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Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato Ligands

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Abstract

The introduction of the periodic table by Mendeleev and Meyer was a renaissance in chemistry which provided a useful tool to chemists to assimilate such a vast array of elements of different physical and chemical properties.

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Notes

  1. 1.

    In 2003, Tilley and co-workers reported the complex [{Cp*(dmpe)(H)MoSi–Mes)}{B(C6F5)4}] (Cp* = η5-C5Me5) with considerable silylidyne character but due to the weak interaction of the H atom with the silicon center, the bonding situation is quite different from that of a genuine silylidyne complex.

  2. 2.

    An analogoues Ge compound [(η5-C5H4Me)Mn(CO)2(GeCl2)] is a stable and isolable species as a THF or benzothiazole adduct; see: P. Jutzi, W. Steiner, Chem. Ber. 1976, 109, 3473.

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  1. Institute für Anorganische Chemie, Rheinische Friedrich-Wilhelms-Universität Bonn, Bonn, Nordrhein-Westfalen, Germany

    Priyabrata Ghana

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Ghana, P. (2019). Introduction. In: Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato Ligands. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-030-02625-7_1

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