Abstract
Germanosilicate glasses of compositions (mol%): \((100 - {\text{x)(33Na}}_{2} {\text{O}} \cdot 6 7 {\text{SiO}}_{2} ) \cdot {\text{xGeO}}_{2} ,\) where x = 20, 25, 30, 35 and 40 were studied using Raman and IR spectroscopy. Structural units existing in glasses were determined. The transition of silicon-containing anionic sheet structures to three-dimensional network with the formation of Si–O–Si bridge atoms was observed when germanium oxide was added to sodium disilicate.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Anfilogov VN., Bykov VN., Osipov AA. Silicatnie rasplavy, M.: Nauka; 2005. [Anfilogov VN., Bykov VN., Osipov AA. Silicate melts. M.: Nauka; 2005. (In Russ.)]
Bykov VN., Anfilogov VN., Osipov AA. Spectroskopiya i structura silicatnih rasplavov i stekol. Miass: Institute of mineralogy, UrB RAS; 2001. [Bykov VN., Anfilogov VN., Osipov AA. Spectroscopy and structure of silicate melts and glasses. Miass: Institute of mineralogy, UrB RAS; 2001. (In Russ.)]
Bykov VN., Ivanova TN., Koroleva ON. Raman spectroscopy of borosilicate and germanate-silicate glasses and melts. Russ. Metall. 2011;8:719–722. https://doi.org/10.1134/S0036029511080040
Cao W., Huang F., Ye R., Cai M., Lei R., Zhang J., Xu S., Zhang X. Structural and fluorescence properties of Ho3+/Yb3+ doped germanosilicate glasses tailored by Lu2O3. J. Alloys Compd. 2018;746:540–548. https://doi.org/10.1016/j.jallcom.2018.02.325
Du LS., Peng L., Stebbins JF. Germanosilicate and alkali germanosilicate glass structure: New insights from high-resolution oxygen-17 NMR. J. Non-Cryst. Solids. 2007;353:2910–2918. https://doi.org/10.1016/j.jnoncrysol.2007.05.122
Furukawa T., White, WB. Raman spectroscopic investigation of the structure and crystallization of binary alkali germanate glasses. J. Mater. Sci. 1980;15(7):1648–1662. https://doi.org/10.1007/BF00550581
Furukawa T., White WB., Raman spectroscopic investigation of the structure of silicate glasses. IV. Alkali–silico–germanate glasses. J. Chem. Phys. 1991;95:776–784. https://doi.org/10.1063/1.461084
Henderson GS., Wang HM. Germanium coordination and the germanate anomaly. Eur. J. Mineral. 2002;14(4):733–744. https://doi.org/10.1127/0935-1221/2002/0014-0733
Ivanova TN. Structura germanatnih stekol i rasplavov po dannim kolebatelnoy spektroskopiy. Ekaterinburg: Institute of metallurgy UrB RAS; 2013. [Ivanova TN. The structure of germanate glasses and melts from the data of vibrational spectroscopy. Ekaterinburg: Institute of metallurgy UrB RAS; 2013. (In Russ.)]
