Abstract
Plasma catalysis has been demonstrated as a promising alternative to thermal catalysis for environmental clean-up and the synthesis of platform chemicals and fuels from different feedstocks at low temperatures. There have been considerable and increasing research activities in this emerging and interdisciplinary field in recent years. However, plasma catalysis, particularly using a single-stage configuration, is a very complex process involving both gas-phase reactions driven by the plasma and plasma-assisted surface reactions. A number of challenges need to be addressed to achieve significant advancement in this field and the full potential of this emerging technology.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsReferences
Gao, J., Zhu, J., Ehn, A., Aldén, M., & Li, Z. (2017). In-situ non-intrusive diagnostics of toluene removal by a gliding arc discharge using planar laser-induced fluorescence. Plasma Chemistry and Plasma Processing, 37, 433–450.
Teramoto, Y., Kim, H. H., Ogata, A., & Negishi, N. (2014). Measurement of OH (X2Σ) in immediate vicinity of dielectric surface under pulsed dielectric barrier discharge at atmospheric pressure using two geometries of laser-induced fluorescence. Journal of Applied Physics, 115, 133302.
Jia, Z., Wang, X., Thevenet, F., & Rousseau, A. (2017). Dynamic probing of plasma-catalytic surface processes: Oxidation of toluene on CeO2. Plasma Processes and Polymers, 14, 1600114.
Klages, C.-P., Hinze, A., & Khosravi, Z. (2013). Nitrogen plasma modification and chemical derivatization of polyethylene surfaces - an in situ study using FTIR-ATR spectroscopy. Plasma Processes and Polymers, 10, 948–958.
Stere, C. E., Anderson, J. A., Chansai, S., Delgado, J. J., Goguet, A., Graham, W. G., Hardacre C., Taylor S. F. R., Tu, X., Wang, Z., & Yang, H. (2017). Non-thermal plasma activation of gold-based catalysts for low-temperature water-gas shift catalysis. Angewandte Chemie, International Edition, 56, 5579–5583.
Neyts, E. C., & Bogaerts, A. (2014). Understanding plasma catalysis through modelling and simulation-a review. Journal of Physics D: Applied Physics, 47, 224010.
Somers, W., Bogaerts, A., Van Duin, A. C. T., Huygh, S., Bal, K. M., & Neyts, E. C. (2013). Temperature influence on the reactivity of plasma species on a nickel catalyst surface: An atomic scale study. Catalysis Today, 211, 131–136.
Tennyson, J., Rahimi, S., Hill, C., Tse, L., Vibhakar, A., & Akello-Egwel, D. (2017). QDB: A new database of plasma chemistries and reactions. Plasma Sources Science & Technology, 26, 055014.
Bogaerts, A., De Bie, C., Eckert, M., Georgieva, V., Martens, T., Neyts, E., & Tinck, S. (2010). Modeling of the plasma chemistry and plasma-surface interactions in reactive plasmas. Pure and Applied Chemistry, 82, 1283–1299.
Aerts, R., Tu, X., Van Gaens, W., Whitehead, J. C., & Bogaerts, A. (2013). Gas purification by nonthermal plasma: A case study of ethylene. Environmental Science & Technology, 47, 6478–6485.
Koen Van, L., & Annemie, B. (2016). Fluid modelling of a packed bed dielectric barrier discharge plasma reactor. Plasma Sources Science and Technology, 25, 015002.
Zhang, Y., Wang, H. Y., Jiang, W., & Bogaerts, A. (2015). Two-dimensional particle-in cell/Monte Carlo simulations of a packed-bed dielectric barrier discharge in air at atmospheric pressure. New Journal of Physics, 17, 12.
Van Laer, K., & Bogaerts, A. (2015). Improving the conversion and energy efficiency of carbon dioxide splitting in a zirconia-packed dielectric barrier discharge reactor. Energy Technology, 3, 1038–1044.
De Bie, C., Martens, T., van Dijk, J., Paulussen, S., Verheyde, B., Corthals, S., & Bogaerts, A. (2011). Dielectric barrier discharges used for the conversion of greenhouse gases: modeling the plasma chemistry by fluid simulations. Plasma Sources Science and Technology, 20, 024008.
Heijkers, S., Snoeckx, R., Kozák, T., Silva, T., Godfroid, T., Britun, N., Snyders, R., & Bogaerts, A. (2015). CO2 conversion in a microwave plasma reactor in the presence of N2: Elucidating the role of vibrational levels. Journal of Physical Chemistry C, 119, 12815–12828.
Cleiren, E., Heijkers, S., Ramakers, M., & Bogaerts, A. (2017). Dry reforming of methane in a gliding arc plasmatron: towards a better understanding of the plasma chemistry. ChemSusChem, 10, 4025-4036.
van Santen, R. A., Markvoort, A. J., Filot, I. A. W., Ghouri, M. M., & Hensen, E. J. M (2013). Mechanism and microkinetics of the Fischer-Tropsch reaction. Physical Chemistry Chemical Physics, 15, 17038–17063.
Filot, I. A. W., van Santen, R. A., & Hensen, E. J. M. (2014). The optimally performing Fischer-Tropsch catalyst. Angewandte Chemie-International Edition, 53, 12746–12750.
Kim, J., Go, D. B., & Hicks, J. C. (2017). Synergistic effects of plasma-catalyst interactions for CH4 activation. Physical Chemistry Chemical Physics, 19, 13010–13021.
Snoeckx, R., & Bogaerts, A. (2017). Plasma technology - a novel solution for CO2 conversion? Chemical Society Reviews, 46, 5805-5863.
Hessel, V., Cravotto, G., Fitzpatrick, P., Patil, B. S., Lang, J., & Bonrath, W. (2013). Industrial applications of plasma, microwave and ultrasound techniques: Nitrogen-fixation and hydrogenation reactions. Chemical Engineering and Processing, 71, 19–30.
Mori, S., Matsuura, N., Tun, L. L., & Suzuki, M. (2016). Direct synthesis of carbon nanotubes from only CO2 by a hybrid reactor of dielectric barrier discharge and solid oxide electrolyser cell. Plasma Chemistry and Plasma Processing, 36, 231–239.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2019 Springer Nature Switzerland AG
About this chapter
Cite this chapter
Whitehead, J.C. (2019). Plasma Catalysis: Challenges and Future Perspectives. In: Tu, X., Whitehead, J., Nozaki, T. (eds) Plasma Catalysis. Springer Series on Atomic, Optical, and Plasma Physics, vol 106. Springer, Cham. https://doi.org/10.1007/978-3-030-05189-1_11
Download citation
DOI: https://doi.org/10.1007/978-3-030-05189-1_11
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-05188-4
Online ISBN: 978-3-030-05189-1
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)