Abstract
Thus far, the synthesis and comprehensive studies on closed- and open-shell group 6 and 7 transition metal tetrylidyne complexes were discussed. In all these complexes, the tetrel atoms are bonded to a bulky organyl group, such as C6H3-2,6-Mes2, N(SiMe3)(C6H2-2,4,6-tBu3) etc., which are necessary to stabilize the highly reactive tetrylidyne complexes. In this chapter, we will focus on the synthesis of heavier analogues of μ2-carbido complexes featuring heavier tetrel atoms, that are bonded only two metal fragments. Furthermore, the reactivity of this interesting class of compounds will be discussed in detail.
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Notes
- 1.
A CSD Survey (11.05.2016) gave 85 compounds with Mo–Si single bonds and 79 compounds with W–Si single bonds, leading to a median/mean Mo–Si and W–Si bond lengths of 2.564/2.559 Å and 2.569/2.568 Å, respectively.
- 2.
The quantum chemical calculations were performed by Dr. G. Schnakenburg.
- 3.
A CSD Survey (17.05.2016) gave 34 compounds with Mo–Ge single bonds and 90 compounds with W–Ge single bonds, leading to a median/mean Mo–Ge and W–Ge bond lengths of 2.625/2.587 Å and 2.605/2.584 Å, respectively.
References
O. Chernov, Novel Molecular Si(II) Precursors for Synthesis of the First Compounds with Metal-Silicon Triple Bonds, Ph. D. Thesis, Bonn Universitäts- und Landesbibliothek, Bonn (2012)
A.C. Filippou, O. Chernov, G. Schnakenburg, Chem. Eur. J. 17, 13574 (2011)
A.C. Filippou, B. Baars, O. Chernov, Y.N. Lebedev, G. Schnakenburg, Angew. Chem. Int. Ed. 53, 565 (2014)
A.C. Filippou, O. Chernov, K.W. Stumpf, G. Schnakenburg, Angew. Chem. Int. Ed. 49, 3296 (2010)
T. Fukuda, T. Yoshimoto, H. Hashimoto, H. Tobita, Organometallics 35, 921 (2016)
A.C. Filippou, H. Rohde, G. Schnakenburg, Angew. Chem. Int. Ed. 43, 2243 (2004)
R.S. Simons, P.P. Power, J. Am. Chem. Soc. 118, 11966 (1996)
L.H. Pu, B. Twamley, S.T. Haubrich, M.M. Olmstead, B.V. Mork, R.S. Simons, P.P. Power, J. Am. Chem. Soc. 122, 650 (2000)
A.C. Filippou, K.W. Stumpf, O. Chernov, G. Schnakenburg, Organometallics 31, 748 (2012)
J. Hicks, T.J. Hadlington, C. Schenk, J.Y. Li, C. Jones, Organometallics 32, 323 (2013)
Y. N. Lebedev, Multiple Bonding of Low-valent Si and Ge to Group 6 and 9 Metals, Ph. D. Thesis, The Rheinische Friedrich-Wilhelms-Universität Bonn, Verlag Dr. Hut, München (2014)
H. Hashimoto, T. Fukuda, H. Tobita, M. Ray, S. Sakaki, Angew. Chem. Int. Ed. 51, 2930 (2012)
A.C. Filippou, A.I. Philippopoulos, P. Portius, D.U. Neumann, Angew. Chem. Int. Ed. 39, 2778 (2000)
A.C. Filippou, P. Portius, A.I. Philippopoulos, Organometallics 21, 653 (2002)
A.C. Filippou, N. Weidemann, A.I. Philippopoulos, G. Schnakenburg, Angew. Chem. Int. Ed. 45, 5987 (2006)
A.C. Filippou, A. Barandov, G. Schnakenburg, B. Lewall, M. van Gastel, A. Marchanka, Angew. Chem. Int. Ed. 51, 789 (2012)
D. Matioszek, N. Katir, N. Saffon, A. Castel, Organometallics 29, 3039 (2010)
W.P. Leung, W.K. Chiu, T.C.W. Mak, Organometallics 31, 6966 (2012)
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Ghana, P. (2019). µ-Ylido Complexes. In: Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato Ligands. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-030-02625-7_7
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