Abstract
Biodiesel is a renewable fuel, produced from waste cooking oils, animal fats, vegetable and algae oils. Its use is intended to replace diesel in conventional diesel engines, causing lower polluting emissions. To produce biodiesel, certain details must be carefully considered, namely feedstock composition, reaction parameters, process conditions, process equipment, purification processes, analysis of biodiesel properties, troubleshooting and storage. In what concerns feedstock composition, parameters such as acidity, insolubles, moisture, phospholipids, sulphur, polymerized triglycerides, impurities, etc., must be determined to decide about the pretreatment steps (washing, degumming, filtration, bleaching, deodorization, among others) to be implemented, and the need for esterification prior to transesterification. In what concerns the selection of process equipment some questions arise, namely the materials, heating methods and thermal insulation to use, alternatives to enhance the reaction, need for neutralization and process control system. The purification process includes biodiesel purification, methanol recovery and glycerine valorisation. The excess methanol must be recovered from biodiesel and glycerine by distillation and reused in the process while glycerine can be further purified and sold for application from the chemical to the pharmaceutical industry. The quality of biodiesel must be certified by the analyses performed according to the standards (e.g. EN 14214, ASTM D6751). Troubleshooting is needed in biodiesel production during start-up and under steady production of a facility; problems may arise regarding quality and appearance of biodiesel, reaction conditions, methanol removal, stirring in reactors, glycerine and biodiesel separation, as well as excess of water and other feedstock impurities. Biodiesel can be stored for up to 6 months; its storage poses challenges concerning degradation by contact with air and light, which cause oxidation. Some additives could extend the lifespan of biodiesel by increasing oxidation stability; other technique is the fractionation to remove the undesired fatty acid methyl ester (FAME).
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Abbreviations
- ACEA:
-
European Automobile Manufacturers’ Association
- ASTM:
-
American Society for Testing and Materials
- BXX:
-
XX% (v/v) Biodiesel
- CO2:
-
Carbon Dioxide
- CO:
-
Carbon Monoxide
- DIN:
-
German Institute for Standardization
- EN:
-
European Normalization
- EU:
-
European Union
- FAME:
-
Fatty Acid Methyl Ester
- FFA:
-
Free Fatty Acid
- HC:
-
Hydrocarbon
- HFRR:
-
High-Frequency Reciprocating Rig
- ISO:
-
International Organization for Standardization
- NaOH:
-
Sodium Hydroxide
- NOx:
-
Nitrogen Oxides
- RME:
-
Rapeseed Oil Methyl Ester
- SO2:
-
Sulphur Dioxide
References
ACEA (2014) ACEA position concerning diesel that might contain more than 7% FAME. www.acea.be/uploads/publications/140422_ACEA_position_on_B7_diesel.pdf. Accessed 28 Mar 2017
Amelio A, Loise L, Azhandeh R, Darvishmanesh S, Calabró V, Degrève J, Luis P, Van der Bruggen B (2016) Purification of biodiesel using a membrane contactor: liquid–liquid extraction. Fuel Process Technol 142:352–360
ASTM D6751 (2008) Standard specification for biodiesel fuel blend stock (B100) for middle distillate fuels
ASTM D975 (2008) Standard specification for diesel fuel oils
Atadashi IM (2015) Purification of crude biodiesel using dry washing and membrane technologies. Alexandria Eng J 54(4):1265–1272
Atadashi IM, Aroua MK Abdul, Aziz AR, Sulaiman NMN (2011a) Refining technologies for the purification of crude biodiesel. Appl Energy 88(12):4239–4251
Atadashi IM, Aroua MK, Abdul Aziz A (2011b) Biodiesel separation and purification: a review. Renew Energy 36(2):437–443
