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Pesticides: Classification, Detection, and Degradation

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Abstract

Extensive and excessive use of organic pesticides poses a serious threat to the environment. The degradation products of most organic pesticides are far more toxic than the parent compound. The toxic effect of common pesticides, their degradation mechanisms, and common detection techniques are evaluated here. A literature survey shows that a detailed discussion on this relationship is extremely relevant in the current scenario.

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References

  • Alavanja, M. C. R., Hoppin, J. A., & Kamel, F. (2004). Health effects of chronic pesticide exposure: Cancer and neurotoxicity. Annual Review of Public Health, 25(1), 155–197.

    Article  PubMed  Google Scholar 

  • Alternative and Biological Pest Controls | Commons Abundance Network. (n.d.).

    Google Scholar 

  • Application of chemically modified fused silica fibers in the extraction of organics from water matrix samples and their rapid transfer to capillary columns. (n.d.). [Online]. Available: https://www.researchgate.net/publication/292092766_Application_of_chemically_modified_fused_silica_fibers_in_the_extraction_of_organics_from_water_matrix_samples_and_their_rapid_transfer_to_capillary_columns. Accessed: 01 Sept 2016.

  • Balinova, A. M., & Balinov, I. (1991). Determination of herbicide residues in soil in the presence of persistent organochlorine insecticides. Fresenius’ Journal of Analytical Chemistry, 339, 6, 409–412.

    Google Scholar 

  • Barker, S. A. (2007). Matrix solid phase dispersion (MSPD). Journal of Biochemical and Biophysical Methods, 70(2), 151–162.

    Article  CAS  PubMed  Google Scholar 

  • Basta, N. T., & Olness, A. (1992). Determination of alachlor, atrazine, and metribuzin in soil by resin extraction. Journal of Environmental Quality, 21(3), 497.

    Article  CAS  Google Scholar 

  • Benson, W. R. (1969). The chemistry of pesticides. Annals of the New York Academy of Sciences, 160(1), 7–29.

    Article  CAS  PubMed  Google Scholar 

  • Bertazzi, P. A., Consonni, D., Bachetti, S., Rubagotti, M., Baccarelli, A., Zocchetti, C., & Pesatori, A. C. (2001). Health effects of dioxin exposure: A 20-year mortality study. American Journal of Epidemiology, 153(11), 1031–1044.

    Article  CAS  PubMed  Google Scholar 

  • de Bertrand, N., Durand, G., & Barceló, D. (1991). Extraction, cleanup and liquid chromatographic-diode array determination of carbamate pesticides in soil samples. Journal of Environmental Science and Health Part A: Environmental Science and Engineering and Toxicology, 26(4), 575–597.

    Google Scholar 

  • Bradberry, S. M., Cage, S. A., Proudfoot, A. T., & Vale, J. A. (2012). Poisoning due to pyrethroids. Toxicological Reviews, 24(2), 93–106.

    Article  Google Scholar 

  • Bushway, R. J., Li, L., Paradis, L. R., & Perkins, L. B. (1995). Determination of thiabendazole in potatoes, fruits, and their processed products by liquid chromatography. Journal of AOAC International, 78(3), 815–820.

    CAS  PubMed  Google Scholar 

  • Carabias-Martínez, R., Rodríguez-Gonzalo, E., Revilla-Ruiz, P., & Hernández-Méndez, J. (2005). Pressurized liquid extraction in the analysis of food and biological samples. Journal of Chromatography A, 1089(1–2), 1–17.

    Article  PubMed  CAS  Google Scholar 

  • Compelling Evidence of Human Health Effects of Pesticides. (n.d.). [Online]. Available: http://www.twn.my/title2/susagri/2015/sa417.htm. Accessed: 27 Aug 2016.

  • Conway, G. R., & Barbier, E. B. (2013). After the green revolution: Sustainable agriculture for development. London: Routledge.

