Skip to main content
SpringerLink
Log in

Application of Spectroscopic Methods in the Studies of Polysiloxanes, Cubic  Oligomeric Silsesquioxanes, and Spherosilicates Modified by Organic Functional Groups via Hydrosilylation

  • Chapter
  • First Online:
Molecular Spectroscopy—Experiment and Theory

Part of the book series: Challenges and Advances in Computational Chemistry and Physics ((COCH,volume 26))

Abstract

Organosilicon compounds whose structure is based on the stable Si–O bonds show high chemical and thermal stability. Incorporation of organic groups into their molecules results in the materials which combine the properties of the Si–O skeleton and those of organic moieties. Hydrosilylation , i.e., catalytic addition of Si–H groups to carbon–carbon double bonds, is a convenient route to prepare organofunctional silicon compounds. In this chapter, the work that has been done since the year 2000 on functionalization via hydrosilylation of polysiloxanes , cubic  oligomeric silsesquioxanes, and spherosilicates , i.e., the main classes of organosilicon compounds containing Si–O bonds, is reviewed. The emphasis is put on spectroscopic investigations of the functionalization process or its products.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 99.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 129.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 199.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Noll W (1968) Chemistry and technology of silicones. Academic Press, pp 1–9

    Google Scholar 

  2. Baney RH, Cao X (2000) Polysilsesquioxanes. In: Jones RG, Ando W, Chojnowski J (eds) Silicon-containing polymers. Kluwer Academic Publishers, pp 157–184

    Google Scholar 

  3. Kuo ACM (1999) Poly(dimethylsiloxane). In: Polymer data handbook. Oxford University Press, Inc., pp 411–435

    Google Scholar 

  4. Graiver D, Fearon G (2000) Polysiloxanes: directions of applications and perspectives. In: Jones RG, Ando W, Chojnowski J (eds) Silicon-containing polymers. Kluwer Academic Publishers, pp 233–243

    Google Scholar 

  5. Zhou Q, Yan S, Han CC, Xie P, Zhang R (2008) Promising functional materials based on ladder polysiloxanes. Adv Mater 20:2970–2976

    Article  CAS  Google Scholar 

  6. Cordes DB, Lickiss PD, Rataboul F (2010) Recent developments in the chemistry of cubic polyhedral oligosilsesquioxanes. Chem Rev 110:2081–2173

    Article  CAS  PubMed  Google Scholar 

  7. Pielichowski K, Njuguna J, Janowski B, Pielichowski J (2006) Polyhedral oligomeric silsesquioxanes (POSS)-containing nanohybrid polymers. Adv Polym Sci 201:225–296

    Article  CAS  Google Scholar 

  8. Kuo SW, Chang F-C (2011) POSS related polymer nanocomposites. Prog Polym Sci 36:1649–1696

    Article  CAS  Google Scholar 

  9. Zhang W, Müller AHE (2013) Architecture, self-assembly and properties of well-defined hybrid polymers based on polyhedral oligomeric silsesquioxane (POSS). Prog Polym Sci 38:1121–1162

    Article  CAS  Google Scholar 

  10. Marciniec B, Guliński J, Urbaniak W, Kornetka ZW (1992) Comprehensive handbook on hydrosilylation. Pergamon Press

    Google Scholar 

  11. Boutevin B, Guida-Pietrasanta F, Ratsimihety A (2000) Side group modified polysiloxanes. In: Jones RG, Ando W, Chojnowski J (ed) Silicon-containing polymers. Kluwer Academic Publishers, pp 79–112

    Google Scholar 

  12. Nyczyk A, Paluszkiewicz C, Pyda A, Hasik M (2011) Preceramic polysiloxane networks obtained by hydrosilylation of 1,3,5,7-tetravinyl-1,3,5,7-tetramethylcyclotetrasiloxane. Spectrochim Acta A 79:801–808

    Article  CAS  Google Scholar 

  13. Nyczyk A, Paluszkiewicz C, Hasik M, Cypryk M, Pospiech P (2012) Cross-linking of linear vinylpolysiloxanes by hydrosilylation—FTIR spectroscopic studies. Vib Spectrosc 59:1–8

