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Alloying and Annealing Effects on Grain Boundary Character Evolution of Al-alloy 7075 Thin Films: An ACOM-TEM Analysis

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Characterization of Minerals, Metals, and Materials 2019

Abstract

Since polycrystalline materials consist of a complex network of various types of grain boundaries (GBs), a detailed study on the types of the GBs , their distribution and how they are connected is crucial to further enhance the material’s performance. Herein, the GB character distribution (types and connectivity) of as-deposited Al and Al-alloy 7075 thin films , as well as annealed Al-alloy thin films , was investigated using an advanced microscopic technique: ACOM-TEM . Annealing processes up to 12 h caused a decrease in the content ratio of random high-angle GBs (r-HAGBs) and triple junctions comprised of r-HAGBs. However, there was no significant consequence of alloying in the GB type and connectivity distribution. Furthermore, our results indicate that vacuum-deposited Al or Al-alloy thin films possess a strong <111> texture, and a characteristic GB distribution consisting of a significantly high fraction of low coincidence site lattice GBs (predominant ∑1 followed by ∑13b, ∑7, ∑21a, ∑31a and ∑19b in descending order) and a minor fraction of r-HAGBs.

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References

  1. Watanabe T (1984) An approach to grain-boundary design for strong and ductile polycrystals. Res Mech 11(1):47–84

    CAS  Google Scholar 

  2. Thaveeprungsriporn V, Was GS (1997) The role of coincidence-site-lattice boundaries in Creep of Ni-16Cr-9Fe at 360 C. MMTA 28(10):2101–2112

    Article  Google Scholar 

  3. Shimada M, Kokawa H, Wang Z, Sato Y, Karibe I (2002) Optimization of grain boundary character distribution for intergranular corrosion resistant 304 stainless steel by twin-induced grain boundary engineering. Acta Mater 50(9):2331–2341

    Article  CAS  Google Scholar 

  4. Kobayashi S, Tsurekawa S, Watanabe T, Palumbo G (2010) Grain boundary engineering for control of sulfur segregation-induced embrittlement in ultrafine-grained nickel. Scripta Mater 62(5):294–297

    Article  CAS  Google Scholar 

  5. Kobayashi S, Nakamura M, Tsurekawa S, Watanabe T (2011) Effect of grain boundary microstructure on fatigue crack propagation in austenitic stainless steel. JMatS 46(12):4254–4260

    CAS  Google Scholar 

  6. Kobayashi S, Takagi H, Watanabe T (2013) Grain boundary character distribution and texture evolution during surface energy-driven grain growth in nanocrystalline gold thin films. Philos Mag 93(10–12):1425–1442

    Article  CAS  Google Scholar 

  7. Gao Y, Ritchie R, Kumar M, Nalla R (2005) High-cycle fatigue of nickel-based superalloy ME3 at ambient and elevated temperatures: role of grain-boundary engineering. MMTA 36(12):3325–3333

    Article  Google Scholar 

  8. Thompson C (1992) Experimental and theoretical aspects of grain growth in thin films. Mater Sci Forum 245–258. Trans Tech Publ

    Google Scholar 

  9. Watanabe T, Fujii H, Oikawa H, Arai K (1989) Grain boundaries in rapidly solidified and annealed Fe-6.5 mass% Si polycrystalline ribbons with high ductility. Acta Metall 37(3):941–952

    Article  CAS  Google Scholar 

  10. Watanabe T, Arai K-I, Yoshimi K, Oikawa H (1989) Texture and grain boundary character distribution (GBCD) in rapidly solidified and annealed Fe–6 5 mass% Si ribbons. Philos Mag Lett 59(2):47–52

    Article  CAS  Google Scholar 

  11. Garbacz A, Grabski M (1989) Modelling of CSL boundaries distribution in polycrystals. ScM 23(8):1369–1374

    Google Scholar 

  12. Zuo L, Watanabe T, Esling C (1994) A theoretical approach to grain boundary character distribution (GBCD) in textured polycrystalline materials. Z Metallkd 85(8):554–558

    CAS  Google Scholar 

  13. Singh VV, King AH, Dixit G (1997) Some further microstructural characteristics of face-centered cubic polycrystalline metal thin films. J Electron Mater 26(9):987–995