    Google Scholar 

  • Dequaire, M., Degrand, C., & Limoges, B. (1999). An immunomagnetic electrochemical sensor based on a perfluorosulfonate-coated screen-printed electrode for the determination of 2,4-dichlorophenoxyacetic acid. Analytical Chemistry, 71(13), 2571–2577.

    Article  CAS  PubMed  Google Scholar 

  • Durand, G., Forteza, R., & Barceló, D. (1989). Determination of chlorotriazine herbicides, their dealkylated degradation products and organophosphorus pesticides in soil samples by means of two different clean up procedures. Chromatographia, 28(11–12), 597–604.

    Article  CAS  Google Scholar 

  • Durand, G., de Bertrand, N., & Barceló, D. (1991). Mobile phase variations in thermospray liquid chromatography-mass spectrometry of pesticides. Journal of Chromatography, 562(1–2), 507–523.

    Article  CAS  PubMed  Google Scholar 

  • Durand, G., Gille, P., Fraisse, D., & Barceló, D. (1992). Comparison of gas chromatographic-mass spectrometric methods for screening of chlorotriazine pesticides in soil. Journal of Chromatography, 603(1–2), 175–184.

    Article  CAS  PubMed  Google Scholar 

  • Eskenazi, B., Bradman, A., & Castorina, R. (1999). Exposures of children to organophosphate pesticides and their potential adverse health effects. Environmental Health Perspectives, 107(Suppl 3), 409–419.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Garcia Sanchez, F., & Aguilar Gallardo, A. (1992). Spectrofluorimetric determination of the insecticide azinphos-methyl in cultivated soils following generation of a fluorophore by hydrolysis. Analyst, 117(2), 195–198.

    Article  CAS  Google Scholar 

  • Gimeno-García, E., Andreu, V., & Boluda, R. (1996). Heavy metals incidence in the application of inorganic fertilizers and pesticides to rice farming soils. Environmental Pollution, 92(1), 19–25.

    Article  PubMed  Google Scholar 

  • Hawthorne, S. B., Grabanski, C. B., Martin, E., & Miller, D. J. (2000). Comparisons of soxhlet extraction, pressurized liquid extraction, supercritical fluid extraction and subcritical water extraction for environmental solids: Recovery, selectivity and effects on sample matrix. Journal of Chromatography. A, 892(1–2), 421–433.

    Article  CAS  PubMed  Google Scholar 

  • Huang, S.-D., Cheng, C.-P., & Sung, Y.-H. (1997). Determination of benzene derivatives in water by solid-phase microextraction. Analytica Chimica Acta, 343(1), 101–108.

    Article  Google Scholar 

  • Kadenczki, L., Arpad, Z., Gardi, I., Ambrus, A., Gyorfi, L., Reese, G., & Ebing, W. (1992). Column extraction of residues of several pesticides from fruits and vegetables – A simple multiresidue analysis method. Journal of AOAC International, 75(1), 53–61.

    CAS  Google Scholar 

  • Kane, M., Dean, J. R., Hitchen, S. M., et al. (1993). Experimental design approach for supercritical fluid extraction. Analyst, 271, 83–90.

    Article  Google Scholar 

  • Karalliedde, L., Wheeler, H., Maclehose, R., & Murray, V. (2000). Possible immediate and long-term health effects following exposure to chemical warfare agents. Public Health, 114(4), 238–248.

    Article  CAS  PubMed  Google Scholar 

  • Karami-Mohajeri, S., & Abdollahi, M. (2011). Toxic effects of organophosphate, carbamate, and organochlorine pesticides on cellular metabolism of lipids, proteins, and carbohydrates: A comprehensive review. Human & Experimental Toxicology, 30(9), 1119–1140.

    Google Scholar 

  • King, J. W., & Nam, K.-S. (1996). Coupling enzyme immunoassay with supercritical fluid extraction. In Immunoassays for residue analysis (vol. 621, pp. 422–438). 0 vols. American Chemical Society, USA.