    Article  CAS  Google Scholar 

  14. Nyczyk-Malinowska A, Wójcik-Bania M, Gumuła T, Hasik M, Cypryk M, Olejniczak Z (2014) New precursors to SiCO ceramics derived from linear poly(vinylsiloxanes) of regular chain composition. J Europ Ceram Soc 34:889–902

    Article  CAS  Google Scholar 

  15. Olejarka J, Łącz A, Olejniczak Z, Hasik M (2018) Non-porous and porous materials prepared by cross-linking of polyhydromethylsiloxane with silazane compounds. Eur Polym J 99:150–164

    Article  CAS  Google Scholar 

  16. Sommer LH, Pietrusza EW, Whitmore FC (1947) Peroxide-catalyzed addition of trichlorosilane to 1-octene. J Am Chem Soc 69:188–188

    Article  CAS  Google Scholar 

  17. Marciniec B, Maciejewski H, Pawluć P (2017) Hydrosilylation of carbon–carbon multiple bonds—application in synthesis and materials science. In: Lee VY (ed) Organosilicon compounds, vol 2. Experiment (physico-chemical studies) and applications. Elsevier, pp 169–217

    Google Scholar 

  18. Marciniec B, Maciejewski H, Pietraszuk C, Pawluć P (2009) Hydrosilylation: a comprehensive review on recent advances. Springer Science & Business Media BV

    Google Scholar 

  19. Troegel D, Stohrer J (2011) Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view. Coord Chem Rev 255:1440–1459

    Article  CAS  Google Scholar 

  20. Speier JL, Webster JA, Barnes GH (1957) The addition of silicon hydrides to olefinic double bonds. Part II. The use of group VIII metal catalysts. J Am Chem Soc 79:974–979

    Article  CAS  Google Scholar 

  21. Karstedt BD (1973) Platinum complexes of unsaturated siloxanes and platinum containing organopolysiloxanes. US 3 775 452

    Google Scholar 

  22. Smith AL (1960) Infrared spectra-structure correlations for organosilicon compounds. Spectrochim Acta 16:87–105

    Article  CAS  Google Scholar 

  23. Hao X, Jeffery JL, Wilkie JS, Meijs GF, Clayton AB, Watling JD, Ho A, Fernandez V, Acosta C, Yamamoto H, Aly MGM, Parel JM, Hughes TC (2010) Functionalised polysiloxanes as injectable, in situ curable accommodating intraocular lenses. Biomaterials 31:8153–8163

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  24. Maciejewski H, Karasiewicz J, Dutkiewicz A, Dutkiewicz M, Dopierała K, Prochaska K (2014) Synthesis and properties of polysiloxanes containing mixed functional groups. React Funct Polym 83:144–154

    Article  CAS  Google Scholar 

  25. Cancouët P, Pernin S, Hélary G, Sauvet G (2000) Functional polysiloxanes. II. Neighboring effect in the hydrosilylation of poly(hydrogenmethylsiloxane-co-dimethylsiloxane)s by allylglycidylether. J Polym Sci A 38:837–845

    Article  Google Scholar 

  26. Taylor RB, Parbhoo B, Fillmore D (1991) Nuclear magnetic resonance spectroscopy. In: Smith AL (ed) The analytical chemistry of silicones. Wiley, pp 347–419

    Google Scholar 

  27. Marsmann H (1981) 2Si-NMR spectroscopic results. In: Diehl P, Fluck E, Kosfeld R (eds) NMR basic principles and progress, vol 17. Springer

    Google Scholar 

  28. Cai G, Weber WP (2002) Synthesis and chemical modification of poly(divinylsiloxane). Polymer 43:1753–1759

    Article  CAS  Google Scholar 

  29. Boehm P, Mondeshki M, Frey H (2012) Polysiloxane-backbone block copolymers in a one-pot synthesis: a silicone platform for facile functionalization. Macromol Rapid Commun 33:1861–1867

    Article  CAS  PubMed  Google Scholar 

  30. Srividhya M, Madhavan K, Reddy BSR (2006) Synthesis of novel soluble poly(imide-siloxane)s via hydrosilylation: characterization and structure property behavior. Eur Polym J 42:2743–2754

    Article  CAS  Google Scholar 

  31. Safa KD, Bahadori A, Tofangdarzadeh S, Nasirtabrizi MH (2008) Trisyl modification of epoxy- and chloromethyl-polysiloxanes. J Iran Chem Soc 5:37–47