Atadashi IM, Aroua MK, Abdul Aziz AR, Sulaiman NMN (2011c) Membrane biodiesel production and refining technology: a critical review. Renew Sustain Energy Rev 15(9):5051–5062
Bakeas E, Karavalakis G, Stournas S (2011) Biodiesel emissions profile in modern diesel vehicles. Part 1: Effect of biodiesel origin on the criteria emissions. Sci Total Environ 409(9):1670–1676
Baroutian S, Aroua MK, Raman AAA, Sulaiman NMN (2011) A packed bed membrane reactor for production of biodiesel using activated carbon supported catalyst. Biores Technol 102(2):1095–1102
Baybutt P (2015) A critique of the hazard and operability (HAZOP) study. J Loss Prev Process Ind 33:52–58
Ben-Iwo J, Manovic V, Longhurst P (2016) Biomass resources and biofuels potential for the production of transportation fuels in Nigeria. Renew Sustain Energy Rev 63:172–192
Berrios M, Skelton RL (2008) Comparison of purification methods for biodiesel. Chem Eng J 144(3):459–465
Bhardwaj M, Gupta P, Kumar N (2014) Compatibility of metals and elastomers in biodiesel: a review. Int J Res 1(7):376–391
Biodiesel Emissions. National Biodiesel Board (nd). https://www.me.utexas.edu/~challengex/family/emissions.pdf. Accessed 31 July 2018
Biodiesel Fact Sheet (nd) Biodiesel Co-ops. http://greenwayrides.com/site/assets/pdfs/Biodiesel-fact-sheet.pdf. Accessed 31 July 2018
Caetano NS, Caldeira D, Martins AA, Mata TM (2017) Valorisation of spent coffee grounds: production of biodiesel via enzymatic catalysis with ethanol and a co-solvent. Waste Biomass Valoriz 8(6):1981–1994
Caetano NS, Silva VFM, Mata TM (2012) Valorization of coffee grounds for biodiesel production. Chem Eng Trans 26:267–272
Cheng L-H, Yen S-Y, Su L-S, Chen J (2010) Study on membrane reactors for biodiesel production by phase behaviors of canola oil methanolysis in batch reactors. Biores Technol 101(17):6663–6668
Datta A, Mandal BK (2014) Use of Jatropha biodiesel as a future sustainable fuel. Energy Technol Policy 1:8–14
Demirbas A (2005) Biodiesel production from vegetable oils via catalytic and non-catalytic supercritical methanol transesterification methods. Prog Energy Combust Sci 31(5–6):466–487
Demirbas A (2007) Biofuels. Springer. ISBN 978-1-84628-995-8
Demirbas A (2008a) Relationships derived from physical properties of vegetable oil and biodiesel fuels. Fuel 87(8–9):1743–1748
Demirbas A (2008b) Biodiesel: a realistic fuel for alternative diesel engines. Springer, London
Demirbas A (2008c) Biofuels sources, biofuel policy, biofuel economy and global biofuel projections. Energy Convers Manag 49(8):2106–2116
Demirbas A (2009) Progress and recent trends in biodiesel fuels. Energy Convers Manag 50(1):14–34
DIN 51606 (1997) Liquid fuels—diesel fuel of fatty acid methyl ester (FAME)—specifications. German Institute for Standardization
Dincer K (2008) Lower emissions from biodiesel combustion. Energy Sources Part A: Recovery Util Environ Eff 30(10):963–968
Dubé MA, Tremblay AY, Liu J (2007) Biodiesel production using a membrane reactor. Biores Technol 98:639–647
Dunn RO (2011) Improving the cold flow properties of biodiesel by fractionation. INTECH Open Access Publisher
Dupont (2017) https://dupont.secure.force.com/CRG_TlargiGuide. Accessed 15 Apr 2017
Ejikeme PM, Anyaogu ID, Ejikeme CL, Nwafor NP, Egbuonu CAC, Ukogu K, Ibemesi JA (2010) Catalysis in biodiesel production by transesterification processes—an insight. E-J Chem 7(4):1120–1132
EN 14214 (2012) Liquid petroleum products—fatty acid methyl esters (FAME) for use in diesel engines and heating applications—requirements and test methods. European Committee for Standardization
EN 590 (2009) Automotive fuels—diesel—requirements and test methods. European Committee for Standardization
European Biodiesel Board (2017) Statistics—the EU biodiesel industry. http://www.ebb-eu.org/stats.php. Accessed 9 Jan 2017
