Skip to main content

Mg-Exchanged Montmorillonite Undergoing External Environmental Solicitation: Crystalline Swelling Process Investigation

  • Conference paper
  • First Online:
Book cover Petrogenesis and Exploration of the Earth’s Interior (CAJG 2018)

Part of the book series: Advances in Science, Technology & Innovation ((ASTI))

Included in the following conference series:

Abstract

This work reports a characterization of the possible effects that might affect the hydration properties of Mg-exchanged low-charge montmorillonite (SWy-2-Mg) when undergoes an external environmental solicitation. The latter was created by an alteration of relative humidity rates (i.e. RH%) over two hydration-dehydration cycles with different sequence. The study was mainly based on the X-ray diffraction profile modeling approach. Obtained results show strong hydration dependence as a function of the RH sequence. The interlayer configuration presents a heterogeneous hydration behavior which was systematically observed at different stages of both cycles. The interlayer water uptake process presents similar hysteresis characterized by fluctuations of interlayer water molecule abundances.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Vengris, T.: Nickel, copper and zinc removal from waste water by modified clay sorbent. Appl. Clay Sci. 18, 183–190 (2001)

    Article  Google Scholar 

  2. Anderson, R.L.: Clay swelling-A challenge in the oilfield. Earth Sci. Rev. 98, 201–216 (2010)

    Article  Google Scholar 

  3. Gu, X.: Modeling the adsorption of Cd(II), Cu(II), Ni(II), Pb(II) and Zn(II) onto montmorillonite. Geochim. Cosmochim. Acta 74, 5718–5728 (2010)

    Article  Google Scholar 

  4. Xu, Y.: Remediation of heavy metal-polluted agricultural soils using clay minerals: a review. Pedosphere 27(2), 193–204 (2017)

    Article  Google Scholar 

  5. Tachi, Y.: Diffusion and sorption of Cs+, Na+, I and HTO in compacted sodium montmorillonite as a function of porewater salinity: Integrated sorption and diffusion model. Geochim. Cosmochim. Acta 132, 75–93 (2014)

    Article  Google Scholar 

  6. Huber, F.: Radionuclide desorption kinetics on synthetic Zn/Ni-labeled montmorillonite nanoparticles. Geochim. Cosmochim. Acta 148, 426–441 (2014)

    Article  Google Scholar 

  7. Mermut, A.R.: Baseline studies of the clay minerals society source clays: chemical analyses of major elements. Clays and Clay Miner 49(5), 381–386 (2001)

    Article  Google Scholar 

  8. Tessier, D. : Etude expérimentale de l’organisation des matériaux argileux. [these], Université de Paris VII, Publication INRA Versailles, Paris, France (1984)

    Google Scholar 

  9. Cuadros, J.: Experimental kinetic study of the smectite-to-illite transformation. Geochim. Cosmochim. Acta 60, 439–453 (1996)

    Article  Google Scholar 

  10. Ferrage, E.: New insights on the distribution of interlayer water in bi-hydrated smectite from X-ray difraction profile modeling of 00 l reflections. Chem. Mater. 17, 3499–3512 (2005)

    Article  Google Scholar 

  11. Oueslati, W.: XRD investigations of hydrated homoionic montmorillonite saturated by several heavy metal cations. Desalination 271, 139–149 (2011)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Walid Oueslati .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2019 Springer Nature Switzerland AG

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Ammar, M., Oueslati, W., Ben Haj Amara, A. (2019). Mg-Exchanged Montmorillonite Undergoing External Environmental Solicitation: Crystalline Swelling Process Investigation. In: Doronzo, D., Schingaro, E., Armstrong-Altrin, J., Zoheir, B. (eds) Petrogenesis and Exploration of the Earth’s Interior. CAJG 2018. Advances in Science, Technology & Innovation. Springer, Cham. https://doi.org/10.1007/978-3-030-01575-6_44

Download citation

Publish with us

Policies and ethics