Abstract
The aim of this chapter is to present the important aspects of the synthesis of an integrated bio-ethanol processor plant for hydrogen production with proton exchange membrane fuel cell systems. It is based on performing a proper energy integration to determine the operating point of maximum efficiency. A large review about the different techniques for obtaining hydrogen from bio-ethanol is investigated to justify the selection of a process based on steam reforming, followed by high- and low-temperature shift reactors and preferential oxidation, coupled to a fuel cell. Applying simulation techniques with HYSYS commercial software and using its specific thermodynamic models, the performance of the complete system has been evaluated for a variety of operating conditions. These models involve mass and energy balances, chemical equilibrium and feasible heat transfer conditions. The main operating points of the variables were determined for those conditions where the endothermic nature of the reformer has a significant effect on the overall system efficiency. Then, a heuristic procedure for defining a preliminary control structure is applied via a sensitivity analysis, evaluating controllability aspects for the most critical disturbances and considering the main objectives of the process.
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References
Luyben WL, Tyreus BD, Luyben ML (1999) Plantwide process control. McGraw-Hill Professional Publishing, New York
Francesconi JA, Mussati MC, Mato RO, Aguirre PA (2007) Analysis of the energy efficiency of an integrated ethanol processor for PEM fuel cell systems. J Power Source 167(1):151–161
Aspen Technology (2006) HYSYS User Manual
Boland P Hewitt G.F, Thomas B.E.A, Guy A.R, Marsland R.H, Linnhoff B, Townsend D (1985) A user guide on process integration for the efficient use of energy. Institute of Chemical Engineers, Rugby, UK
Luyben ML, Luyben WL (1997) Essentials of process control. Chemical Engineering Series. McGraw-Hill, International Editions, New York
Pukrushpan J, Stefanopoulou A, Varigonda S, Eborn J, Haugstetter C (2006) Control-oriented model of fuel processor for hydrogen generation in fuel cell applications. Control Eng Practice 14(3):277–293
Godat J, Marechal F (2003) Optimization of a fuel cell system using process integration techniques. J Power Source 118(1–2):411–423
Vaidya P, Rodrigues A (2006) Insight into steam reforming of ethanol to produce hydrogen for fuel cells. Chem Eng J 117(1):39–49
Haryanto A, Fernando S, Murali N, Adhikari S (2005) Current status of hydrogen production techniques by steam reforming of ethanol: a review. Energy Fuels 19(5):2098–2106
Ni M, Leung D, Leung M (2007) A review on reforming bio-ethanol for hydrogen production. Int. J. Hydrogen Energy 32(15):3238–3247
Haryanto A, Fernando S, Murali N, Adhikari S (2005) Current status of hydrogen production techniques by steam reforming of ethanol: A review. Energy Fuels 19(5):2098–2106
Garcia E, Laborde M (1991) Hydrogen production by the steam reforming of ethanol: thermodynamic analysis. Int. J. Hydrogen Energy 16(5):307–312
Vasudeva P, Mitra N, Umasankar P, Dhingra S (1996) Steam reforming of ethanol for hydrogen production: thermodynamic analysis. Int. J. Hydrogen Energy 21(1):13–18
Fishtik I, Alexander A, Datta R, Geana D (2000) A thermodynamic analysis of hydrogen production by steam reforming of ethanol via response reactions. Int. J. Hydrogen Energy 25(1):439–452
Comas J, Laborde M, Amadeo N (2004) Thermodynamic analysis of hydrogen from ethanol using cao as a co2 sorbent. J. Power Source 138(1–2):61–67
Mas V, Kipreos R, Amadeo N, Laborde M (2006) Thermodynamic analysis of ethanol/water system with the stoichiometric method. Int. J. Hydrogen Energy 31(1):21–28
Cavallaro S, Freni S (1996) Ethanol steam reforming on rh/al2o3 catalysts. Energy Fuels 14(3):119–128
Galvita V, Semin G, Belyaev V, Semikolenov V, Tsiakaras P, Sobyanin V (2001) Synthesis gas production by steam reforming of ethanol. Appl Catal A 220(1–2):123–127
Auprete F, Descorme C, Duprez D (2002) Bio-ethanol catalytic steam reforming over supported metal catalysts. Catal Commun 3(6):263–267
Llorca J, Homs N, Sales J, DeLa Piscina P (2002) Efficient production of hydrogen over supported cobalt catalysts from ethanol steam reforming. J Catal 209(2):306–317
Cavallaro S, Chiodo V, Freni D, Mondello N, Frusteri F (2003) Performance of rh/al2o3 catalyst in the steam reforming of ethanol: H2 production for mcfc. Appl Catal A 249(1):119–128
Luo R, Misra M, Himmelblau D (2005) Sensor fault detection via multiscale analysis and dynamic PCA. Ind Eng Chem Res 38:1489–1495
Comas J, Marino F, Laborde M, Amadeo N (2004) Bio-ethanol steam reforming on ni/al2o3 catalyst. Chem Eng J 98(1–2):61–68
Benito M, Sanz J, Isabel R, Padilla R, Arjona R, Daza L (2005) Bio-ethanol steamreforming: insights on the mechanism for hydrogen production. J Power Source 151:11–17
Duan S, Senkan S (2005) Catalytic conversion of ethanol to hydrogen using combinatorial methods. Ind Eng Chem Res 44(16):6381–6386
Llorca J, DeLa Piscina P, Dalmon J, Sales J, Homs N (2003) Co-free hydrogen from steam reforming of bioethanol over zno-supported cobalt catalysts: effect of the metallic precursor. Appl Catal B 43(3):355–369