Garlapati VK, Shankar U, Budhiraja A (2016) Bioconversion technologies of crude glycerol to value added industrial products. Biotechnol Rep 9:9–14
Ghaly AE, Dave D, Brooks MS, Budge S (2010) Production of biodiesel by enzymatic transesterification: a review. Am J Biochem Biotechnol 6(2):54–76
Gude VG, Patil P, Martinez-Guerra E, Deng S, Nirmalakhandan N (2013) Microwave energy potential for biodiesel production. Sustain Chem Process 1:5
Hajjari M, Tabatabaei M, Aghbashlo M, Ghanavati H (2017) A review on the prospects of sustainable biodiesel production: a global scenario with an emphasis on waste-oil biodiesel utilization. Renew Sustain Energy Rev 72:445–464
Haseeb A, Fazal M, Jahirul M, Masjuki H (2011) Compatibility of automotive materials in biodiesel: a review. Fuel 90(3):922–931
Jeschke B (2009) Plant oil biofuel: rationale, production and application. In: Soetaert W, Vandamme EJ (eds) Biofuels. Wiley, Chichester, UK
Jung B, Batal AB (2011) Nutritional and feeding value of crude glycerin for poultry. 2. Evaluation of feeding crude glycerin to broilers. J Appl Poult Res 20:514–527
Karmakar A, Karmakar S, Mukherjee S (2010) Properties of various plants and animals feedstocks for biodiesel production. Biores Technol 101(19):7201–7210
Kletz TA (1971) Hazard analysis—a quantitative approach to safety. In: Major loss prevention in the process industries, Symposium series No. 34. Institution of Chemical Engineers, Rugby, UK, pp 75–81
Knothe G, Dunn RO, Bagby MO (1997) Biodiesel: the use of vegetable oils and their derivatives as alternative diesel fuels. ACS Symp Ser 666:172–208
Kombe GG, Temu AK, Rajabu HM, Mrema GD, Kansedo J, Lee KT (2013) Pre-treatment of high free fatty acids oils by chemical re-esterification for biodiesel production—a review. Adv Chem Eng Sci 3:242–247
Kwon EE, Yi H, Jeon YJ (2013) Transforming rapeseed oil into fatty acid ethyl ester (FAEE) via the noncatalytic transesterification reaction. AIChE J 59:1468–1471
Lapuerta M, Armas O, Rodríguez-Fernández J (2008) Effect of biodiesel fuels on diesel engine emissions. Prog Energy Combust Sci 34(2):198–223
Lawley HG (1974) Operability studies and hazard analysis. Chem Eng Prog 70(4):45–56
Liu CH, Huang CC, Wang Y-W, Lee D-J, Chang J-S (2012) Biodiesel production by enzymatic transesterification catalyzed by Burkholderia lipase immobilized on hydrophobic magnetic particles. Appl Energy 100:41–46
Mahmudul HM, Hagos FY, Mamat R, Adam AA, Ishak WFW, Alenezi R (2017) Production, characterization and performance of biodiesel as an alternative fuel in diesel engines—a review. Renew Sustain Energy Rev 72:497–509
Mata T, Mendes A, Caetano N, Martins AA (2014) Properties and sustainability of biodiesel from animal fats and fish oil. Chem Eng Trans 38:175–180
Mata TM, Martins AA, Caetano NS (2010) Microalgae for biodiesel production and other applications: a review. Renew Sustain Energy Rev 14(1):217–232
Mesiano AJ, Beckman EJ, Russell AJ (1999) Supercritical biocatalysis. Chem Rev 99(2):623–634
Miri SM, Mousavi Seyedim SR, Ghobadian B (2017) Effects of biodiesel fuel synthesized from non-edible rapeseed oil on performance and emission variables of diesel engines. J Clean Prod 142(4):3798–3808
Mittelbach M (2009) Process technologies for biodiesel production. In: Soetaert W, Vandamme EJ (eds) Biofuels. Wiley, Chichester, UK
NBB (National Biodiesel Board) (2018). Emissions calculator. http://biodiesel.org/using-biodiesel/handling-use/emissions-calculator. Accessed 31 July 2018
Pulz O (2007) Evaluation of GreenFuel’s 3D matrix algae growth engineering scale unit. Performance summary report. IGV Institut für Getreideverarbeitung GmbH, Germany
Pushparaj T, Ramabalan S (2013) Green fuel design for diesel engine, combustion, performance and emission analysis. Procedia Eng 64:701–709