    Article  CAS  Google Scholar 

  32. Racles C, Cozan V (2011) Synthesis of glucose-modified siloxanes by a simplified procedure. Soft Materials 10:413–425

    Article  CAS  Google Scholar 

  33. El-Sukkary MMA, Ismail DA, Rayes SMEl, Saad MA (2013) Synthesis, characterization and surface properties of amino-glycopolysiloxane. J Ind Eng Chem 20:3342–3348

    Article  CAS  Google Scholar 

  34. Kowalewska A, Stańczyk WA (2003) Highly thermally resistant UV-curable poly(siloxane)s bearing bulky substituents. Chem Mater 15:2991–2997

    Article  CAS  Google Scholar 

  35. Rutnakornpituk M (2005) Modification of epoxy–novolac resins with polysiloxane containing nitrile functional groups: synthesis and characterization. Eur Polym J 41:1043–1052

    Article  CAS  Google Scholar 

  36. Min C, Pu Q, Yang L, Fan H (2014) Synthesis, film morphology, and performance on cotton substrates of dodecyl/piperazine functional polysiloxane. J Appl Polym Sci 131:40186

    Article  CAS  Google Scholar 

  37. Wang H, Ni T, Li G, Lu Y (2013) Conducting pseudo graft copolymers based on polyaniline and carbonyl-functionalized polysiloxanes: preparation and properties. Synth Met 177:52–59

    Article  CAS  Google Scholar 

  38. Lin F, Song M, He Z, Zhang T (2008) Synthesis and structural characterization of methacrylic acid/octadecyl acrylate-graft-poly(methylhydrosiloxane) by hydrosilylation. J Appl Polym Sci 107:3773–3780

    Article  CAS  Google Scholar 

  39. Mukbaniani O, Zaikov G, Pirckheliani N, Tatrishvili T, Meladze S (2007) Hydrosilylation and dehydrocondensation reactions of methylhydridesiloxane to acrylic and methacrylic acids. J Appl Polym Sci 103:3243–3252

    Article  CAS  Google Scholar 

  40. Pryakhina TA, Shragin DI, Kononevich YN, Vasi’ev GV, Buzin MI, Papkov VS, Muzafarov AM (2015) Synthesis, rheological, and thermal properties of polydimethylsiloxanes modified with long-chain hydrocarbon substituents with polar fragments. Russ Chem Bull Int Ed 64:605–612

    Article  CAS  Google Scholar 

  41. Ganicz T, Mizerska U, Moszner M, O’Brien M, Perry R, Stańczyk WA (2004) The effectiveness of rhodium (I), (II) and (III) complexes as catalysts in hydrosilylation of model olefin and polyether with triethoxysilane and poly(dimethylsiloxane-co-methylsiloxane). Appl Catal A 259:49–55

    Article  CAS  Google Scholar 

  42. Wang Z, Li R, Chen H, Ma F, Zhang X, Cheng Y, Gu X, Qi Z (2017) Cationic amphiphilic copolymers: synthesis, characterization, self-assembly and drug-loading capacity. Polym Int 66:1199–1205

    Article  CAS  Google Scholar 

  43. Pricop L, Hamciuc V, Marcu M, Ioanid A, Alazaroaie S (2005) Graft copolymers polydimethylsiloxane–polyethyleneoxide. Synthesis and characterization. High Perform Polym 17:303–312

    Article  CAS  Google Scholar 

  44. Chung DW, Kim TG (2007) Solvent Effect on the hydrosilylation reactions for the synthesis of polydimethylsiloxane grafted with polyoxyethylene catalyzed by Speier’s catalyst. J Ind Eng Chem 13:979–984

    CAS  Google Scholar 

  45. Chung DW, Kim TG (2007) Study on the effect of platinum catalyst for the synthesis of polydimethylsiloxane grafted with polyoxyethylene. J Ind Eng Chem 7:571–577

    Google Scholar 

  46. Chung DW, Lim JC (2009) Study on the effect of structure of polydimethylsiloxane grafted with polyethylene oxide on surface activities. Colloids Surf A 336:35–40

    Article  CAS  Google Scholar 

  47. Zhang Z, Sherlock D, West R, West R (2003) Cross-linked network polymer electrolytes based on a polysiloxane backbone with oligo(oxyethylene) side chains: synthesis and conductivity. Macromolecules 36:9176–9180