Liguras D, Kondarides D, Verykios X (2003) Production of hydrogen for fuel cells by steam reforming of ethanol over supported noble metal catalysts. Appl Catal B 43(4):345–354
Akande A, Aboudheir A, Idem R, Dalai A (2006) Kinetic modeling of hydrogen production by the catalytic reforming of crude ethanol over a co-precipitated ni-al2o3 catalyst in a packed bed tubular reactor. Int J Hydrogen Energy 31(12):1707–1715
Sahoo D, Vajpai S, Patel S, Pant K (2007) Kinetic modeling of steam reforming of ethanol for the production of hydrogen over co/al2o3 catalyst. Chem Eng J 125(3):139–147
Akpan E, Akande A, Aboudheir A, Ibrahim H, Idem R (2007) Experimental, kinetic and 2-d reactor modeling for simulation of the production of hydrogen by the catalytic reforming of concentrated crude ethanol (crcce) over a ni-based commercial catalyst in a packed-bed tubular reactor. Chem Eng Sci 62(12):3112–3126
Little A (1994) Multi-fuel reformers for fuel cells used in transportation-multi-fuel reformers: phase i. Technical report, Cambridge Arthur D. Little
Zalc J, Loffler D (2002) Fuel processing for pem fuel cells: transport and kinetic issues of system design. J Power Source 111(1):58–64
Campbell J (1970) Influences of catalyst formulation and poisoning on the activity and die-off of low temprature shift catalysts. Ind Eng Chem Proc Des Dev 9(4):588–595
Loffler D, McDermott S, Renn C (2003) Activity and durability of water-gas shift catalysts used for the steam reforming of methanol. J Power Source 114(1):15–20
Ruettinger W, Ilinich O, Farrauto R (2003) A new generation of water gas shift catalysts for fuel cell applications. J Power Source 118(12):61–65
Choi Y, Stenger H (2003) Water gas shift reaction kinetics and reactor modeling for fuel cell grade hydrogen. J Power Source 124(2):432–439
Ayastuy J, Gutierrez-Ortiz M, Gonzalez-Marcos J, Aranzabal A, Gonzalez-Velasco J (2005) Kinetics of the low temperature wgs reaction over a cuo/zno/al2o3 catalyst. Ind Eng Chem Res 44(1):41–50
Levent M (2001) Water-gas shift reaction over porous catalyst: temperature and reactant concentration distribution. Int. J. Hydrogen Energy 26(6):551–558
Kim D, Mayor J, Ni J (2005) Parametric study of microreactor design for water gas shift reactor using an integrated reaction and heat exchange model. Chem Eng J 110(1-3):1–10
Pasel J, Samsun R, Schmitt D, Peters R, Stolten D (2005) Test of a water-gas-shift reactor on a 3 kwe-scale–design points for high- and low-temperature shift reaction. J Power Source 152:189–195
Quiney A, Germani G, Schuurman Y (2006) Optimization of a water-gas shift reactor over a pt/ceria/alumina monolith. J Power Source 160(2):1163–1169
Basile A, Chiappetta G, Tosti S, Violante V (2001) Experimental and simulation of both pd and pd/ag for a water gas shift membrane reactor. Sep Purif Technol 25(1–3):549–571
Keiski R, Salmi T, Pohjola V (1992) Development and verification of a simulation model for a non-isothermal water-gas shift reactor. Chem Eng J 48(1):17–29
Amadeo N, Laborde M (1995) Hydrogen production from the low-temperature water-gas shift reaction: kinetics and simulation of the industrial reactor. Int J Hydrogen Energy 20(12):949–956
Hulteberg P, Brandin J, Silversand F, Lundberg M (2005) Preferential oxidation of carbon monoxide on mounted and unmounted noble-metal catalysts in hidrogen-rich streams. Int J Hydrogen Energy 30(11):1235–1242
Choi Y, Stenger H (2004) Kinetics, simulation and insights for co selective oxidation in fuel cell applications. J Power Source 129(2):246–254
Echigo M, Tabata T (2004) Development of novel ru catalyst of preferential co oxidation for residential polymer electrolyte fuel cell systems. Catal Today 90(3–4):269–275
Echigo M, Tabata T (2003) A study of co removal on an activated ru catalyst for polymer electrolyte fuel cell applications. Appl Catal A 251(1):157–166
Toyoshima I, Somorjai G (1979) Heat of chemisorption of \({\hbox{o}}_2,\) \({\hbox{h}}_2,\) co, \({\hbox{co}}_2\) and \({\hbox{n}}_2\) on polycristalline and single crystal transition metal surfaces. Catal Rev - Sci Eng 19(1):105–159
Bissett E, Oh S, Sinkevitch R (2005) Pt surface kinetics for a prox reactor for fuel cell feedstream processing. Chem Eng Sci 60(17):4709–4721
Linnhoff B, Townsend P, Boland P, Hewitt G.F, Thomas B.E.A, Guy A.R, Marsland R.H (1994) A user guide on process integration for the efficient use of energy. Institute of chemical engineers, Rugby, UK, rev sub edition
Feroldi D, Serra M, Riera J (2007) Performance improvement of a pemfc system controlling the cathode outlet air flow. J Power Source 169(1):205–212
Qi A, Peppley B, Karan K (2007) Integrated fuel processors for fuel cell application: a review. Fuel Process Technol 88(1):3–22
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Degliuomini, L.N., Biset, S., Basualdo, M. (2012). Design and Control of an Integrated Bio-Ethanol Processor with PEMFC. In: Basualdo, M., Feroldi, D., Outbib, R. (eds) PEM Fuel Cells with Bio-Ethanol Processor Systems. Green Energy and Technology. Springer, London. https://doi.org/10.1007/978-1-84996-184-4_9
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DOI: https://doi.org/10.1007/978-1-84996-184-4_9
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