    Google Scholar 

  • Kligerman, A. D., Doerr, C. L., Tennant, A. H., & Zucker, R. M. (2000). Cytogenetic studies of three triazine herbicides: I. In vitro studies1. Mutation Research Genetic Toxicology and Environmental Mutagenesis, 465(1–2), 53–59.

    Article  CAS  PubMed  Google Scholar 

  • Kotouček, M., & Opravilová, M. (1996). Voltammetric behaviour of some nitropesticides at the mercury drop electrode. Analytica Chimica Acta, 329(1), 73–81.

    Article  Google Scholar 

  • Kumar, V., Upadhay, N., Wasit, A., Singh, S., & Kaur, P. (2013). Spectroscopic methods for the detection of organophosphate pesticides – A preview. Current World Environment Journal, 8(2), 313–318.

    Article  Google Scholar 

  • Lawruk, T. S., Lachman, C. E., Jourdan, S. W., Fleeker, J. R., Herzog, D. P., & Rubio, F. M. (1993). Determination of metolachlor in water and soil by a rapid magnetic particle-based ELISA. Journal of Agricultural and Food Chemistry, 41(9), 1426–1431.

    Article  CAS  Google Scholar 

  • Liao, W., Joe, T., & Cusick, W. G. (1991). Multiresidue screening method for fresh fruits and vegetables with gas chromatographic/mass spectrometric detection. Journal Association of Official Analytical Chemists, 74(3), 554–565.

    CAS  PubMed  Google Scholar 

  • Longnecker, M. P., Rogan, W. J., & Lucier, G. (1997). The human health effects of Ddt (dichlorodiphenyltrichloroethane) and Pcbs (polychlorinated biphenyls) and an overview of organochlorines in public health. Annual Review of Public Health, 18(1), 211–244.

    Article  CAS  PubMed  Google Scholar 

  • López-Mesas, M., Crespi, M., Brach, J., & Mullender, J. P. (2000). Clean-up of a pesticide-lanolin mixture by gel permeation chromatography. Journal of Chromatographic Science, 38(12), 551–555.

    Article  PubMed  Google Scholar 

  • Martin-Neto, L., Traghetta, D. G., Vaz, C. M. P., Crestana, S., & Sposito, G. (2001). On the interaction mechanisms of atrazine and hydroxyatrazine with humic substances. Journal of Environmental Quality, 30(2), 520.

    Article  CAS  PubMed  Google Scholar 

  • McHugh, M., & Krukonis, V. (2013). Supercritical fluid extraction: Principles and practice. New York: Elsevier.

    Google Scholar 

  • Miyahara, M., Okada, Y., Takeda, H., Aoki, G., Kobayashi, A., & Saito, Y. (1994). Multiresidue procedures for the determination of pesticides in food using capillary gas chromatographic, flame photometric, and mass spectrometric techniques. Journal of Agricultural and Food Chemistry, 42(12), 2795–2802.

    Article  CAS  Google Scholar 

  • Mustafa, A., & Turner, C. (2011). Pressurized liquid extraction as a green approach in food and herbal plants extraction: A review. Analytica Chimica Acta, 703(1), 8–18.

    Article  CAS  PubMed  Google Scholar 

  • Nkedi-Kizza, P., & Owusu-Yaw, J. (1992). Simultaneous high-performance liquid chromatographic determination of nitrate, nitrite, and organic pesticides in soil solution using a multidimensional column with ultraviolet detection. Journal of Environmental Science and Health, Part A Environmental Science Engineering, 27(1), 245–259.

    Google Scholar 

  • Norris, M. V., Vail, W. A., & Averell, P. R. (1954). Pesticide residues, colorimetric estimation of malathion residues. Journal of Agricultural and Food Chemistry, 2(11), 570–573.

    Article  CAS  Google Scholar 

  • Omeroglu, P. Y., Boyacioglu, D., Ambrus, Á., Karaali, A., & Saner, S. (2012). An overview on steps of pesticide residue analysis and contribution of the individual steps to the measurement uncertainty. Food Analytical Methods, 5(6), 1469–1480.