    Article  CAS  Google Scholar 

  48. Karatas Y, Kaskhedikar N, Burjanadze M, Wiemhöfer HD (2006) Synthesis of cross-linked comb polysiloxane for polymer electrolyte membranes. Macromol Chem Phys 207:419–425

    Article  CAS  Google Scholar 

  49. Kang J, Fang S (2002) Synthesis and ionic conductivity of comb-like polysiloxanes with pendant oligo(oxyethy1ene) side chains and quaternary ammoniurn groups. Polym Bull 49:127–134

    Article  CAS  Google Scholar 

  50. Mukbaniani O, Titvinidze G, Dundua A, Doroshenko M, Tatrishvili T (2008) Synthesis of polysiloxanes with pendant methoxy-substituted aromatic fragments. J Appl Polym Sci 107:2567–2571

    Article  CAS  Google Scholar 

  51. Chen G, Feng J, Qiu W, Zhao Y (2017) Eugenol-modified polysiloxanes as effective anticorrosion additives for epoxy resin coatings. RSC Adv 7:55967–55976

    Article  CAS  Google Scholar 

  52. Li X, Li Y, Ren L, Zhu K, Zhao Y, Yuan X (2017) Self-crosslinking coatings of fluorinated polysiloxanes with enhanced icephobicity. Thin Solid Films 639:113–122

    Article  CAS  Google Scholar 

  53. Indulekha K, Behera PK, Rajeev RS, Gouri C, Ninan KN (2017) Polyfluoroalkyl siloxanes with varying trifluoropropyl content: synthesis, characterization and solvent resistance studies. J Fluorine Chem 200:24–32

    Article  CAS  Google Scholar 

  54. Indulekha K, Mathew A, Rajeev RS, Ninan KN, Gouri C (2017) A facile route to fluoroalkylsiloxane polymers having resistance to corrosive acidic conditions: synthesis and characterization. Eur Polym J 97:94–103

    Article  CAS  Google Scholar 

  55. Zhan-Xiong L (2008) Preparation, characterization and antifoaming property of fluorosilicone oils with fluoroalkyloxypropyl group substitution. e-Polymers 003:1–12

    Google Scholar 

  56. Fukurawa Y, Kotera M (2002) Synthesis of fluorosilicone having highly fluorinated alkyl side chains based on the hydrosilylation of fluorinated olefins with polyhydromethylsiloxane. J Polym Sci Part A Polym Chem 40:3120–3128

    Article  CAS  Google Scholar 

  57. Boutevin B, Guida-Pietrasanta F, Ratsimihety A (2000) Synthesis of photocrosslinkable fluorinated polydimethylsiloxanes: direct introduction of acrylic pendant groups via hydrosilylation. J Polym Sci A 38:3722–3728

    Article  CAS  Google Scholar 

  58. Colomines G, Andre S, Andrieu X, Rousseau A, Boutevin B (2003) Synthesis and characterization of ultraviolet-curable fluorinated polydimethylsiloxanes as ultraviolet-transparent coatings for optical fiber gratings. J Appl Polym Sci 90:2021–2026

    Article  CAS  Google Scholar 

  59. Snyder JF, Hutchison JC, Ratner MA, Shriver DF (2003) Synthesis of comb polysiloxane polyelectrolytes containing oligoether and perfluoroether side chains. Chem Matter 15:4223–4230

    Article  CAS  Google Scholar 

  60. Liu H, Fu B, Li Y, Shang Q, Xiao G (2013) Antigraffiti polyurethane coating containing fluorocarbon side chains grafted polymethylsiloxane. J Coat Technol Res 10:361–369

    Article  CAS  Google Scholar 

  61. Wang Y, Du X, Li Y, Long Y, Qiu D, Tai H, Tang X, Jiang Y (2013) A simple route to functionalize siloxane polymers for DMMP sensing. J Appl Polym Sci 130:4516–4520

    CAS  Google Scholar 

  62. Huang J, Jiang Y, Du X, Bi J (2010) A new siloxane polymer for chemical vapor sensor. Sens Actuators B 146:388–394

    Article  CAS  Google Scholar 

  63. El-Ashgar NM, El-Nahhal IM, Chehimi MM, Babonneau F, Livage J (2010) Extraction of Co, Ni, Cu, Zn and Cd ions using 2-aminophenylaminopropylpolysiloxane. Environ Chem Lett 8:311–316

