Abstract
The work presented in this thesis is predominantly focused on the development of unprecedented open-shell tetrylidyne complexes of group 6 and 7 transition metals comprising of a tetrel-centered unpaired electron, and the heavier analogues of metallacarbyne complexes featuring a multiply-bonded tetrel element between two metal fragments. In addition, an unique intermetallic plumbylidyne ligand transfer reaction was discovered and an NHC-stabilized disilavinylidene was isolated for the first time under normal experimental conditions.
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Ghana, P. (2019). Summary. In: Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato Ligands. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-030-02625-7_11
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DOI: https://doi.org/10.1007/978-3-030-02625-7_11
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Publisher Name: Springer, Cham
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Online ISBN: 978-3-030-02625-7
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