    Article  Google Scholar 

  • Oniszczuk, A., Waksmundzka-Hajnos, M., Skalicka-Woźniak, K., & Głowniak, K. (2013). Comparison of matrix-solid phase dispersion and liquid–solid extraction connected with solid-phase extraction in the quantification of selected furanocoumarins from fruits of Heracleum leskowii by high performance liquid chromatography. Industrial Crops and Products, 50, 131–136.

    Article  CAS  Google Scholar 

  • Raju, J., & Gupta, V. K. (1991). A simple spectrophotometric determination of endosulfan in river water and soil. Fresenius’ Journal of Analytical Chemistry, 339(6), 431–433.

    Google Scholar 

  • Rogers, K. R., Cao, C. J., Valdes, J. J., Eldefrawi, A. T., & Eldefrawi, M. E. (1991a). Acetylcholinesterase fiber-optic biosensor for detection of anticholinesterases. Fundamental and Applied Toxicology: Official Journal of the Society of Toxicology, 16(4), 810–820.

    Article  CAS  Google Scholar 

  • Rogers, K. R., Eldefrawi, M. E., Menking, D. E., Thompson, R. G., & Valdes, J. J. (1991b). Pharmacological specificity of a nicotinic acetylcholine receptor optical sensor. Biosensors & Bioelectronics, 6(6), 507–516.

    Article  CAS  Google Scholar 

  • Rogers, K. R., Valdes, J. J., & Eldefrawi, M. E. (1991c). Effects of receptor concentration, media pH and storage on nicotinic receptor-transmitted signal in a fiber-optic biosensor. Biosensors & Bioelectronics, 6(1), 1–8.

    Article  CAS  Google Scholar 

  • Rosenfeld, J. M. (1999). Solid-phase analytical derivatization: Enhancement of sensitivity and selectivity of analysis. Journal of Chromatography. A, 843(1–2), 19–27.

    Article  CAS  PubMed  Google Scholar 

  • Saillenfait, A.-M., Ndiaye, D., & Sabaté, J.-P. (2015). Pyrethroids: Exposure and health effects – An update. International Journal of Hygiene and Environmental Health, 218(3), 281–292.

    Article  CAS  PubMed  Google Scholar 

  • Schade, G., & Heinzow, B. (1998). Organochlorine pesticides and polychlorinated biphenyls in human milk of mothers living in northern Germany: Current extent of contamination, time trend from 1986 to 1997 and factors that influence the levels of contamination. Science of The Total Environment, 215(1–2), 31–39.

    Article  CAS  PubMed  Google Scholar 

  • Senanayake, N., & Karalliedde, L. (1987). Neurotoxic effects of organophosphorus insecticides. The New England Journal of Medicine, 316(13), 761–763.

    Article  CAS  PubMed  Google Scholar 

  • Shafer, T. J., Meyer, D. A., & Crofton, K. M. (2005). Developmental neurotoxicity of pyrethroid insecticides: Critical review and future research needs. Environmental Health Perspectives, 113(2), 123–136.

    Article  CAS  PubMed  Google Scholar 

  • Singh, R. B. (2000). Environmental consequences of agricultural development: A case study from the Green Revolution state of Haryana, India. Agriculture, Ecosystems and Environment, 82(1–3), 97–103.

    Article  Google Scholar 

  • Sposito, G., Martin-Neto, L., & Yang, A. (1996). Atrazine complexation by soil humic acids. Journal of Environmental Quality, 25(6), 1203.

    Article  CAS  Google Scholar 

  • Sterling, T. D., & Arundel, A. V. (1986). Health effects of phenoxy herbicides: A review. Scandinavian Journal of Work, Environment & Health, 12(3), 161–173.

    Article  CAS  Google Scholar 

  • Suchan, P., Pulkrabová, J., Hajšlová, J., & Kocourek, V. (2004). Pressurized liquid extraction in determination of polychlorinated biphenyls and organochlorine pesticides in fish samples. Analytica Chimica Acta, 520(1–2), 193–200.