    Article  CAS  Google Scholar 

  64. Zawartka W, Pośpiech P, Cypryk M, Trzeciak AM (2015) Palladium supported on aminopropyl-functionalized polymethylsiloxane microspheres: simple and effective catalyst for the Suzuki-Miyaura C–C coupling. J Mol Catal A Chem 407:230–235

    Article  CAS  Google Scholar 

  65. Zawartka W, Pośpiech P, Cypryk M, Trzeciak AM (2016) Carbonylative Suzuki-Miyaura coupling catalyzed by palladium supported on aminopropyl polymethylsiloxane microspheres under atmospheric pressure of CO. J Mol Catal A Chem 417:76–80

    Article  CAS  Google Scholar 

  66. Wang Z, Beletskiy EV, Sungsik L, Hou X, Wu Y, Li T, Kung MC, Kung HH (2015) Amine-functionalized siloxane oligomer facilitated synthesis of subnanometer colloidal Au particles. J Mater Chem A 3:1743–1751

    Article  CAS  Google Scholar 

  67. Sauvet G, Fortuniak W, Kazmierski K, Chojnowski J (2003) Amphiphilic block and statistical siloxane copolymers with antimicrobial activity. J Polym Sci A 41:2939–2948

    Article  CAS  Google Scholar 

  68. Brook MA (2000) Silicon in organic, organometallic, and polymer chemistry. Wiley, pp 404–406

    Google Scholar 

  69. Binet C, Dumont M, Fitremann J, Gineste S, Laurent E, Marty JD, Mauzac M, Mingotaud AF, Moukarzel W, Palaprat G, Zadoina L (2008) Hydrosilylation of polymethylhydrogenosiloxanes in the presence of functional molecules such as amines, esters or alcohols. In: Ganachaud F, Boileau S, Boury B (eds) Silicon based polymers. Springer, Dordrecht, pp 135–150

    Chapter  Google Scholar 

  70. Kanjilal B, Noshadi I, McCutcheon JR, Asandei AD, Parnas RS (2015) Allylcyclohexylamine functionalized siloxane polymer and its phase separated blend as pervaporation membranes for 1,3-propanediol enrichment from binary aqueous mixtures. J Membr Sci 486:59–70

    Article  CAS  Google Scholar 

  71. Guerra-Contreras A, Villegas A, Ramirez-Oliva E, Cervantes J (2015) Characterization and study of properties in a polar solvent of a functionalized and quaternized poly(dimethylsiloxane-co-methyl-hydridosiloxane). Silicon 9:525–533

    Article  CAS  Google Scholar 

  72. Lei Y, Zhou S, Dong C, Zhang A, Lin Y (2018) PDMS tri-block copolymers bearing quaternary ammonium salts for epidermal antimicrobial agents: synthesis, surface adsorption and non-skin-penetration. React Funct Polym 124:20–28

    Article  CAS  Google Scholar 

  73. Zhao J, An QF, Li XQ, Huang LX, Xu X (2015) A comblike polysiloxane with pendant quaternary ammonium polyether groups: its synthesis, physical properties and antibacterial performance. J Polym Res 22:174

    Article  CAS  Google Scholar 

  74. Hou Z, Kan C (2015) Polysiloxanes with quaternary ammonium groups for SPPO aqueous emulsions. J Surfact Deterg 18:517–522

    Article  CAS  Google Scholar 

  75. Grazulevicius JV, Strohriegl P, Pielichowski J, Pielichowski K (2003) Carbazole-containing polymers: synthesis, properties and applications. Prog Polym Sci 28:1297–1353

    Article  CAS  Google Scholar 

  76. Claessens CG, Hahn U, Torres T (2008) Phthalocyanines: from outstanding electronic properties to emerging applications. Chem Rec 8:75–97

    Article  CAS  PubMed  Google Scholar 

  77. Nordin NH, Othman N, Ahmad Z (2013) Synthesis and thermal stability of cross-linked carbazole-substituted poly(dimethylsiloxane) for LED encapsulation. Adv Mater Res 747:733–736

