Abstract
It is well understood that the swelling behavior of alkali contaminated kaolinitic clays is mainly influenced by mineralogical and morphological changes. However, complete mineralogical changes occur over a long period of time due to slow reaction rates at normal temperatures or field contamination conditions. The long term effects of alkali on kaolinitic clays can be simulated by increasing the reaction rate through carrying the studies at elevated temperatures. The present study focused on understanding the effect of temperature (35, 60, 80 and 110 °C) on mineral dissolution and new mineral formations of alkali contaminated kaolinitic clays. Further, the obtained results were compared with the mineralogy changes observed in soil samples after interacting with alkali for a long period (60 days) in laboratory at normal temperature of about 27 °C, considering the field contamination condition. It is clear from the XRD and SEM studies that a complete change in morphology was observed when exposed to higher temperatures.
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References
Shekhtman, L.M., Baranov, V.T., Nesterenko, G.F.: Building deformations caused by the leakage of chemical reagents. Soil Mech. Found. Eng. 32(1), 32–36 (1995)
Sibley, M.H., Vadgama, N.J.: Investigation of ground heave at ICI Mond division, Castner-Keller works. Runcorn. Geol. Soc. Lond. Eng. Geol. Spec. Publ. 2, 367–373 (1986)
Cuadros, J., Linares, J.: Experimental kinetic study of the smectite-to-illite transformation. Geochim. Cosmochim. Acta 60, 439–453 (1996)
Wang, Y., Siu, W.: Structure characteristics and mechanical properties of kaolinite soils. I. Surface charges and structural characterizations. Can. Geotech. J. 43, 587–600 (2006)
Mitchell, J.K.: Fundamentals of Soil Behavior, 2nd edn. Wiley, New York, NY (1993)
Barrer, R.M.: Hydrothermal Chemistry of Zeolites. Academic Press, London (1982)
Chavali, R.V.P., Vindula, S.K., Reddy, H.P.P., Ambili, B., Rakesh Pillai, J.: Swelling behavior of kaolinitic soils contaminated with alkali solutions: a micro-level study. Appl. Clay Sci. 135, 575–582 (2016)
Sruthi, P.L., Reddy, H.P.P.: Characterization of kaolinitic clays subjected to alkali contamination. Appl. Clay Sci. 146, 535–547 (2017)
Russell, A.: Topaz from Cornwall, with an account of its localities. Mineral. Mag. 20(106), 221–236 (1924)
Barnes, M.C., Addai-Mensah, J., Gerso, A.R.: A methodology for quantifying sodalite and cancrinite phase mixtures and the kinetics of the sodalite to cancrinite phase transformation. Microporous Mesoporous Mater. 31, 303–319 (1999)
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Lakshmi Sruthi, P., Hari Prasad Reddy, P. (2019). Temperature Effect on Alkali Contaminated Kaolinitic Clays. In: Kallel, A., et al. Recent Advances in Geo-Environmental Engineering, Geomechanics and Geotechnics, and Geohazards. CAJG 2018. Advances in Science, Technology & Innovation. Springer, Cham. https://doi.org/10.1007/978-3-030-01665-4_55
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DOI: https://doi.org/10.1007/978-3-030-01665-4_55
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