheres: facile preparation and superior lithium storage performances. Mater Res Bull 70:573–578CrossRefGoogle Scholar
  8. 8.
    Yang S, Huang Y, Han G, Liu J, Cao Y (2017) Synthesis and electrochemical performance of double shell SnO2@amorphous TiO2 spheres for lithium ion battery application. Powder Technol 322Google Scholar
  9. 9.
    Quinzeni I, Ferrari S, Quartarone E, Capsoni D, Caputo M, Goldoni A, Mustarelli P, Bini M (2014) Fabrication and electrochemical characterization of amorphous lithium iron silicate thin films as positive electrodes for lithium batteries. J Power Sources 266:179–185CrossRefGoogle Scholar
  10. 10.
    Tao P, Shao M, Song C, Li C, Yin Y, Wu S, Cheng M, Cui Z (2015) Morphologically controlled synthesis of porous Mn2O3 microspheres and their catalytic applications on the degradation of methylene blue. Desalin Water Treat 57:1–6Google Scholar
  11. 11.
    Kiener J, Tosheva L, Parmentier J (2017) Carbide, nitride and sulfide transition metal-based macrospheres. J Eur Ceram Soc 37:1127–1130CrossRefGoogle Scholar
  12. 12.
    Hassoun J, Panero S, Reale P, Scrosati B (2009) A new, safe, high-rate and high-energy polymer lithium-ion battery. Adv Mater 21:4807–4810CrossRefGoogle Scholar
  13. 13.
    Mysen B (2007) Partitioning of calcium, magnesium, and transition metals between olivine and melt governed by the structure of the silicate melt at ambient pressure. Am Miner 92:844–862CrossRefGoogle Scholar
  14. 14.
    Tang Q, Dieckmann R (2012) Orientation, oxygen activity and temperature dependencies of the diffusion of cobalt in cobalt orthosilicate, Co2SiO4. Solid State Ion 228:70–79Google Scholar
  15. 15.
    Wang X, Wu XL, Guo YG, Zhong Y, Cao X, Ma Y, Yao J (2010) Synthesis and lithium storage properties of Co3O4 nanosheet-assembled multishelled hollow spheres. Adv Func Mater 20:1680–1686CrossRefGoogle Scholar
  16. 16.
    Poizot P, Laruelle S, Grugeon S, Dupont L, Tarascon JM (2010) ChemInform abstract: nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries. Nature 407:496–499CrossRefGoogle Scholar
  17. 17.
    Varghese B, Reddy MV, Zhu Y, Chang SL, Hoong TC, Rao GVS, Chowdari BVR, Wee ATS, Lim CT, Sow CH (2008) Fabrication of NiO nanowall electrodes for high performance lithium ion battery. Chem Mater 20:3360–3367CrossRefGoogle Scholar

Copyright information

© The Minerals, Metals & Materials Society 2019

Authors and Affiliations

  • Yunyun Wei
    • 1
  • Guihong Han
    • 1
  • Yanfang Huang
    • 1
    Email author
  • Duo Zhang
    • 1
  1. 1.School of Chemical Engineering and EnergyZhengzhou UniversityZhengzhouPeople’s Republic of China

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