    Article  CAS  Google Scholar 

  78. Nordin NH, Ramli MR, Othman N, Ahmad Z (2015) Synthesis of carbazole-substituted poly(dimethylsiloxane) and its improved refractive index. J Appl Polym Sci 41654:1–9

    Google Scholar 

  79. Hua J, Li Z, Long K, Qin J, Li S, Ye C, Lu Z (2005) Synthesis and second order nonlinear optical properties of multifunctional polysiloxanes with sulfonyl based chromophores. J Polym Sci A 43:1317–1324

    Article  CAS  Google Scholar 

  80. Li Z, Li J, Qin J, Qin J, Ye C (2005) Synthesis and characterization of polysiloxanes containing carbazolyl and sulfonyl-indole based chromophore as side chains. Polymer 46:363–368

    Article  CAS  Google Scholar 

  81. Moon IK, Oh JW, Kim N (2008) Synthesis and optical properties of benzocarbazole-substituted polysiloxanes for polymeric photorefractive materials. J Photochem Photobiol A 194:351–355

    Article  CAS  Google Scholar 

  82. Ganicz T, Makowski T, Stanczyk WA, Tracz A (2012) Side chain polysiloxanes with phthalocyanine moieties. Express Polym Lett 6:373–382

    Article  CAS  Google Scholar 

  83. Mefteh WB, Touzi H, Chevalier Y, Ouada HB, Othmane A, Kalfat R, Jaffrezic-Renault N (2014) Comparison of polysiloxane films substituted by undecenyl-cyclam and by naphthyl-cyclam for the design of ISFET devices sensitive to Fe3+ ions. Sens Actuators B 204:723–733

    Article  CAS  Google Scholar 

  84. Manson BW, Morrison JJ, Coupar I, Jaffrès PA, Morris RE (2001) Synthesis of aldehyde functionalised polyhedral oligomeric silsesquioxane. J Chem Soc Dalton Trans: 1123–1127

    Google Scholar 

  85. Herrero M, Alonso B, Losada J, Garcıaě-Armada P, Casado CM (2012) Ferrocenyl dendrimers based on octasilsesquioxane cores. Organometallics 31:6344–6350

    Article  CAS  Google Scholar 

  86. Liu Y, Zheng S, Nie K (2005) Epoxy nanocomposites with octa(propylglycidyl ether) polyhedral oligomeric silsesquioxane. Polymer 46:12016–12025

    Article  CAS  Google Scholar 

  87. Zeng K, Liu Y, Zheng S (2008) Poly(ethylene imine) hybrids containing polyhedral oligomeric silsesquioxanes: Preparation, structure and properties. Eur Polym J 44:3946–3956

    Article  CAS  Google Scholar 

  88. Szubert K, Marciniec B, Dutkiewicz M, Potrzebowski MJ, Maciejewski H (2014) Functionalization of spherosilicates via hydrosilylation catalyzed by well-defined rhodium siloxide complexes immobilized on silica. J Mol Catal A: Chem 391:150–157

    Article  CAS  Google Scholar 

  89. Soh MS, Yap AUJ, Sellinger A (2007) Methacrylate and epoxy functionalized nanocomposites based on silsesquioxane cores for use in dental applications. Eur Polym J 43:315–327

    Article  CAS  Google Scholar 

  90. Kastner J, Lorret O, Rank A, Schwarzinger C, Dittert B, Mühlberger M (2015) Nanocontact printing stamp material via bi-functionalization of polyhedral oligomeric silsesquioxane. Eur Polym J 65:221–231

    Article  CAS  Google Scholar 

  91. Zhang C, Laine RM (2000) Hydrosilylation of Allyl Alcohol with [HSiMe2OSiO1.5]8: octa(3-hydroxypropyldimethylsiloxy)octasilsesquioxane and its octamethacrylate derivative as potential precursors to hybrid nanocomposites. J Am Chem Soc 122:6979–6988

    Article  CAS  Google Scholar 

  92. Kim KM, Inakura T, Chujo Y (2001) Organic-inorganic polymer hybrids using octasilsesquioxanes with hydroxyl groups. Polym Bull 46:351–356

    Article  CAS  Google Scholar 

  93. Kuo SW, Lin HC, Huang WJ, Huang CF, Chang FC (2006) Hydrogen bonding interactions and miscibility between phenolic resin and octa(acetoxystyryl) polyhedral oligomeric silsesquioxane (AS-POSS) nanocomposites. J Pol Sci Pol Phys 44:673–686