    Article  CAS  Google Scholar 

  14. Parajuli P, Mendoza-Cruz R, Santiago U, Ponce A, Yacamán MJ (2018) The evolution of growth, crystal orientation, and grain boundaries disorientation distribution in gold thin films. Cryst Res Technol 53(8):1–7

    Article  Google Scholar 

  15. Watanabe T (2011) Grain boundary engineering: historical perspective and future prospects. JMatS 46(12):4095–4115

    CAS  Google Scholar 

  16. Lejcek P (2010) Grain boundary segregation in metals. Springer Science & Business Media

    Google Scholar 

  17. Raabe D, Herbig M, Sandlöbes S, Li Y, Tytko D, Kuzmina M, Ponge D, Choi P-P (2014) Grain boundary segregation engineering in metallic alloys: a pathway to the design of interfaces. Curr Opin Solid State Mater Sci 18(4):253–261

    Article  CAS  Google Scholar 

  18. Raabe D, Sandlöbes S, Millán J, Ponge D, Assadi H, Herbig M, Choi P-P (2013) Segregation engineering enables nanoscale martensite to austenite phase transformation at grain boundaries: a pathway to ductile martensite. Acta Mater 61(16):6132–6152

    Article  CAS  Google Scholar 

  19. Palumbo G, Aust K (1995) Solute effects in grain boundary engineering. Can Metall Q 34(3):165–173

    Article  Google Scholar 

  20. Tacikowski M, Grabski M, Driver J, Kobylanski A (1996) The effect of carbon and sulphur on the character of the grain boundary population in α-iron. Mater Sci Eng A 205(1–2):133–138

    Article  Google Scholar 

  21. Belluz R, Aust K (1975) Effect of solutes on preferred orientation in high-purity aluminum. Metall Trans A 6:219–220

    Article  CAS  Google Scholar 

  22. Parajuli P, Mendoza-Cruz R, Hurtado-Macias A, Santiago U, Yacamán MJ (2018) A direct observation of ordered structures induced by Cu segregation at grain boundaries of Al 7075 Alloys. Phys Status Solidi (a) 215(19):1–8

    Google Scholar 

  23. Rauch EF, Veron M (2014) Automated crystal orientation and phase mapping in TEM. Mater Charact 98:1–9

    Article  CAS  Google Scholar 

  24. Mackenzie J (1958) Second paper on statistics associated with the random disorientation of cubes. Biome 45(1–2):229–240

    Google Scholar 

  25. Déchamps M, Baribier F, Marrouche A (1987) Grain-boundaries: criteria of specialness and deviation from CSL misorientation. Acta Metall 35(1):101–107

    Article  Google Scholar 

  26. Zhou Y, Erb U, Aust K, Palumbo G (2003) The effects of triple junctions and grain boundaries on hardness and Young’s modulus in nanostructured Ni–P. Scripta Mater 48(6):825–830

    Article  CAS  Google Scholar 

  27. Vitos L, Ruban AV, Skriver HL, Kollar J (1998) The surface energy of metals. Surf Sci 411(1–2):186–202

    Article  CAS  Google Scholar 

  28. Dillamore I, Smallman R (1965) The stacking-fault energy of FCC metals. Philos Mag 12(115):191–193

    Article  CAS  Google Scholar 

  29. Humphreys FJ, Hatherly M (2012) Recrystallization and related annealing phenomena. Elsevier

    Google Scholar 

Download references

Acknowledgements

The authors are thankful to the Welch Foundation Grant (No. AX-1615) and Department of Defense Grant (No. 64756-RT-REP and 72489-RT-REP). RMC acknowledges the National Council for Science and Technology (Conacyt), Mexico, for the support provided through the Postdoctoral Scholarship Program.

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Correspondence to Arturo Ponce .

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Parajuli, P., Mendoza-Cruz, R., Yacamán, M.J., Ponce, A. (2019). Alloying and Annealing Effects on Grain Boundary Character Evolution of Al-alloy 7075 Thin Films: An ACOM-TEM Analysis. In: Li, B., et al. Characterization of Minerals, Metals, and Materials 2019. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-05749-7_12

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