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A New Method for the Synthesis of Manganese Tetrylidyne Complexes

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Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato Ligands

Part of the book series: Springer Theses ((Springer Theses))

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Abstract

Thus far, only tetrylidyne complexes of group 6 transition metals were discussed and the chemistry was explored to a certain extend in the last two decades.

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Notes

  1. 1.

    A Cambridge Structural Database survey (29/02/2016) gave 50 hits of Mn complexes containing single bonds to four-coordinate Sn atoms. The Mn−Sn single bond lengths ranged from 2.455 to 2.758 Å with mean and median values of 2.619 and 2.620 Å, respectively. For the shortest and longest reported Mn−Sn single bonds, respectively, see (a) Schiemenz, B.; Ettel, F.; Huttner, G.; Zsolnai, L. J. Organomet. Chem. 1993, 458, 159; (b) Haupt, H.-J.; Preut, H.; Wolfes, W. Z. Anorg. Allg. Chem. 1978, 446, 105.

  2. 2.

    The solid state structure of 42 was also determined by single crystal X-ray diffraction analysis and showed the same structural motif and bonding parameters for the complex cation as in 41. However, due to the low quality of the two data sets for two different samples, the structure of 42 was not further considered.

  3. 3.

    The closest interionic contact (2.399 Å) exists between a F atom of the counteranion and a m-CH group of the central phenyl ring of the m-terphenyl substituent. No contacts to the Sn atom were found that are shorter than van der Waals contacts.

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  1. Institute Für Anorganische Chemie, Rheinische Friedrich-Wilhelms-Universität Bonn, Bonn, Nordrhein-Westfalen, Germany

    Priyabrata Ghana

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Ghana, P. (2019). A New Method for the Synthesis of Manganese Tetrylidyne Complexes. In: Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato Ligands. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-030-02625-7_5

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