    Article  CAS  Google Scholar 

  94. Lin HC, Kuo SW, Huang CF, Chang FC (2006) Thermal and surface properties of phenolic nanocomposites containing octaphenol polyhedral oligomeric silsesquioxane. Macromol Rapid Commun 27:537–541

    Article  CAS  Google Scholar 

  95. Huang KW, Tsai LW, Kuo SW (2009) Influence of octakis-functionalized polyhedral oligomeric silsesquioxanes on the physical properties of their polymer nanocomposites. Polymer 50:4876–4887

    Article  CAS  Google Scholar 

  96. Lu YS, Kuo SW (2014) Functional groups on POSS nanoparticles influence the self-assembled structures of diblock copolymer composites. RSC Adv 4:34849–34859

    Article  CAS  Google Scholar 

  97. Lu YS, Yu CY, Ln YC, Kuo SW (2016) Hydrogen bonding strength of diblock copolymers affects the self-assembled structures with octa-functionalized phenol POSS nanoparticles. Soft Matter 12:2288–2300

    Article  CAS  PubMed  Google Scholar 

  98. Yu CY, Kuo SW (2018) Phenolic functionality of polyhedral oligomeric silsesquioxane nanoparticles affects self-assembly supramolecular structures of block copolymer hybrid complexes. Ind Eng Chem Res 57:2546–2559

    Article  CAS  Google Scholar 

  99. Sheen YC, Lu CH, Huang CF, Kuo SW, Chang FC (2008) Synthesis and characterization of amorphous octakis-functionalized polyhedral oligomeric silsesquioxanes for polymer nanocomposites. Polymer 49:4017–4024

    Article  CAS  Google Scholar 

  100. Igarashi M, Kobayashi T, Sato K, Ando W, Matsumoto T, Shimada S, Hara M, Uchida H (2013) Selective hydrosilylation of allyl esters with octahydridosilsesquioxane. J Organomet Chem 725:54–59

    Article  CAS  Google Scholar 

  101. Kim Y, Roh J, Kim JH, Kang CM, In-NK Jun B, Lee C, Hwang DH (2013) Photocurable propyl-cinnamate-functionalized polyhedral oligomeric silsesquioxane as a gate dielectric for organic thin film transistors. Org Electron 14:2315–2323

    Article  CAS  Google Scholar 

  102. Zhang X, Wang C, Fang S, Sun J, Li C, Hu Y (2013) Synthesis and characterization of well-defined star PLLA with a POSS core and their microspheres for controlled release. Colloid Polym Sci 291:789–803

    Article  CAS  Google Scholar 

  103. Mya KY, Li X, Chen L, Ni X, Li J, He C (2005) Core-corona structure of cubic silsesquioxane-poly(ethylene oxide) in aqueous solution: fluorescence, light scattering, and TEM studies. J Phys Chem B 109:9455–9462

    Article  CAS  PubMed  Google Scholar 

  104. Markovic E, Ginic-Markovic M, Clarke S, Matisons J, Hussain M, Simon GP (2007) Poly(ethylene glycol)-octafunctionalized polyhedral oligomeric silsesquioxane: synthesis and thermal analysis. Macromolecules 40:2694–2701

    Article  CAS  Google Scholar 

  105. Pozza GME, Crotty S, Rawiso M, Schubert US, Lutz PJ (2015) Molecular and structural characterization of hybrid poly(ethylene oxide)—polyhedral oligomeric silesquioxanes star-shaped macromolecules. J Phys Chem B 119:1669–1680

    Article  CAS  PubMed  Google Scholar 

  106. Dutkiewicz M, Maciejewski H, Marciniec B, Karasiewicz J (2011) New fluorocarbofunctional spherosilicates: synthesis and characterization. Organometallics 30:2149–2153

    Article  CAS  Google Scholar 

  107. Wang X, Ye Q, Song J, Cho CM, Heab C, Xu J (2015) Fluorinated polyhedral oligomeric silsesquioxanes. RSC Adv 5:4547–4553

    Article  CAS  Google Scholar 

  108. Majumdar P, Lee E, Gubbins N, Stafslien SJ, Daniels J, Thorson CJ, Chisholm BJ (2009) Synthesis and antimicrobial activity of quaternary ammonium functionalized POSS (Q-POSS) and polysiloxane coating containing Q-POSS. Polymer 50:1124–1133