Jiao K., Zhang, Z., Xu X., Lv Z., Song J., Lin C., Sun J., He M., Gies H. Synthesis and characterization of germanosilicate molecular sieves: GeO2/SiO2 ratio, H2O/TO2 ratio and temperature. Dalton Trans. 2017;46(7):2270–2280. https://doi.org/10.1039/C6DT04688F
Kamitsos EI., Yiannopoulos YD., Karakassides MA., Chryssikos, GD., Jain H. Raman and infrared structural investigation of xRb2O•(1-x)GeO2 glasses. J. Phys. Chem. 1996;100(28):11755–11765. https://doi.org/10.1021/jp960434+
Koroleva ON., Anfilogov VN., Shatskiy A., Litasov KD. Structure of Na2O–SiO2 melts as a function of composition: in situ Raman spectroscopic study. J. Non-Cryst. Solids. 2013;375:62–68. https://doi.org/10.1016/j.jnoncrysol.2013.04.060
Koroleva ON., Shtenberg MV., Khvorov PV. Vibrational spectroscopic and X-ray diffraction study of crystalline phases in the Li2O-SiO2 system. Russ. J. Inorg. Chem. 2014;59(3):255–258. https://doi.org/10.1134/S0036023614030139
Narendrudu T., Suresh S., Chinna Ram G., Veeraiah N., Krishna Rao D. Spectroscopic and structural properties of Cr3+ ions in lead niobium germanosilicate glasses. J. Lumin. 2017;183:17–25. https://doi.org/10.1016/j.jlumin.2016.11.005
Narendrudu T., Suresh S., Yusub S., Kumar AS., Rajyasree C., Rao MV., Kumar VR., Rao DK. Structural investigations of lead germanosilicate glasses doped with Nb2O5 by means of spectroscopic and dielectric studies. J. Mol. Struct. 2015;1098:181–190. https://doi.org/10.1016/j.molstruc.2015.05.051
Osaka A., Ariyoshi K., Takahashi K. Network structure of alkali germanosilicate glasses. J. Non-Cryst. Solids. 1986;83:335–343. https://doi.org/10.1016/0022-3093(86)90246-2
Potter BG Jr., Ochoa R., Chen DG., Simmons JH. Raman scattering investigation of xGeO2-(l - x)SiO2 planar waveguides. Opt. Lett. 1992;17(19):1349–1351. https://doi.org/10.1364/OL.17.001349
Santos R., Santos LF., Almeida RM., Deubener J., Wondraczek L. Crystallization of niobium germanosilicate glasses. J. Solid State Chem. 2010b;183(1):128–135. https://doi.org/10.1016/j.jssc.2009.10.031
Santos R., Santos LF., Almeida RM. Optical and spectroscopic properties of Er-doped niobium germanosilicate glasses and glass ceramics. J. Non-Cryst. Solids. 2010a;356(44-49):2677–2682. https://doi.org/10.1016/j.jnoncrysol.2010.03.036
Smets BMJ., Lommen TPA. The structure of germanosilicate glasses, studied by X-ray photoelectron spectroscopy. J. Non-Cryst. Solids. 1981;46:21–32. https://doi.org/10.1016/0022-3093(81)90071-5
Ventura M., Monteiro G., Almeida RM., Schwarz R., Santos LF. Germanosilicate glassceramics for non-linear optics. J. Mater. Sci. 2015;50(9):3477–3484. https://doi.org/10.1007/s10853-015-8908-1
Verweij H. Raman study of the structure of alkali germanosilicate glasses (I): sodium and potassium metagermanosilicate glasses. J. Non-Cryst. Solids. 1979a;33:41–53. https://doi.org/10.1016/0022-3093(79)90094-2
Verweij H. Raman study of the structure of alkali germanosilicate glasses (II) lithium, sodium and potassium digermanosilicate glasses. J. Non-Cryst. Solids. 1979b;33:55–69. https://doi.org/10.1016/0022-3093(79)90095-4
Acknowledgements
This work was financially supported by the Russian Foundation for Basic Research, projects No. 16-35-60045 and No. 18-05-00079.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2020 Springer Nature Switzerland AG
About this paper
Cite this paper
Korobatova, N.M., Shtenberg, M.V., Ivanova, T.N., Koroleva, O.N. (2020). Raman and IR Spectroscopy of Na2O–SiO2–GeO2 System. In: Votyakov, S., Kiseleva, D., Grokhovsky, V., Shchapova, Y. (eds) Minerals: Structure, Properties, Methods of Investigation. Springer Proceedings in Earth and Environmental Sciences. Springer, Cham. https://doi.org/10.1007/978-3-030-00925-0_15
Download citation
DOI: https://doi.org/10.1007/978-3-030-00925-0_15
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-00924-3
Online ISBN: 978-3-030-00925-0
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)