    Article  CAS  Google Scholar 

  • Taylor S. G. (Florida Department of Agriculture and Consumer Services, Tallahassee, FL). (1991). General method for determination of pesticides in soil samples from pesticide mixer/loader sites. Journal Association of Official Analytical Chemists, USA 74, 878–883.

    Google Scholar 

  • Timperley, C. M., Casey, K. E., Notman, S., Sellers, D. J., Williams, N. E., Williams, N. H., & Williams, G. R. (2006). Synthesis and anticholinesterase activity of some new fluorogenic analogues of organophosphorus nerve agents. Journal of Fluorine Chemistry, 127(12), 1554–1563.

    Article  CAS  Google Scholar 

  • Venugopal, N. V. S., Sumalatha, B., & Syedabano. (2012). Spectrophotometric determination of malathion in environmental samples. Journal of Chemistry, 9(2), 857–862.

    CAS  Google Scholar 

  • Vijverberg, H. P. M., & vanden Bercken, J. (1990). Neurotoxicological effects and the mode of action of pyrethroid insecticides. Critical Reviews in Toxicology, 21(2), 105–126.

    Article  CAS  PubMed  Google Scholar 

  • Wan, H. B., & Wong, M. K. (1996). Minimization of solvent consumption in pesticide residue analysis. Journal of Chromatography. A, 754(1), 43–47.

    Article  CAS  Google Scholar 

  • Wang, Z.-D., Gamble, D. S., & Langford, C. H. (1990a). Interaction of atrazine with Laurentian fulvic acid: Binding and hydrolysis. Analytica Chimica Acta, 232, 181–188.

    Article  CAS  Google Scholar 

  • Wang, Z.-D., Pant, B. C., & Langford, C. H. (1990b). Spectroscopic and structural characterization of a Laurentian fulvic acid: Notes on the origin of the color. Analytica Chimica Acta, 232, 43–49.

    Article  CAS  Google Scholar 

  • Welhouse, G. J., & Bleam, W. F. (1992). NMR spectroscopic investigation of hydrogen bonding in atrazine. Environmental Science & Technology, 26(5), 959–964.

    Article  CAS  Google Scholar 

  • Wesseling, C., Keifer, M., Ahlbom, A., McConnell, R., Moon, J.-D., Rosenstock, L., & Hogstedt, C. (2002). Long-term neurobehavioral effects of mild poisonings with organophosphate and n-methyl carbamate pesticides among banana workers. International Journal of Occupational and Environmental Health, 8(1), 27–34.

    Article  CAS  PubMed  Google Scholar 

  • What are Pesticides|Definition|Types|Uses and Effects. (2016). Chemistry.

    Google Scholar 

  • Wolfe, W. H., Michalek, J. E., Miner, J. C., et al. (1990). Health status of air force veterans occupationally exposed to herbicides in Vietnam: I. Physical health. JAMA, 264(14), 1824–1831.

    Article  CAS  PubMed  Google Scholar 

  • Wong, J. M., Li, Q. X., Hammock, B. D., & Seiber, J. N. (1991). Method for the analysis of 4-nitrophenol and parathion in soil using supercritical fluid extraction and immunoassay. Journal of Agricultural and Food Chemistry, 39(10), 1802–1807.

    Article  CAS  Google Scholar 

  • Zacharia, & Tano, J. (2011). Identity, physical and chemical properties of pesticides. In M. Stoytcheva (Ed.), Pesticides in the modern world – trends in pesticides analysis. Rijeka: InTech.

    Google Scholar 

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Sarath Chandran, C., Thomas, S., Unni, M.R. (2019). Pesticides: Classification, Detection, and Degradation. In: Sarath Chandran, C., Thomas, S., Unni, M. (eds) Organic Farming. Springer, Cham. https://doi.org/10.1007/978-3-030-04657-6_5

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