    Article  CAS  Google Scholar 

  109. Majumdar P, He J, Lee E, Kallam A, Gubbins N, Stafslien SJ, Daniels J, Chisholm BJ (2010) Antimicrobial activity of polysiloxane coatings containing quaternary ammonium-functionalized polyhedral oligomeric silsesquioxane. J Coat Technol Res 7(4):455–467

    Article  CAS  Google Scholar 

  110. Su X, Guang S, Xu H, Liu X, Wang X, Deng Y, Wang P (2009) Controllable preparation and optical limiting properties of POSS-based functional hybrid composites with different molecular architectures. Macromolecules 42:899–8976

    Article  CAS  Google Scholar 

  111. Białecka-Florjańczyk E, Sołtysiak JT (2011) Synthesis and characterization of liquid crystalline silsesquioxanes containing azobenzene groups. Mol Cryst Liq Cryst Sci Technol 548:28–36

    Article  CAS  Google Scholar 

  112. Ledin PA, Tkachenko I, Xu W, Choi I, Shevchenko VV, Tsukruk VV (2014) Star-shaped molecules with polyhedral oligomeric silsesquioxane core and azobenzene dye arms. Langmuir 30:8856–8865

    Article  CAS  PubMed  Google Scholar 

  113. Miniewicz A, Girones J, Karpinski P, Mossety-Leszczak B, Galina H, Dutkiewicz M (2014) Photochromic and nonlinear optical properties of azo-functionalized POSS nanoparticles dispersed in nematic liquid crystals. J Mater Chem C 2:432–440

    Article  CAS  Google Scholar 

  114. Imae I, Kawakami Y (2005) Development of a novel POSS-based material having carbazole moiety. In: Proceedings of SPIE, vol 5937

    Google Scholar 

  115. Markovic E, Nguyen K, Clarke S, Constantopoulos K, Matisons J, Simon GP (2013) Synthesis of POSS-polyurethane hybrids using octakis(m-isoprenyl-α,α′-dimethylbenzylisocyanato dimethylsiloxy) octasilsesquioxane (Q8M8 TMI) as a crosslinking agent. J Polym Sci A 51:5038–5045

    Article  CAS  Google Scholar 

  116. Schäfer S, Kickelbick G (2017) Simple and high yield access to octafunctional azido, amine and urea group bearing cubic spherosilicates. Dalton Trans 46:221–226

    Article  CAS  Google Scholar 

  117. Hu WH, Huang KW, Chiou C, Kuo SW (2012) Complementary multiple hydrogen bonding interactions induce the self-assembly of supramolecular structures from heteronucleobase-functionalized benzoxazine and polyhedral oligomeric silsesquioxane nanoparticles. Macromolecules 45:9020–9028

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Materials Science and Ceramics, AGH University of Science and Technology, 30 Mickiewicza Av., 30-059, Krakow, Poland

    Aleksandra Chechelska-Noworyta, Jan Mrówka, Maria Owińska & Magdalena Hasik

Authors
  1. Aleksandra Chechelska-Noworyta
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jan Mrówka
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Maria Owińska
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Magdalena Hasik
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Magdalena Hasik .

Editor information

Editors and Affiliations

  1. Faculty of Materials Science and Ceramics, AGH University of Science and Technology, Kraków, Poland

    Andrzej Koleżyński

  2. Faculty of Materials Science and Ceramics, AGH University of Science and Technology, Kraków, Poland

    Magdalena Król

Rights and permissions

Reprints and permissions

Copyright information

© 2019 Springer Nature Switzerland AG

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Chechelska-Noworyta, A., Mrówka, J., Owińska, M., Hasik, M. (2019). Application of Spectroscopic Methods in the Studies of Polysiloxanes, Cubic  Oligomeric Silsesquioxanes, and Spherosilicates Modified by Organic Functional Groups via Hydrosilylation. In: Koleżyński, A., Król, M. (eds) Molecular Spectroscopy—Experiment and Theory. Challenges and Advances in Computational Chemistry and Physics, vol 26. Springer, Cham. https://doi.org/10.1007/978-3-030-01355-4_12

Download citation

Publish with us

Policies and ethics

Search

Navigation