Skip to main content

Temperature Effect on Alkali Contaminated Kaolinitic Clays

  • Conference paper
  • First Online:
Recent Advances in Geo-Environmental Engineering, Geomechanics and Geotechnics, and Geohazards (CAJG 2018)

Part of the book series: Advances in Science, Technology & Innovation ((ASTI))

Included in the following conference series:

  • 1270 Accesses

Abstract

It is well understood that the swelling behavior of alkali contaminated kaolinitic clays is mainly influenced by mineralogical and morphological changes. However, complete mineralogical changes occur over a long period of time due to slow reaction rates at normal temperatures or field contamination conditions. The long term effects of alkali on kaolinitic clays can be simulated by increasing the reaction rate through carrying the studies at elevated temperatures. The present study focused on understanding the effect of temperature (35, 60, 80 and 110 °C) on mineral dissolution and new mineral formations of alkali contaminated kaolinitic clays. Further, the obtained results were compared with the mineralogy changes observed in soil samples after interacting with alkali for a long period (60 days) in laboratory at normal temperature of about 27 °C, considering the field contamination condition. It is clear from the XRD and SEM studies that a complete change in morphology was observed when exposed to higher temperatures.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Similar content being viewed by others

References

  1. Shekhtman, L.M., Baranov, V.T., Nesterenko, G.F.: Building deformations caused by the leakage of chemical reagents. Soil Mech. Found. Eng. 32(1), 32–36 (1995)

    Article  Google Scholar 

  2. Sibley, M.H., Vadgama, N.J.: Investigation of ground heave at ICI Mond division, Castner-Keller works. Runcorn. Geol. Soc. Lond. Eng. Geol. Spec. Publ. 2, 367–373 (1986)

    Google Scholar 

  3. Cuadros, J., Linares, J.: Experimental kinetic study of the smectite-to-illite transformation. Geochim. Cosmochim. Acta 60, 439–453 (1996)

    Article  Google Scholar 

  4. Wang, Y., Siu, W.: Structure characteristics and mechanical properties of kaolinite soils. I. Surface charges and structural characterizations. Can. Geotech. J. 43, 587–600 (2006)

    Google Scholar 

  5. Mitchell, J.K.: Fundamentals of Soil Behavior, 2nd edn. Wiley, New York, NY (1993)

    Google Scholar 

  6. Barrer, R.M.: Hydrothermal Chemistry of Zeolites. Academic Press, London (1982)

    Google Scholar 

  7. Chavali, R.V.P., Vindula, S.K., Reddy, H.P.P., Ambili, B., Rakesh Pillai, J.: Swelling behavior of kaolinitic soils contaminated with alkali solutions: a micro-level study. Appl. Clay Sci. 135, 575–582 (2016)

    Google Scholar 

  8. Sruthi, P.L., Reddy, H.P.P.: Characterization of kaolinitic clays subjected to alkali contamination. Appl. Clay Sci. 146, 535–547 (2017)

    Article  Google Scholar 

  9. Russell, A.: Topaz from Cornwall, with an account of its localities. Mineral. Mag. 20(106), 221–236 (1924)

    Google Scholar 

  10. Barnes, M.C., Addai-Mensah, J., Gerso, A.R.: A methodology for quantifying sodalite and cancrinite phase mixtures and the kinetics of the sodalite to cancrinite phase transformation. Microporous Mesoporous Mater. 31, 303–319 (1999)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to P. Hari Prasad Reddy .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2019 Springer Nature Switzerland AG

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Lakshmi Sruthi, P., Hari Prasad Reddy, P. (2019). Temperature Effect on Alkali Contaminated Kaolinitic Clays. In: Kallel, A., et al. Recent Advances in Geo-Environmental Engineering, Geomechanics and Geotechnics, and Geohazards. CAJG 2018. Advances in Science, Technology & Innovation. Springer, Cham. https://doi.org/10.1007/978-3-030-01665-4_55

Download citation

Publish with us

Policies and ethics