Putrasari Y, Lim O (2017) A study on combustion and emission of GCI engines fueled with gasoline-biodiesel blends. Fuel 189:141–154
Rajagopal D, Zilberman D (2007) Review of environmental, economic and policy aspects of biofuels. Policy Research Working Paper; No. 4341. World Bank, Washington, DC. © World Bank. https://openknowledge.worldbank.org/handle/10986/7337. Accessed 20 Mar 2017
Rausand M, Høyland A (2004) System reliability theory: models, statistical methods, and applications, 2nd edn. Wiley, Hoboken, New Jersey
Show PL, Tang MSY, Nagarajan D, Ling TC, Ooi CW, Chang JS (2017) A holistic approach to managing microalgae for biofuel applications. Int J Mol Sci 18(1):215–248
Soetaert W, Vandamme EJ (2009) Biofuels in perspective. In: Soetaert W, Vandamme EJ (eds) Biofuels. Wiley, Chichester, UK
Stojković IJ, Stamenković OS, Povrenović DS, Veljković VB (2014) Purification technologies for crude biodiesel obtained by alkali-catalyzed transesterification. Renew Sustain Energy Rev 32:1–15
Tabatabaei M, Karimi K, Horváth IS, Kumar R (2015) Recent trends in biodiesel production. Biofuel Res J 7:258–267
Tickell J, Roman K (ed), Tickell K (1999) From the fryer to the fuel tank: the complete guide to using vegetable oil as an alternative fuel. Green Teach Publishing, Florida
Tran D-T, Chang J-S, Lee D-J (2017) Recent insights into continuous-flow biodiesel production via catalytic and non-catalytic transesterification processes. Appl Energy 185(1):376–409
Upham P, Thornley P, Tomei J, Boucher P (2009) Substitutable biodiesel feedstocks for the UK: a review of sustainability issues with reference to the UK RTFO. J Clean Prod 17(S1):S37–S45
Van Gerpen J (2005) Biodiesel processing and production. Fuel Proc Technol 86(10):1097–1107
Veljković VB, Banković-Ilić IB, Stamenković OS (2015) Purification of crude biodiesel obtained by heterogeneously-catalyzed transesterification. Renew Sustain Energy Rev 49:500–516
Vijayaraj K, Sathiyagnanam AP (2016) Experimental investigation of a diesel engine with methyl ester of mango seed oil and diesel blends. Alexandria Eng J 55(1):215–221
Volkswagen (2010) Biodiesel statement. www.volkswagen.co.uk/assets/common/pdf/general/biodiesel.pdf. Accessed 28 Mar 2017
Vyas AP, Verma JL, Subrahmanyam N (2010) A review on FAME production processes. Fuel 89(1):1–9
Wang W, Lyons D, Clark N, Gautam M, Norton P (2000) Emissions from nine heavy trucks fueled by diesel and biodiesel blend without engine modification. Environ Sci Technol 34(6):933–939
Xu W, Lijing G, Guomin X (2015) Biodiesel production optimization using monolithic catalyst in a fixed-bed membrane reactor. Fuel 159:484–490
Xue J, Grift T, Hansen A (2011) Effect of biodiesel on engine performances and emissions. Renew Sustain Energy Rev 15(2):1098–1116
Zittelli GC, Rodolfi L, Bassi N, Biondi N, Tredici MR (2013) Photobioreactors for microalgal biofuel production. Algae for biofuels and energy. Springer, Berlin, pp 115–131
Acknowledgements
This work was partially supported by the project POCI-01-0145-FEDER-006939 (Laboratory for Process Engineering, Environment, Biotechnology and Energy—UID/EQU/00511/2013) funded by the European Regional Development Fund (ERDF), through COMPETE2020—Programa Operacional Competitividade e Internacionalização (POCI) and by the national funds, through FCT—Fundação para a Ciência e a Tecnologia.
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Caetano, N.S., Ribeiro, V., Ribeiro, L., Baptista, A., Monteiro, J. (2019). Biodiesel Production Systems: Operation, Process Control and Troubleshooting. In: Tabatabaei, M., Aghbashlo, M. (eds) Biodiesel. Biofuel and Biorefinery Technologies, vol 8. Springer, Cham. https://doi.org/10.1007/978-3-030-00985-4_3
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